• Title/Summary/Keyword: ultraviolet spectra

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Ultraviolet Spectrophotometry of VV Cephei

  • Kang, Young-Woon
    • Bulletin of the Korean Space Science Society
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    • 1992.10a
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    • pp.14-14
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    • 1992
  • The IUE archival spectra of VV Cephei were collected to investigate the eclipse nature in the ultraviolet. The temperature of the B star has been determined, as approximately30,OOOK, based en the flux distributions durstributions during egress, Light curves of VV Cephei were reduced from the spectrophotometry of the IUE archival spectra. Three light curves at the center wavelengths of 2350A,2550A and :!850A have been analyzed by the modified Wilson and Oevinney light curve program. the radii of the B star and M star were deduced to 0.05 and 0.22 of uint separation, respectively. The UV light curves show anevidence that the light was attenuated by the highly opaque atmosphere of the M star

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FUV Images and Physical Properties of the Orion-Eridanus Superbubble region

  • Ko, Young-Soo;Min, Kyoung-Wook;Seon, Kwang-Il
    • The Bulletin of The Korean Astronomical Society
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    • v.35 no.2
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    • pp.71.1-71.1
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    • 2010
  • The far-ultraviolet (FUV) C IV and H2 emission spectra of Orion-Eridanus Superbubble (OES) is hereby presented. The OES seems to consist of multiple phase through the detection of highly-ionized gas and pervasive neutral hydrogen. The former is traced by hot gas while the latter is traced by cold medium. A spectral image made with H2 fluorescent emission shows that the spatial distribution of hydrogen molecule is well correlated with the dust map. The model spectra was taken from a photodissociation region (PDR) radiation code which finds a best suitable parameter such as hydrogen density and intensity of the radiation field. C IV emission is caused by intermediate temperature ISM about 10^5 K. Therefore we could get more clear evidence to reveal the morphology of OES. In this process, the hydrogen density and gas temperature were also estimated. The data were obtained with the Far-Ultraviolet Imaging Spectrograph (FIMS) and the whole data handling were followed by previous FIMS analysis.

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ULTRAVIOLET SPECTROPHOTOMETRY OF VV CEPHEI

  • Kang, Young-Woon
    • Journal of Astronomy and Space Sciences
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    • v.9 no.1
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    • pp.111-119
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    • 1992
  • The IUE archival spectra of VV Cephei were collected to investigate the eclipse nature in the ultraviolet. The temperature of the B star has been determined, as approximately 30000K, based on the flux distributions during egress. Light curves of VV Cephei were reduced from the spectrophotometry of the IUE archival spectra. Three light curves at the center wavelengths of 2350 ${\AA}$, 2550 ${\AA}$ and 2850 ${\AA}$ have been analyzed by the modified Wilson and Devinney light curve program. The radii of the B star and M star were deduced to 0.05 and 0.22 of unit separation, respectively. The UV light curves show an evidence that the light was attenuated by the highly opaque atmosphere of the M star.

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Determination of Acetaminophen in Tablet Formulations by Second Derivative Ultraviolet Spectrometry (2차 미분 자외부 분광광도법에 의한 정제중의 아세트아미노펜 정량)

  • 유경수;고익배
    • YAKHAK HOEJI
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    • v.30 no.2
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    • pp.100-103
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    • 1986
  • The second derivative absorption spectra of acetaminophen in commercial tablet forms were measured without prior separation from other pharmaceutical adjuvants. The second derivative spectra of acetaminophen were found to have no influence on the characteristic absorbance band of it. A plot of 25 sets of the ordinate (Z) values with various acetaminophen concentrations mixed in other additives gave a straight line (correlation coefficient, 0.9999) and the slope was 2.901${\times}10^{-2}Z$ value/($\mu\textrm{g}$/ml). The procedures were sufficiently sensitive, precise and economical for the assay of tablets of acetaminophen.

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Spectroscopic Studies of Conjugated Uracil $Derivatives^+$

  • Chang Kiu Lee;Young Hie Kim
    • Bulletin of the Korean Chemical Society
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    • v.12 no.2
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    • pp.207-210
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    • 1991
  • Ultraviolet spectra of 5-and 6-uracilyl compounds which contain conjugated double bonds were obtained and their characteristic phenomena were examined. 5-Formyluracil and 6-methyl-5-formyluracil showed bathochromic shifts which should be expected from a conjugated carbonyl compound. 6-Formyluracil did not show any shift in absorbing wavelength. 5-and 6-uracilylacrylic acid derivatives, on the other hand, showed absorption at similar wavelengths, indicating the presence of a hexatriene chromophore. The ratio of ${\Delta}ν/J$ in nuclear magnetic resonance spectra of those compounds decreased drastically as the acrylic acids or esters were converted into amides.

