• Title/Summary/Keyword: under-dispersion

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Effect of Dispersant and Silane on Dispersion of Magnetic Powder Paste (연자성 금속 분말의 분산에 분산제와 실란이 미치는 영향)

  • Lee, Chang Hyun;Shin, Hyo Soon;Yeo, Dong Hun;Nahm, Sahn
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.32 no.1
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    • pp.25-29
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    • 2019
  • Various process technologies for manufacturing power inductors are under development. The core goal is to increase the mixing ratio of the soft magnetic powder in the epoxy, and to uniformly disperse it in a molding-type power inductor, manufactured by the injection molding method. In this study, we investigated the effect of dispersant and silane on the dispersion of soft magnetic metal powders in epoxy. We added 0.6 wt% of dispersant and 2.0 wt% of silane, and an excellent dispersibility resulted. Under the conditions of 0.3 wt% of dispersant and 0.5 wt% of silane, we added both dispersant and silane together to observe the effect of their interaction on dispersibility. Similarly, the addition of 0.3 wt% of dispersant and 0.1 wt% of silane resulted in a sharp increase in viscosity, considered to be due to the interaction of the dispersant and silane. The addition of 0.1 wt% of dispersant with 0.5 wt% of silane resulted in a sharp rise in viscosity, and sedimentation-height decreased sharply due to the dispersion optimization.

Effect of Organic Processing Parameters in Non-aqueous Tape-casting on Dispersion Stability of Barium Titanate-Borosilicate Glass Based Suspensions (비수계 테잎성형공정의 유기공정변수의 변화에 따른 티탄산바륨-붕규산염유리계 현탁액의 분산안정성)

  • Yeo, Jeong-Gu;Choi, Sung-Churl
    • Korean Journal of Materials Research
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    • v.13 no.11
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    • pp.725-731
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    • 2003
  • The effect of organic processing parameters on the dispersion stability of the BaTiO$_3$-based dielectric particles and borosilicate glass particulate suspensions was investigated in a system where organic solvents, dispersant, binder and modifier were used as processing additives in a low temperature cofired ceramic fabrication processes. Two- and three-component organic solvents were used to disperse ceramic particles and it was found the better stability in the particulate suspension prepared in a bi-solvent, which was consists of toluene and ethanol in a non-azeotropic composition. The addition amount of organic additives had a great impact on dispersion in the present investigation. The flow curves of the suspensions prepared with binder and modifier were fitted according to the power-law equation, which indicates that the internal structure of the suspension could be disturbed under the applied shear stress. Finally, the LTCC green tapes were successfully tape-cast based upon the optimum formulation of LTCC suspension and its microstructure was compared with that of the hard-agglomerates.

A Study on the Dispersion of Air Pollutants in Local Circulation of Mesoscale (중규모 국지 순환에서 대기 오염 물질의 확산에 관한 연구)

  • 이화운;오은주
    • Journal of Environmental Science International
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    • v.3 no.1
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    • pp.39-47
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    • 1994
  • Dispersion characteristics of air pollutants in the mountainous coastal area are investigated in considering with the mesoscale local circulations using a two dimensional numerical model with two kinds of topograpy of 500m and 300m. In the model, land-sea breezes and mountain-valley wind are mainly considered under the condition of the absence of large scale prevailing flow in the circulation analysis, and the pollutants dispersion is traced by the Lagrangian methods. According to the results, the wind velocity is affected by topography and is stronger in the case of 500m height mountain than that of 300m, the Pollutants that source is near the coast transported over the mountain and dispersed to behind inland area. It is classified that the topography change control affects the wind velocity and the circulations. The pollutants that source is different transported and concentrated to behind inland and/or diffused to the sea area by the combination of the wind system with topographic changes. The results can be applied to the air pollution control with the arrangement design of industrial area and the planning of coastal developments.

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Random Walk Simulation of Atmospheric Dispersion on Surface Urbanization over Complex Terrain (복잡지형에서 도시화에 따른 대기오염 확산에 관한 시뮬레이션)

  • 이순환;이화운;김유근
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.2
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    • pp.67-83
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    • 2002
  • The coupled model (SMART) of dynamic meteorology model and particle dispersion model was developed. The numerical experiment on the relationship between change of land use and diffusion behavior in complex terrain was carried out using this model. It tried to investigate the change of particle diffusion behavior and local weather under the condition in which land-land breeze and sea breeze and mountain breeze intermingled. The numerical experiment results are as follows; 1) The more complicated local circulation field of the interaction of sea breeze, mountain breeze and Land -land breeze is formed. Then, the region circulation in which the urbanization is specific by location of the region is strengthened and is weakened. 2) Though in the region with dominant sea breeze, Land-land breeze does not appear directly, the progress of the sea wind to the inland is affected. 3) In the prediction of the air diffusion, emission high quality and accurate information of the emission site are important. That is to say, the dispersion predicting result which emission high quality and small error of the site perfectly vary for Land - land breeze in the effect may be brought about.

