• Title/Summary/Keyword: ultraviolet spectra

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SPECTRA OF CHROMOSPHERICALLY ACTIVE STARS (채층 활동이 강한 별들의 분광선)

  • KANG YOUNG WOON;KIM HOIL;LEE WOO BAIK;OH KYU DONG
    • Publications of The Korean Astronomical Society
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    • v.15 no.spc1
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    • pp.93-102
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    • 2000
  • We have reviewed the magnetic activity in close binaries. Solar like magnetic activity indicators such as photometric spots, chromo spheric emission, coronal X-ray and radio emission, and flare activity are commonplace in many cool stars with convective envelopes. Using the UV spectra we confirmed the strength of stellar activity increases with more rapid rotation and later spectral types which corresponds to the increasing depth of the star's convective envelope. Apart from very young stellar objects such as T Tauri stars, the stars with the highest levels of activity are close binary systems composed of cool stars, i.e., the chromospherically active binaries such as RS CVn, BY Dra, W UMa and related systems. The IUE low and high dispersion spectra of V711 Tau, VW Cep and SW Lac are used for ultraviolet photometry and for a variation study of chromospheric activity. Evidence of chromospherically activity is indicated by the intensity variation of the Mg II emission line with orbital phase.

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Synthesis of Praseodymium-Doped TiO2 Nanocatalysts by Sol-Microwave and Their Photocatalytic Activity Study

  • Huang, Fengping;Wang, Shuai;Zhang, Shuang;Fan, Yingge;Li, Chunxue;Wang, Chuang;Liu, Chun
    • Bulletin of the Korean Chemical Society
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    • v.35 no.8
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    • pp.2512-2518
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    • 2014
  • The praseodymium-doped $TiO_2$ photocatalyst samples, which could degrade methyl orange under UV irradiation, were prepared by sol-microwave method for improving the photocatalytic activity of $TiO_2$. The resulting materials were analyzed by X-ray diffraction (XRD), scanning electron microscopy (SEM), Transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), Raman spectra, Fourier transform infrared spectra (FTIR) and Ultraviolet-visible diffuse reflectance spectra (UV-vis DRS). It was found Pr doping retarded the growth of crystalline size and the phase transformation from anatase to rutile, and narrowed the band gap energy. Praseodymium doping brought about remarkable improvement in the photoactivity. The optimal dopant amount of Pr was 2% by molar of cement and the calcination temperature was $500^{\circ}C$ for the best photocatalytic activity. The improvement of photocatalytic activity was ascribed to the occurrence of lattice distortion and the effective containment of the recombination of the electron-hole by $Pr^{3+}$.

Fluorescence Analysis of Harmful Food Colors -Establishment of Fluorescence Assay Method by the Use of Filter Paper Adsorption- (유해성(有害性) 식품착색료(食品着色料)의 형광검사(螢光檢査) -여지흡착(濾紙吸着)을 이용한 형광분석법(螢光分析法)의 확립-)

  • Lee, Mie-Soon
    • Korean Journal of Food Science and Technology
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    • v.13 no.2
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    • pp.114-120
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    • 1981
  • A rapid and simple method for detecting colors was attempted on the basis of absorption and emission spectra of reflected light at $45^{\circ}$ angle from color-adsorbed filter paper illuminated by ultraviolet light through interference filter. Absorption spectra of prepared samples revealed more characteristic patterns than emission spectra. Detection of colors was readily accomplished by the investigation of wave length range, distribution pattern, the number of absorption bands and the degree of quenching.

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CORONAL TEMPERATURE, DENSITY AND NONTHERMAL VELOCITY DERIVED FROM SERTS EUV SPECTRA

  • MOON YONG-JAE;YUN HONG-SIK;DAVILA J. M.;PARK YOUNG DEUK
    • Journal of The Korean Astronomical Society
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    • v.29 no.2
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    • pp.207-215
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    • 1996
  • To derive coronal temperature, electron density and nonthermal velocity, we have analyzed high resolution spectra (e.g., Fe XII 338.3, Fe XII 352.1, Fe XIV 334.2, Fe XIV 353.8, Fe XV 284.2, Fe XV 321.8, Fe XV 327.0, Fe XVI 335.4, and Fe XVI 360.8) taken from AR 6615 by SERTS (Solar Extreme Ultraviolet Rocket Telescope and Spectrograph). Important findings emerging from the present study are as follows: (1) Temperature estimated from Fe XVI 335.4 and Fe XIV, 334.2 is $\~2.4\times10^6 K$ and no systematic difference in temperature is found between the active region and its adjacent quiet region; (2) Mean electron density estimated from Fe XV is $\~3\times10^9 cm^{-3}\;and\;\~10^{10} cm^{-3}$ from Fe XII and Fe XIV; (3) Mean density of the active region is found to be higher than that of the quiet region by a factor of 2; (4) Nonthermal velocity estimated from Fe XV and Fe XVI is $20\times25 km\;s^{-l}$ which decreases with increasing ionization temperatures. This supports the notion that the nonthermal velocity declines outwards above the transition region.

