• Title/Summary/Keyword: ultra-high-degree

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Effect of ${\gamma}$-Ray Irradiation on Surface Oxidation of Ultra High Molecular Weight Polyethylene/Zirconia Composite Prepared by in situ Ziegler-Natta Polymerization

  • Kwak, Soon-Jong;Noh, Dong-Il;Chun, Heung-Jae;Lim, Youn-Mook;Nho, Young-Chang;Jang, Ju-Woong;Shim, Young-Bock
    • Macromolecular Research
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    • v.17 no.8
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    • pp.603-608
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    • 2009
  • Novel ultra-high molecular weight polyethylene (UHMWPE)/zirconia composites were previously prepared by the in situ polymerization of ethylene using a Ti-based Ziegler-Natta catalyst supported on to the surface of zirconia, as a bearing material for artificial joints. Tribological tests revealed that a uniform dispersion of zirconia in UHMWPE markedly increased the wear resistance. The effects of zirconia content on the oxidation behavior of the ${\gamma}$-ray-treated UHMWPE/zirconia composite surfaces were examined. The oxidation index that estimates the oxidation degree as the content of total carbonyl compounds was monitored using Fourier transform infrared spectroscopy-attenuated total reflectance. The changes in the surface composition due to the oxidation were confirmed by electron spectroscopy for chemical analysis. The extent of oxidation decreased with increasing zirconia content, which was attributed to the increased crystallinity as well as the decreased polymer portion of the UHMWPE/zirconia composites.

Study on the Fabrication of a Large Steel Ingot with the Ultra Clean and Low Hot Top Ratio (저압탕 고청정 대형 잉고트 제조 연구)

  • Oh, S.H.;Lee, D.H.;Kim, N.S.;NamKung, J.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2009.05a
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    • pp.91-93
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    • 2009
  • A large steel ingot needs to be larger and larger in size and an ultra high clean, no defect in quality with a low hot top ratio for the resent heavy industry. The demands are very difficult to achieve simultaneously because of their contradictive effect to each other in results. In this study, 30ton steel ingot was cast in a foundry with an optimized design parameter of cast mold and cast process conditions for the low hot top ratio, 12%. The cast ingot was analyzed in macro defect, segregations, and cleanness. No macro defect was founded in central surface of the ingot. The degree of segregation and cleanness are in the controlled range with a sound quality.

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Characteristics of Early-Age Restrained Shrinkage and Tensile Creep of Ultra-High Performance Cementitious Composites (UHPCC) (초고성능 시멘트 복합체의 초기 재령 구속 수축 및 인장 크리프 특성)

  • Yoo, Doo-Yeol;Park, Jung-Jun;Kim, Sung-Wook;Yoon, Young-Soo
    • Journal of the Korea Concrete Institute
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    • v.23 no.5
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    • pp.581-590
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    • 2011
  • Since ultra-high performance cementitious composites (UHPCC) not only represents high early age shrinkage strain due to its low water-to-binder ratio (W/B) and high fineness admixture usage but also reduces the cross section of structure from the higher mechanical properties, it generally has more shrinkage cracks from the restraints of formwork and reinforcing bars. In this study, free and restrained shrinkage experiments were conducted to evaluate the suitability of incorporating both expansive admixture (EA) and shrinkage reducing agent (SRA). The test results indi-cated that approximately 40~44% of free shrinkage strain was decreased. Also, the results showed that 35% and 47% of residual tensile stresses were relieved by synergetic effect of SRA and EA, respectively. Residual tensile stresses from ringtest were relaxed by approximately 61% and 64% of elastic shrinkage stresses due to SRA and EA, respectively, because of the tensile creep effect. Therefore, the creep effect should be considered to precisely estimate the restrained shrinkage behavior of concrete structures. The degree of restraint of UHPCC was approximately in the range of 0.78~0.85. The addition of combined EA and SRA showed minute influence on the degree of restraint. However, the effect decreased when thicker concrete ring was used. Tensile creep strains were measured and compared to the predicted values from 4-parametric prediction model considering time dependent restrained forces.

