• Title/Summary/Keyword: type of a ring

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Theoretical Studies on the Progonation Equilibria of Benzoyl Derivatives

  • Kim, Wang Gi;Kim, Yong Bin;Kim, Chang Gon;Lee, Bon Su
    • Bulletin of the Korean Chemical Society
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    • v.22 no.4
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    • pp.395-400
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    • 2001
  • The effects of ortho- (R = H and CH3) and Y-substituents (Y = OCH3, CH3H and CN), which are directly attached to the carbonyl carbon, on the protonation equilibria of the para-X-substituted benzoyl derivatives, 4-X -2, 6-di-R-C6H2-C(=O)-Y, are investigated theoretically using the B3LYP method with 6-31+G* basis set. Structurally, both of the (B) and (BH+ ) forms in the species with R = H are nearly coplanar regardless of the Y-substituents implying that the steric repulsion between Y-substituent and R = H is relatively small. In the species with R = CH3 , the tortional angle (Θ) between the carbonyl moiety and aryl ring varies from zero to near right angle depending on the degree of steric repulsion between Y and R = CH3 and the resonance demand. However the reaction energies, ΔG°, for the protonation processes are more favorable for R = CH3 than for R = H due to stronger electron donating effect of R = CH3 , although the species with R = CH3 are unfavorable sterically. On the other hand, the Hammett type plots are progressively better correlated with б+ than with б values on going from Y = OCH3 to Y = CN for both species with R = H and CH3 indicating that the degree of resonance delocalization between carbonyl moiety and X-substituent is increased for a more electron accepting Y-substituent. Nevertheless the effects of R = CH3 on the magnitude of Hammett type reaction constants ( б or б+ ) are not much different from those of R = H.

Characteristic of Crack Growth and Progress on the Contact Fatigue (In a case of Metal) (접촉피로에 있어서 균열의 발생과 진전특성)

  • Yu, Seong-Geun
    • Korean Journal of Materials Research
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    • v.7 no.1
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    • pp.62-68
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    • 1997
  • In the first part of the paper, the crack growth process in rolling contact fatigue has been investigated on ring type plate specimens, in which crack growth is two dimensional and cracks are observed on the side surface of the specimens. The results have shown that cracks are initated from the contact surface in tensile mode in the direction approximately normal to the contact surface and after some short length of growth, shear mode growth occurs from the tip of the crack and it grows until the separation of the surface layer, namely flakung type failure, occurs. In the second part, mode U fatigue crack growth tests have been made by using an apparatus designed based on the concept that the subsurface fatigue crack growth in rolling contact fatigue is the mode U fatigue crack growth under the stress state where the tensile mode growth is suppressed by compression stress. The rest results have shown that the mode U fatigue crack growth occurs if the superposed compression stress is enough to suppress the tensile mode growth.

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Synthesis and Characterization of Liquid Crystalline Polyurethanes Containing Aromatic Ring Moiety (방향족 고리를 갖는 액정폴리우레탄의 합성 및 특성)

  • Lee, Jong-Baek
    • Elastomers and Composites
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    • v.48 no.2
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    • pp.141-147
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    • 2013
  • Polyurethanes containing no mesogenic unit were prepared by polyaddition reaction of homo- and copolyurethanes based on para-type 1,4-phenylene diisocyanate (1,4-PDI), 2,6-bis($\omega$-hydroxypentoxy)naphthalene (BHN5) with 1,4-bis($\omega$-hydroxypentoxy)benzene (BHB5). All copolyurethanes showed monotropic liquid crystallinity, when measurements were performed under shearing. For example, a polyurethane Poly(50/50, mol%) with $[\eta]$=0.32 dL/g exhibited liquid crystallinity in the temperature range from $223^{\circ}C$ to $211^{\circ}C$ in the cooling stage. In contrast, two homopolyurethanes exhibited no explicit mesomorphic behavior, which was observed by DSC (Differental Scanning calorimeter) and measurement and polarized microscopic observation. The mesomorphic behavior of synthesized polyurethane was identified and characterized by differential scanning calorimetry, polarized optical microscope and X-ray.

Development of the paper bagging machine for grapes (휴대용 포도자동결속기 개발연구)

  • Park, K.H.;Lee, Y.C.;Moon, B.W.
    • Journal of Practical Agriculture & Fisheries Research
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    • v.11 no.1
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    • pp.79-94
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    • 2009
  • The research project was conducted to develop a paper bagging machine for grape. This technology was aimed to highly reduce a labor for paper bagging in grape and bakery. In agriculture labor and farm population has rapidly decreased since 1980 in Korea so there was so limit in labor. In particular there is highly population in women and old age at rural area and thus labor cost is so high. Therefore a labor saving technology in agricultural sector might be needed to be replaced these old age with mechanical and labor saving tool in agriculture. The following was summarized of the research results for development of a paper bagging machine for grape. 1. Development of a new paper bagging machine for grape - This machine was designed by CATIA VI2/AUTO CAD2000 programme. - A paper bagging machine was mechanically binded a paper bag of grape which should be light and small size. This machine would be designed for women and old age with convenience during bagging work at the field site. - This machine was manufactured with total weight of less than 350g. - An overage bagging operation was more than 99% at the actual field process. - A paper bagging machine was designed with cartridge type which would be easily operated between rows and grape branches under field condition. - The type of cartridge pin was designed as a C-ring type with the length of 500mm which was good for bagging both grape and bakery. - In particular this machine was developed to easily operated among vines of the grape trees. 2. Field trials of a paper bagging machine in grape - There was high in grape quality as compared to the untreated control at the application of paper bagging machine. - The efficiency of paper bagging machine was 102% which was alternative tool for the conventional. - The roll pin of paper bagging machine was good with 5.3cm in terms of bagging precision. - There was no in grape quality between the paper bagging machine and the conventional method. - Disease infection and grape break was not in difference both treatments.