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ON THE HOMOGENEITY OF THE EXTINCTION LAW IN OUR GALAXY

  • Bondar, A.;Galazutdinov, G.;Patriarchi, P.;Krelowski, J.
    • Journal of The Korean Astronomical Society
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    • v.39 no.3
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    • pp.73-80
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    • 2006
  • We analyze the extinction law towards several B1V stars-members of our Galaxy, searching for possible discrepancies from the galactic average extinction curve. Our photometric data allow to build extinction curves in a very broad range: from extreme UV till infrared. Two-colour diagrams, based on the collected photometric data from the ANS UV satellite, published UBV measurements and on the infrared 2MASS data of the selected stars, are constructed. Slopes of the fitted straight lines are used to build the average extinction curve and to search for discrepant objects. The selected stars have also been observed spectroscopically from the Terskol and ESO Observatories; these spectra allow to check their Sp/L's. The spectra of only about 30% of the initially selected objects resemble closely that of HD144470, considered as the standard of B1 V type. Other spectra either show some emission features or belong clearly to another spectral types. They are not used to build the extinction curve. Two-colour diagrams, constructed for the selected B1 V stars, showing no emission stellar features, prove that the interstellar extinction law is homogeneous in the Galaxy. Both the shape of the curve and the total-to-selective extinction ratio do not differ from the galactic average and the canonical value(3.1) respectively. The circumstellar emissions usually cause some discrepancies from the average interstellar extinction law; the discrepancies observed in the extraterrestrial ultraviolet, usually follow some misclassifications.

On the UV and IR Spectra of Dioxane Lignin from Bamboo Culm (죽재(竹材) Dioxane Lignin의 UV, IR Spectrum에 대하여)

  • Moon, Chang-Kuck;Jo, Jong-Soo
    • Journal of the Korean Wood Science and Technology
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    • v.15 no.4
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    • pp.26-31
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    • 1987
  • The ultraviolet and infrared spectra of dioxane lignin from bamboo were investigated. 1. Spectrum curve type considerably resembled that of wood lignin. There were 3 absorption peak positions at 210nm(max. peak), at 260-270nm(shallow mini. peak), at 280nm(lower max. peak) as in the wood lignin spectra. 2. The lower minimum peak near at 280 nm is the typical peak of lignin. This peak does not exist exactly at 280 nm but from 282nm to 285nm in this bamboo UV spectra. The absorption intensities are equal in this region and the peak is not sharp. 3. The absorption band of aromatic nucleus is near at wave number $1550cm^{-1}$ in the IR spectra of bamboo lignin. The intensity at about 1040-$1130cm^{-1}$ and at about 1230-$1275cm^{-1}$ were similar in the hardwood lignin but reverse to that of softwood lignin spectrum.

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Study of Unidentified Spectral Lines in the High-Resolution Spectra of Comet Machholz (C/2004Q2) (Machholz 혜성(C/2004Q2) 고분산 스펙트럼을 이용한 미확인 분광선 연구)

  • Hwang, Sung-Won;Han, Je-Hee;Sim, Chae-Kyung;Kim, Sang-Joon;Jin, Ho;Im, Myung-Shin;Kim, Kang-Min
    • Journal of Astronomy and Space Sciences
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    • v.26 no.4
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    • pp.487-498
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    • 2009
  • We observed Comet Machholz (C/2004Q2) using the BOES (BOao Echelle Spectograph) at the Bohyunsan Observatory on January 4, 2005. We have studied a wavelength range of $4800{\sim}8100{\AA}$ in order to investigate unidentified spectral lines in the high-resolution spectra of Machholz. We compared the Machholz spectra with the high-resolution spectra of previous comets: Swift-Tuttle, Brorsen-Metcalf, Austin, and 122P/de Vico. We identified many molecular lines, which are previously unknown; and these identifications will be useful information for studying high-resolution spectra of future comets.