Lubrication Performance Analysis of a Spiral Groove Dry Gas Seal for a High-Speed Flying Object (고속비행체용 스파이럴 그루브 드라이 가스 시일의 윤활 성능해석)

  • Lee An Sung;Kim Jun Ho
    • Tribology and Lubricants
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    • v.21 no.1
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    • pp.8-15
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    • 2005
  • In this study a general Galerkin FE lubrication analysis method is utilized to analyze the complex lubrication performance of a spiral groove seal, which is being designed and developed for a high-speed flying object application operating at a high-speed of over 50,000 rpm. As at the equilibrium seal clearance the axial stiffness of the seal is predicted to have almost such a constant high value of $1.04\times10^8\;N/m$ regardless of a rotating speed, the seal is expected to maintain a stable thickness of lubrication film under a certain external excitation acting. Also, as even at an ultra high-speed of 80,000 rpm the axial damping of the seal is shown to have a rotatively high value of 5,775 N-s/m, the dynamic stability of the seal system at the axial degree of freedom is assured well enough.

Role of CH2F2 and N-2 Flow Rates on the Etch Characteristics of Dielectric Hard-mask Layer to Extreme Ultra-violet Resist Pattern in CH2F2/N2/Ar Capacitively Coupled Plasmas

  • Kwon, B.S.;Lee, J.H.;Lee, N.E.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.210-210
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    • 2011
  • The effects of CH2F2 and N2 gas flow rates on the etch selectivity of silicon nitride (Si3N4) layers to extreme ultra-violet (EUV) resist and the variation of the line edge roughness (LER) of the EUV resist and Si3N4 pattern were investigated during etching of a Si3N4/EUV resist structure in dual-frequency superimposed CH2F2/N2/Ar capacitive coupled plasmas (DFS-CCP). The flow rates of CH2F2 and N2 gases played a critical role in determining the process window for ultra-high etch selectivity of Si3N4/EUV resist due to disproportionate changes in the degree of polymerization on the Si3N4 and EUV resist surfaces. Increasing the CH2F2 flow rate resulted in a smaller steady state CHxFy thickness on the Si3N4 and, in turn, enhanced the Si3N4 etch rate due to enhanced SiF4 formation, while a CHxFy layer was deposited on the EUV resist surface protecting the resist under certain N2 flow conditions. The LER values of the etched resist tended to increase at higher CH2F2 flow rates compared to the lower CH2F2 flow rates that resulted from the increased degree of polymerization.

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Changes in Physicochemical Properties of Rice Starch Processed by Ultra-Fine Pulverization

  • Han, Myung-Ryun;Chang, Moon-Jeong;Kim, Myung-Hwan
    • Journal of Applied Biological Chemistry
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    • v.50 no.4
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    • pp.234-238
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    • 2007
  • The effects of ultra-fine pulverization on the physicochemical properties of rice starch (RS) were investigated using a high impact planetary mill. After pulverization, RVA characteristics, peak viscosity, break down, and set back values of RS decreased from 274.75 to 9.42 RVU, 214.46 to 6.17 RVU, and 87.80 to 17.00 RVU, respectively. The pasting properties also changed significantly. X-Ray diffractogram revealed RS had four A-type peaks, which disappeared after pulverization. The peak temperature and gelatinization enthalpy of RS using differential scanning calorimetry (DSC) were 13.99 J/g at $75.14^{\circ}C$, whereas the pulverized RS (PRS) had two peaks, 0.13 J/g at $63.88^{\circ}C$ and 1.23 J/g at $101.24^{\circ}C$. DSC measurement showed the retrogradation degree of PRS was lower than that of RS after storage at 4 and $25^{\circ}C$. The enzymatic (${\alpha}$-amylase) digestibilities of RS and PRS were 72.7 and 77.3%, respectively.

