• Bulletin of the Korean Chemical Society
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• v.35 no.12
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• pp.3427-3432
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• 2014

This study introduces a new method of combining Imaging Differential Optical Absorption Spectroscopy (Imaging-DOAS) data and plume dispersion formulas for power plant emissions to determine the three-dimensional structure of a dispersing pollution plume and the spatial distributions of trace gas volume mixing ratios (VMRs) under conditions of negligible water droplet and aerosol effects on radiative transfer within the plume. This novel remote-sensing method, applied to a power plant stack plume, was used to calculate the two-dimensional distributions of sulfur dioxide ($SO_2$) and nitrogen dioxide ($NO_2$) VMRs in stack emissions for the first time. High $SO_2$ VMRs were observed only near the emission source, whereas high $NO_2$ VMRs were observed at locations several hundreds of meters away from the initial emission. The results of this study demonstrate the capability of this new method as a tool for estimating plume dimensions and trace gas VMRs in power plant emissions.

• Atmosphere
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• v.25 no.4
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• pp.659-667
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• 2015

In this study, sensitivity of inflow wind speed and turbulent Schmidt number to pollutant dispersion in an urban street canyon is investigated, by comparing CFD-simulated results to wind-tunnel results. For this, we changed systematically inflow wind speed at the street-canyon height ($1.5{\sim}10.0m\;s^{-1}$ with the increment of $0.5m\;s^{-1}$) and turbulent Schmidt number (0.2~1.3 with interval of 0.1). Also, we performed numerical experiments under the conditions that turbulent Schmidt numbers selected with the magnitude of mean kinetic energy at each grid point were assigned in the street canyon. With the increase of the inflow wind speed, the model underestimated (overestimated) pollutant concentration in the upwind (downwind) side of the street canyon because of the increase of pollutant advection. This implies that, for more realistic reproduction of pollutant dispersion in urban street canyons, large (small) turbulent Schmidt number should be assigned for week (strong) inflow condition. In the cases of selectively assigned turbulent Schmidt number, mean bias remarkably decreased (maximum 60%) compared to the cases of constant turbulent Schmidt number assigned. At week (strong) inflow wind speed, root mean square error decreases as the area where turbulent Schmidt number is selectively assigned becomes large (small).

• Journal of Korean Society on Water Environment
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• v.20 no.5
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• pp.520-524
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• 2004

As a feasibility study for the application of carbon nanotubes to the treatment of environmental pollutants, the adsorption characteristics of humic acid on carbon nanotubes has been investigated. The dispersion features of carbon nanotubes in aquatic environment were investigated by measuring the variation of their electrokinetic potentials with pH, and the effects of some dispersants on their dispersion features were also examined. Under the experimental conditions, humic acid was observed to mostly adsorb on nanotubes within a few minutes and reach the equilibrium state within about one hour. The adsorption features of humic acid on nanotubes were found to follow the Freundlich model better than the Langmuir Model. Humic acid adsorbed on carbon nanotubes endothermically and the change of enthalpy in adsorption reaction was estimated to be ca. 18.37kJ/mol at standard state. The entropic change in adsorption reaction for humic acid was ca. 0.0503kJ/mol at standard state and the activation energy for adsorption was also estimated based on the change of rate constants with temperature. FT-IR investigations showed that the functional groups such as alcohol, ester, and aromatics existing in the chemical structure of humic acid might work as the bridge in its adsorption on nanotubes.

• Journal of the Korean Ceramic Society
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• v.31 no.3
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• pp.298-304
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• 1994

Water-based magnetic fluids were made of the synthesized ultrafine magnetite with surfactants such as sodium oleate and loeic acid. The water-based magnetic fluid was prepared under the condition that added amounts of sodium oleate and oleic acid dissolved with NH4OH were 2.64$\times$10-2 mol, 1.5~2.0$\times$10-2 mol respectively. The water-based magnetic fluid was stable and should be dispersed well dispersion in the range of pH 9.0 to pH 11.0. As the solid content increased from 0.05 g/cc to 0.4 g/cc, the viscosity of water-based magnetic fluids increased from 2.5 cP to 152 cP and their magnetization at 5 KOe linearly increased from 3.1 emu/g to 26 emu/g. The aggregated powder after drying the water-based magnetic fluid was also successfully re-dispersed in dilute NH4OH solution and in kerosene.

• Structural Engineering and Mechanics
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• v.56 no.3
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• pp.491-506
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• 2015

Propagation of the generalized Rayleigh waves in an initially stressed elastic half-space covered by an elastic layer is investigated. It is assumed that the initial stresses are caused by the uniformly distributed normal compressional forces acting on the face surface of the covering layer. Two different cases where the compressional forces are "dead" and "follower" forces are considered. Three-dimensional linearized theory of elastic waves in initially stressed bodies in plane-strain state is employed and the elasticity relations of the materials of the constituents are described through the Murnaghan potential where the influence of the third order elastic constants is taken into consideration. The dispersion equation is derived and an algorithm is developed for numerical solution to this equation. Numerical results for the dispersion of the generalized Rayleigh waves on the influence of the initial stresses and on the influence of the character of the external compressional forces are presented and discussed. These investigations provide some theoretical foundations for study of the near-surface waves propagating in layered mechanical systems with a liquid upper layer, study of the structure of the soil of the bottom of the oceans or of the seas and study of the behavior of seismic surface waves propagating under the bottom of the oceans.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.22 no.6
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• pp.501-505
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• 2009