Properties of MgMoO4:Eu3+ Phosphor Thin Films Grown by Radio-frequency Magnetron Sputtering Subjected to Thermal Annealing Temperature (열처리 온도 변화에 따른 라디오파 마그네트론 스퍼터링으로 성장된 MgMoO4:Eu3+ 형광체 박막의 특성)

  • Cho, Shinho
    • Current Photovoltaic Research
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    • v.4 no.1
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    • pp.25-29
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    • 2016
  • $Eu^{3+}$-activated $MgMoO_4$ phosphor thin films were grown at $400^{\circ}C$ on quartz substrates by radio-frequency magnetron sputter deposition from a 15 mol% Eu-doped $MgMoO_4$ target. After the deposition, the phosphor thin films were annealed at several temperatures for 30 min in air. The influence of thermal annealing temperature on the structural and optical properties of $MgMoO_4:Eu^{3+}$ phosphor thin films was investigated by using X-ray diffraction (XRD), photoluminescence (PL), and ultraviolet-visible spectrophotometry. The transmittance, optical band gap, and intensities of the luminescence and excitation spectra of the thin films were found to depend on the thermal annealing temperature. The XRD patterns indicated that all the thin films had a monoclinic structure with a main (220) diffraction peak. The highest average transmittance of 91.3% in the wavelength range of 320~1100 nm was obtained for the phosphor thin film annealed at $800^{\circ}C$. At this annealing temperature the optical band gap energy was estimated as 4.83 eV. The emission and excitation spectra exhibited that the $MgMoO_4:Eu^{3+}$ phosphor thin films could be effectively excited by near ultraviolet (281 nm) light, and emitted the dominant 614 nm red light. The results show that increasing RTA temperature can enhance $Eu^{3+}$ emission and excitation intensity.

Qualitative Analysis of the Major Constituents in Traditional Oriental Prescription Bang-poong-tong-sung-san by Liquid Chromatography/Ultraviolet Detector/Ion-Trap Time-of-Flight Mass Spectrometry

  • Eom, Han Young;Kim, Hyung-Seung;Han, Sang Beom
    • Mass Spectrometry Letters
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    • v.5 no.1
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    • pp.24-29
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    • 2014
  • An advanced and reliable high performance liquid chromatography (HPLC)/ultraviolet detector (UV)/ion-trap time-of-flight (IT-TOF) mass spectrometry was developed for the simultaneous quantification of 19 marker compounds in Bang-poong-tong-sung-san (BPTS), a traditional oriental prescription. Various parameters affecting HPLC separation and IT-TOF detection were investigated, and optimized conditions were identified. The separation was achieved on a Capcell PAK C18 column ($1.5mm{\times}250mm$, $5{\mu}m$ particle size) using a gradient elution of acetonitrile and water containing 0.1% formic acid at a flow rate of 0.1 mL/min. The column temperature was maintained at $40^{\circ}C$ and the injection volume was $2{\mu}L$. IT-TOF system was equipped with an electrospray ion source (ESI) operating in positive or negative ion mode. The optimized electrospray ionization parameters were as follows: ion spray voltage, +4.5 kV (positive ion mode), or -3.5 kV (negative ion mode); drying gas ($N_2$), 1.5 L/min; heat block temperature, $200^{\circ}C$. Automatic $MS^n$ (n = 1~3) analyses were carried out to obtain structural information of analytes. Elemental compositions and their mass errors were calculated based on their accurate masses obtained from a formula predictor software. The marker compounds in BPTS were identified by comparisons between $MS^n$ spectra from standards and those from extracts. Moreover, the libraries of $MS^2$ and $MS^3$ spectra and accurate masses of parent and fragment ions for marker compounds were constructed. The developed method was successfully applied to the BPTS extracts and identified 17 out of 19 marker compounds in the BPTS extracts.

Influence of Inorganic Ions and pH on the Photodegradation of 1-Methylimidazole-2-thiol with TiO2 Photocatalyst Based on Magnetic Multi-walled Carbon Nanotubes

  • Jiang, Yinhua;Luo, Yingying;Lu, Ziyang;Huo, Pengwei;Xing, Weinan;He, Ming;Li, Jiqin;Yan, Yongsheng
    • Bulletin of the Korean Chemical Society
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    • v.35 no.1
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    • pp.76-82
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    • 2014
  • 1-Methylimidazole-2-thiol, as a kind of mercaptans, is a typical organic pollutant which has not been efficiently removed. In this study, titanium dioxide ($TiO_2$) photocatalyst based on magnetic multi-walled carbon nanotubes (MWCNTs) was synthesized via hydrothermal and sol-gel methods. The as-prepared photocatalyst was extensively characterized by X-ray diffraction (XRD), X-ray energy diffraction spectrum (EDS), transmission electron microscope (TEM), Fourier transform infrared (FT-IR) spectra, UV-Vis diffuse reflectance spectra (UV-vis DRS) and vibrating sample magnetometer (VSM). This photocatalyst of $TiO_2$/$Fe_3O_4$/MWCNTs was proved to exhibit high photocatalytic efficiency and the photodegradation rate could reach nearly 82.7% for the degradation of 1-methylimidazole-2-thiol under ultraviolet irradiation. In addition, the results demonstrated that inorganic ions had a negative impact on photodegradation of 1-methylimidazole-2-thiol to varying degrees. Moreover, pH had a great and complex effect on photocatalytic degradation of 1-methylimidazole-2-thiol under ultraviolet irradiation.