A Study on a Ultra-wide-angle Wireless Digital Electronic Endoscope Modules (초광각 무선 디지털 전자 내시경 모듈에 관한 연구)

  • Shim, Dongha;Kim, Hyung-O;Lee, Bong-Ju;Hong, Seung-Cheol;Lee, Jason;Cha, Jaesang
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.63 no.4
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    • pp.570-574
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    • 2014
  • This paper proposes a wireless digital endoscope with a ultra-wide-angle view. Two key components are implemented to demonstrate the feasibility of the proposed endoscope. First, a ultra-wide-angle lens module with the field of view of 144 degree and F-number of 2.2 is designed and manufactured. Second, a wireless module for a high-speed video transfer is implemented using a USB device server and wireless LAN router. The wireless module can directly transfer a streaming video to a computer with the resolution of 1920x1080, frame rate of 30 fps, and data rate of 53.3 Mbps without an internet connection. Since the wireless module supports two USB devices, two spots can be simultaneously observed using the proposed endoscope.

Static behavior of stud shear connectors with initial damage in steel-UHPC composite bridges

  • Qi, Jianan;Tang, Yiqun;Cheng, Zhao;Xu, Rui;Wang, Jingquan
    • Advances in concrete construction
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    • v.9 no.4
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    • pp.413-421
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    • 2020
  • For steel-concrete girders made composite using shear studs, initial damage on studs induced by weld defect, unexpected overloading, fatigue and others might degrade the service performance and even threaten the structural safety. This paper conducted a numerical study to investigate the static behavior of damaged stud shear connectors that were embedded in ultra high performance concrete (UHPC). Parameters included damage degree and damage location. The material nonlinear behavior was characterized by multi-linear stress-strain relationship and damage plasticity model. The results indicated that the shear strength was not sensitive to the damage degree when the damage occurred at 2/3d (d is the stud diameter) from the stud root. An increased stud area would be engaged in resisting shear force as the distance of damage location from stud root increased and the failure section becomes inclined, resulting in a less reduction in the shear strength and shear stiffness. The reduction factor was proposed to consider the degradation of the shear strength of the damaged stud. The reduction factor can be calculated using two approaches: a linear relationship and a square relationship with the damage degree corresponding to the shear strength dominated by the section area and the nominal diameter of the damaged stud. It was found that the proposed method is preferred to predict the shear strength of a stud with initial damage.

A Piezo-driven Ultra-precision Stage for Alignment Process of a Contact-type Lithography (접촉식 리소그라피의 정렬공정을 위한 압전구동 초정밀 스테이지)

  • Choi, Kee-Bong;Lee, Jae-Jong;Kim, Gee-Hong;Lim, Hyung-Jun
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.20 no.6
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    • pp.756-760
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    • 2011
  • This paper proposed an alignment stage driven by piezo actuators for alignment process of a contact-type lithography. Among contact-type lithography processes, an UV-curable nanoimprint process is an unique process to be able to align patterns on upper and lower layers. An alignment stage of the UV-curable nanoimprint process requires nano-level resolution as well as high stiffness to overcome friction force due to contact moving. In this paper, the alignment stage consists of a compliant mechanism using flexure hinges, piezo actuators for high force generation, and capacitive sensors for high-resolution measurement. The compliant mechanism is implemented by four prismatic-prismatic compliant chains for two degree-of-freedom translations. The compliant mechanism is composed of flexure hinges with high stiffness, and it is directly actuated by the piezo actuators which increases the stiffness of the mechanism, also. The performance of the ultra-precision stage is demonstrated by experiments.

Simultaneous Analysis of Multi-residual pesticides using GC/NPD (GC/NPD를 이용한 다성분 잔류농약의 동시분석)

  • 김우성;이선화;김상엽;정동윤;김재이;이영자;이홍재;정성욱;박흥재
    • Journal of Environmental Science International
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    • v.12 no.10
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    • pp.1117-1120
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    • 2003
  • Pesticides were extracted from samples with 70% acetone and methylene chloride in order, and then cleaned up via open-column chromatography apparatus packed with florisil, and finally analyzed simultaneously the organophosphorus pesticides using GC/NPD. Ultra-2 and Ultra-1 fused silica capillary columns were used to separate and identify the products. Recovery of most analytes from soybean sample, taken from pesticide residues well, was greater than(80%) for all except(6) analytes. This method can simultaneously determine multiple pesticides with a high degree of accuracy and precision.