Analysis of Breakdown Voltage Dispersion and Breakdown Process in Mineral Oil (광유 중 절연파괴전압의 분산과 절연파괴진전 과정의 분석)

  • Lim, Dong-Young;Park, Sung-Gyu;Park, Cheol-Ho;Kim, Ki-Chai;Lee, Kwang-Sik;Choi, Eun-Hyeok
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.29 no.6
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    • pp.35-41
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    • 2015
  • This paper presents a breakdown voltage and a process of breakdown progress in mineral oil under an quasi-uniform field with decomposition products which occur after the oil discharge. The breakdown voltage in the oil revealed the characteristics of dispersion regardless of an electrode gap. The cumulative probability distribution was used to analyze the dispersion of the breakdown voltage. In addition, the process of breakdown progress in the oil can be reasonably described by the electron breakdown theory based on both electrons emitted from the cathode and ions by field-aided dissociation of the oil. The proposed breakdown process will be used for the basic data to explain the behavior pattern of the decomposition product to cause the dispersion of the breakdown voltage.

Dispersion of Highly Pure Single-Walled Carbon Nanotube in Aqueous Solution of Various Surfactants (다양한 계면활성제를 이용한 고순도 단일벽 탄소나노튜브의 수계 분산)

  • Goak, Jeung-Choon;Kim, Myoung-Su;Lee, Nae-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.153-153
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    • 2008
  • Practical application of single-walled carbon nanotubes (SWCNTs) qualified as a promising material has been limited by either poor dispersion or their insolubility in aqueous or organic media due to formation of bundling by relatively high surface energy. Thus, major attention to overcome this issue has been paid at surface modification of CNTs by functionalization, but this introduces defects to the sidewall of CNTs, consequently perturbing the inherent electronic and optical properties. Therefore, using surfactants is a general approach to disperse SWCNTs with lower damages by which bundled nanotubes could be dispersed up to the level of individuals or small bundles. Here, we have investigated various surfactants for their efficiency in dissolving purified SWCNTs produced by arc discharge in deionized water. To compare the surfactants respectively, we have determined the least amount of each surfactant to suspend the nanotubes under optimized experimental conditions(CNT amount, sonication power, and centrifugation speed, etc.) set on the basis of the most common surfactant (sodium dodecyl sulfate, SDS) and discussed the qualitative and quantitative characterization of SWCNT dispersions by UV-Vis absorption spectroscopy. Quantitative aspect about nanotube dispersion was that in particular N-methyl-2-pyrrolidone (NMP) and sodium dodecylbenzene sulfonate (NaDDBS) were found to be effective in dispersing individual tubes.

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Tracer Experiment for the Investigation of Urban Scale Dispersion of Air Pollutants - Simulation by CALPUFF Dispersion Model and Diffusion Feature of Tracer Gases (추적자 확산 실험에 의한 서울 도심 확산 현상 연구 - 추적기체의 확산특징과 CALPUFF 모델에 의한 모사)

  • Lee, Chong-Bum;Kim, Jea-Chul;Lee, Gang-Woong;Ro, Chul-Un;Kim, Hye-Kyeong
    • Journal of Korean Society for Atmospheric Environment
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    • v.23 no.4
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    • pp.405-419
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    • 2007
  • A series of tracer experiments for the evaluation of atmospheric dispersion was performed over the urban area of Seoul using two inert, non-deposition perfluorocarbon (PMCH and m-PDCH) gases during three years campaign on 2002, 2003 and 2005. 30 sampling sites for collecting these tracers were located along two arcs of 2.5 and 5 kilometers downwind from the release point. About ten measurements which each lasted for 2 hours or 4 hours were made over the two consecutive days during each campaign. CALPUFF and MM5 meteorological model were applied to evaluate the urban dispersion in detail. Size of Modeling domain was $27\;km{\times}23\;km$ and the fine nest in the modeling domain had a grid size of 0.5 km. The results showed that CALPUFF dispersion model had a tendency to estimate tracer concentrations about $2{\sim}5$ times less than those of ambient samples under many conditions. These consistent inaccuracy in urban dispersion was attributed to inherent inaccuracy and lack of details in terrain data at urban area.