$TiO_2$ nano-particle paste was prepared by ethyl cellulose, $\alpha$-terpineol and bis(2-ethylhexyl) phthalate (dioxcyl phthalate) for dye-sensitized solar cells (DSSCs). Dispersion and absorbance of $TiO_2$ photoanode films was controlled by adding different amount of ethyl cellulose and $\alpha$-terpineol. The morphology of prepared $TiO_2$ films was studied by field emission scanning electron microscopy (FE-SEM) and the optical properties of $TiO_2$ films were measured by UV/vis spectra. Photovoltaic-current density was observed to determine the electrochemical response of DSSCs. Energy conversion efficiency was obtained about 7.1% at ethyl cellulose and $\alpha$-terpineol at optimal mixed ratio (as ethyl cellulose: 0.1 g; $\alpha$-terpineol: 1.5 ml) under illumination with AM 1.5($100\;Wcm^{-2}$) simulated sunlight.

• Nuclear Engineering and Technology
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• v.50 no.6
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• pp.899-906
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• 2018

The irradiation performance of $U_3Si$ dispersion fuel in an Al matrix, $U_3Si-Al$, under the Hi-Flux Advanced Neutron Application Reactor (HANARO) design full-power condition of 30 MW was tested for full-power qualification of the fuel. A test assembly was fabricated containing 18 fuel rods made with atomized $U_3Si$ powder manufactured at the Korea Atomic Energy Research Institute. The test assembly was irradiated for 188 full-power operation days in the HANARO subject to the normal fuel-loading scheme and achieved about 60 at% U-235 average burnup and 75 at% U-235 peak burnup. The maximum linear power of the test assembly was 98 kW/m. Nondestructive and destructive postirradiation examinations were conducted. The measured postirradiation examination data were compared with data from previous irradiations and the design criteria required for HANARO fuel. Consequently, it was concluded that in-pile performance was acceptable and fuel integrity was maintained, and the behavior satisfied the fuel design requirements.

• Journal of the Korean Geosynthetics Society
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• v.18 no.4
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• pp.97-106
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• 2019

This study was conducted to propose a reasonable requirement regulation of barrier system of rubble mound revetment offshore landfill for preventing contaminant leakage. The barrier is composed with bottom layer and side barrier. The bottom layer was assumed as impermeable clay layer and side barrier was composed with HDPE sheet (primary element) and mid-protection layer (supplementary element). Seepage-advection-dispersion numerical analysis has been conducted using SEEP/W and CTRAN/W programs under steady flow. As the results, the minimum required barrier regulations for hydraulic conductivity and thickness of the bottom layer were suggested. For side barrier, the extended length of HDPE sheet and the hydraulic conductivity of mid-protection layer were also suggested.

• Journal of Food Hygiene and Safety
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• v.18 no.2
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• pp.43-50
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• 2003

A liquid chromatographic method, using matrix solid-phase dispersion (MSPD) is developed for the extraction of residual furazolidone in chicken eggs. Blank or fortified egg samples (0.5 g) were blended with Octadecylsilyl (Bulk $C_{18}$, 40${\mu}{\textrm}{m}$, 18%. load, endcapped. 2 g) derivatized silica. After homogenization, $C_{18}$/egg and Na$_2$S $O_4$matrix were transferred to a column made of 10 ml glass syringe and filter paper and compressed 4.0∼4.5 ml volume. The column was washed with 8 ml of hexane and dried under $N_2$ gas. Furazolidone was eluted with acetonitrile (8 ml) under gravity. The eluate containing furazolidone was free from interfering compounds when analyzed by HPLC with UV detection (365 nm, photodiode array). Calibration curves were linear (r = 0.99985) and inter- (1.47%) and intra-assay (5.29%) variabilities for the concentration range examined (7.8∼497 ng/g of eggs, 20 ${mu}ell$ injection volume) were indicative of an acceptable methodology for the analysis of furazolidone. Average recovery of furazolidone added to egg was 96.2%. The limit of detection for the proposed method was 1 ng/g for furazolidone. The method using MSPD is proposed as an alternative assay to the classical method which involves the use of large volumes of a harmful solvent and requires a long tedious separation and clean-up processes prior to its determination.

• Journal of the Korean Applied Science and Technology
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• v.13 no.3
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• pp.83-94
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• 1996

EMA-co-DAMA were synthesized from 2-diethylaminoethyl metacrylate and ethylhexyl metacrylate in acrylmonomer. To facilitate water emulsification, acrylic copolymer was cationized by acetic acid to produce acetated acrylic copolymer. The structures of the synthesized copolymer and acetated copolymers were confirmed by IR, NMR, and molecular weight was measure by GPC, and C.H.N elemental analysis. Acetated acrylic copolymers were perfectly emulsified in water and showed increased emulsion stability. Polymer dispersion for cement modifier[(PDCM-PED) water proof agent of cement for concrete in building construction] was prepared by blending of the guaternized acrylic copolymer syndisized above, sodium silicate, sodium gluconate and oleic acid emulsion. The result with prepared polymer dispersion of cement modifier was examined, and it was found that excellent waterprooffing effect ; Water permeability ratio is 0.50 under the water pressure of $100g/cm^2$ and 0.60 under $3kg/cm^2$, and water absorption ratio is $0.42{\sim}0.50$ and $1.0{\sim}1.02$ compressive strength ratio at mixed of water/PDCM-PED is 50 times.