Enhanced Photocatalytic Activity of 3,4,9,10-Perylenetetracarboxylic Diimide Modified Titanium Dioxide Under Visible Light Irradiation

  • Kim, Ji-Won;Kim, Hee-Sung;Yu, Kook-Hyun;Fujishima, Akira;Kim, Young-Soon
    • Bulletin of the Korean Chemical Society
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    • v.31 no.10
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    • pp.2849-2853
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    • 2010
  • A method to improve the photocatalytic activity of titanium dioxide by modification with a sensitizer and a metal oxide is proposed. To achieve this goal, we used metal oxides as dopants. In particular, $CaWO_4$ and $Gd_2O_2S$:Tb were used because their 2.6 eV and 2.2 eV band gap energy and optical properties have a large positive effect on photocatalysis. The improvement in the photocatalytic activity of $TiO_2$ modified with $Gd_2O_2S$:Tb under ultraviolet light irradiation is described in a previous study. The present work focuses on the sensitization of metal oxide-modified $TiO_2$. Having observed the ultraviolet-visible absorption spectra of 3,4,9,10-Perylenetetracarboxylic diimide in the wide visible-light region from 400 nm to 650 nm and the broad peaks in its photoluminescence spectra at 695 nm and 717 nm, we decided to use this perylene dye to sensitize modified $TiO_2$ to enhance its activity as a visible-light harvesting photocatalyst. We also explored the positive effects thin-film surface changes stemming from ultraviolet pre-treatment have on photocatalytic activity. Finally, we subjected several metal oxide-modified $TiO_2$ products sensitized by the perylene dye to ultraviolet pre-treatment, obtaining the most active photocatalysts.

UV emission of ZnO:Er films prepared by ultrasonic spray pyrolysis (초음파분무법으로 제조한 ZnO:Er막의 UV 발광 특성)

  • Choi, Mu-Hee;Ma, Tae-Young
    • Journal of Sensor Science and Technology
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    • v.16 no.4
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    • pp.307-312
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    • 2007
  • The films of Er-doped ZnO (ZnO:Er) were prepared onto MgO wafers by ultrasonic spray pyrolysis at $550^{\circ}C$. The concentration of Er in the deposition source varied from 0.5 wt% to 3.0 wt%. The crystallographic properties and surface morphologies of the films were investigated by X-ray diffraction (XRD) and scanning electron microscope (SEM), respectively. The properties of photoluminescence (PL) for the films were investigated by dependence of PL spectra on the Er concentration in the films. The films were grown as polycrystalline with a dominant direction of [002]. The grain size of the films were reduced by Er-doping. Er-doping enhanced the ultraviolet emission of ZnO:Er films. The ZnO:Er films prepared with the deposition source of 2.0 wt% Er showed the strongest ultraviolet light emission peak among the films in this study.

On the UV Spectra of AcBr Lignins from Softwoods grown in Mt. Jiri (지리산산(智異山産) 침엽수재(針葉樹材) AcBr Lignin의 UV Spectra에 대(對)하여)

  • Jo, Jong-Soo;Moon, Chang-Kuck
    • Journal of the Korean Wood Science and Technology
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    • v.12 no.3
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    • pp.35-40
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    • 1984
  • The ultraviolet absorption spectra of AcBr lignin (Acetyl Bromide lignin) from 10 species grown in Mt. Jiri were determined. There were 3 peak positions, at 249nm (max peak), at 267-268 nm (shallow min. peak) and at 280 nm (lower max. peak). The Bjorkman lignin and lignin sulfonic acid spectra had shoulders, but the AcBr lignin had not them. Average absorbances and absorptivities of the AcBr lignins at peak positions were $0.367{\pm}0.0015$, $24.56{\pm}0.0535$, at 249 nm, $0.278{\pm}0.0016$, $18.50{\pm}0.0569$, at 267-268 nm and $0.306{\pm}0.0016$, $20.42{\pm}0.0627$ at 280 nm, respectively.

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Synthesis of N$^6$-Aminoalkyl-5'-adenylic Acid Derivatives

  • Kang, Jung-Bu
    • Bulletin of the Korean Chemical Society
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    • v.1 no.4
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    • pp.126-131
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    • 1980
  • Seventeen new $N^{6}$-aminoalkyl derivatives of 5'-adenylic acid and adenosine 5'-triphosphate (Compound I-XVII) were synthesized from 6-chloropurine ribonucleoside by reaction with appropriate diamines. This paper discusses the procedure of synthesis and the identification of the derivatives by ultraviolet spectra, high voltage electrophoresis, paper chromatography, elemental analyses, and other chemical methods.