The Characteristics of Creep for Dispersion Strengthened Copper (분산강화 동합금의 Creep 특성)

  • Park, K.C.;Kim, G.H.;Mun, J.Y.;Choi, J.H.
    • Journal of the Korean Society for Heat Treatment
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    • v.14 no.4
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    • pp.220-227
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    • 2001
  • The static creep behaviors of dispersion strengthened copper GlidCop were investigated over the temperature range of $650{\sim}690^{\circ}C$ (0.7Tm) and the stress range of 40~55 MPa (4.077~5.61 $kg/mm^2$). The stress exponents for the static creep deformation of this alloy was 8.42, 9.01, 9.25, 9.66 at the temperature of 690, 677, 663, and $650^{\circ}C$, respectively. The stress exponent, (n) increased with decreasing the temperature and became dose to 10. The apparent activation energy for the static creep deformation, (Q) was 374.79, 368.06, 361.83, and 357.61 kg/mole for the stress of 40, 45, 50, and 55 MPa, respectively. The activation energy (Q) decreased with increasing the stress and was higher than that of self diffusion of Cu in the dispersion strengthened copper. In results, it can be concluded that the static creep deformation for dispersion strengthened copper was controlled by the dislocation climb over the ranges of the experimental conditions. Larson-Miller parameter (P) for the crept specimens for dispersion strengthened copper under the static creep conditions was obtained as P=(T+460)(logtr+23). The failure plane observed for SEM slightly showed up transgranular at that experimental range, however, universally it was dominated by characteristic of the intergranular fracture.

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ASSESSMENT OF WIND CHARACTERISTICS AND ATMOSPHERIC DISPERSION MODELING OF 137Cs ON THE BARAKAH NPP AREA IN THE UAE

  • Lee, Jong Kuk;Kim, Jea Chul;Lee, Kun Jai;Belorid, Miloslav;Beeley, Philip A.;Yun, Jong-Il
    • Nuclear Engineering and Technology
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    • v.46 no.4
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    • pp.557-568
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    • 2014
  • This paper presents the results of an analysis of wind characteristics and atmosphere dispersion modeling that are based on computational simulation and part of a preliminary study evaluating environmental radiation monitoring system (ERMS) positions within the Barakah nuclear power plant (BNPP). The return period of extreme wind speed was estimated using the Weibull distribution over the life time of the BNPP. In the annual meteorological modeling, the winds from the north and west accounted for more than 90 % of the wind directions. Seasonal effects were not represented. However, a discrepancy in the tendency between daytime and nighttime was observed. Six variations of cesium-137 ($^{137}Cs$) dispersion test were simulated under severe accident condition. The $^{137}Cs$ dispersion was strongly influenced by the direction and speed of the main wind. A virtual receptor was set and calculated for observation of the $^{137}Cs$ movement and accumulation. The results of the surface roughness effect demonstrated that the deposition of $^{137}Cs$ was affected by surface condition. The results of these studies offer useful information for developing environmental radiation monitoring systems (ERMSs) for the BNPP and can be used to assess the environmental effects of new nuclear power plant.

Solubility Study of Graphene-oxide with Various Solvents (산화그래핀(Graphene oxide)의 솔벤트(solvent)별 Solubility에 대한 연구)

  • Jung, Su-Yeon;Choi, Sung-Woong
    • Composites Research
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    • v.35 no.1
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    • pp.18-22
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    • 2022
  • Dispersion is one of the most important factors in the manufacture of composite materials. In the manufacture of composite materials, solvents are used to better disperse the reinforcement, nano-filler in the matrix. Since dispersion is affected with solvents, it is necessary to study which solvent is adopted to get good dispersion. In this study, the dispersion behavior and solubility of graphene oxide(GO) were examined under various solvents (DMF, NMP, ethylene glycol, Acetone, DI water) to identify dispersion. As a result of UV-Vis spectroscopy absorbance measurement, it was found that DMF and ethylene glycol had the best dispersibility, whereas DI water showed the lowest dispersibility. In addition, as a result of visually observing the dispersion according to the surface tension and time, it was found that the dispersibility was excellent in the order of DI water, ethylene glycol, NMP, DMF, and acetone, which was consistent with the Hansen solubility parameter value.