Evaluation of Tensile Properties of Alloy 690TT Steam Generator Tube at Room Temperature and 343℃ (상온과 343℃에서 Alloy 690TT 증기발생기 전열관의 인장물성치 평가)

  • Eom, Ki Hyeon;Kim, Jin Weon
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.38 no.6
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    • pp.655-662
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    • 2014
  • This study conducted tensile tests on an Alloy 690TT tube at room temperature (RT) and at $343^{\circ}C$ using tube- and ring-type specimens to investigate the stress-strain behavior and tensile properties of a steam generator (SG) tube in the axial and circumferential directions at RT and at the design temperature of a nuclear power plant (NPP). The results of the axial tensile test showed that yield point phenomena appeared at both RT and $343^{\circ}C$, and serrated flow in the stress-strain curve appeared at $343^{\circ}C$. Yield and tensile strengths for both directions were clearly lower at $343^{\circ}C$ compared to RT; however, the elongations were approximately the same at both test temperatures. Regardless of the test temperature, the strengths in the circumferential direction were lower by approximately 5~10 % than those in the axial direction. In addition, the test data revealed that the reduction in the yield and tensile strengths of the Alloy 690TT SG tube with the test temperature was more significant than that estimated by the temperature correction factor of ASME Sec.II.

A Study on Signal Analysis of the Data Aquisition System for Photosensor (데이터 획득장치에 이용되는 포토센서에 대한 DAS의 신호분석연구)

  • Hwang, InHo;Yoo, Sun Kook
    • Journal of rehabilitation welfare engineering & assistive technology
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    • v.10 no.3
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    • pp.237-242
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    • 2016
  • The major advantage of slip-ring technology in Spiral CT is that it facilitates continuous rotation of the x-ray tube, so that volume data can be acquired from a patient quickly. Not only for such a fast scan, but also for the dose reduction purpose, high signal-to-noise ratio and fast data acquisition system is required. In this study, we have built a multi-channel photodetector and multi-channel data acquisition system for CT application. The detector module consisted of CdWO4 crystal and Si photodiode in 16 channels. For the performance test of the preamplifier stage, both the transimpedance and switched integrator types are optimized for the photodetector modules. Switched integrator showed better noise performance in the limited bandwidth which is suitable for the current CT application. The control sequence for data acquisition and 20 bit ADC is designed with VHDL(Very High Speed Integrated Circuit Hardware Description Language) and implemented on FPGA(Field Programmable Gate Array) chip. Our Si photodiode detector module coupled to CdWO4 crystal showed comparable signal with other commercially available photodiode for CT. Switched integrator type showed higher SNR but narrower bandwidth compared to transimpedance preamplifier. Digital hardware is designed by FPGA, so that the control signal could be redesigned without hardware alteration.

A Study on the Modern Transformation on Public Residential Houses through the Changes of Plan Types (평면유형 변화로 본 공영단독주택의 근대적 변용)

  • Yoo, Jae-Woo
    • Journal of architectural history
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    • v.15 no.2
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    • pp.95-114
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    • 2006
  • This study was conducted on the premise that plan types of the public residential houses proposed after the 1945 implicatively showed the developing process of the modern housing. The formal characteristics created through the developing process were analyzed in Micro-Historically. Moreover, by providing a new viewpoint on the changes of the residential houses that occurred around 1945, we tried to provide the fundamental research background for the research on the developing processes of the future housing cultures. The research pursued mainly on the major spaces that became the modern change indices of housing plan changes from the traditional housings in 1940s to the modern housings such as the master bedrooms(An-Bang), kitchen, the main floored-space(Maru), and the secondary bedroom (Kune-Bang). The major experimental subjects are the 87 public residential plan types designed and supplied by the Korea Housing Cooperation in between 1945 and 1970. The study synthesized the developing process of the public residential houses from the traditional residential houses in 1940s through modern situation and intrusion of foreign housing cultures. Following results were derived from the study: First, various and experimental housing plan types had been proposed as public residential houses since 1945. Among them, the plan having the main floored-space(Maru) were the representative type of public residential houses and various series of houses were constructed based on this type. Second, the main floored-space(Maru) type had continued building connection order of the R-M-R that were used in the traditional houses. On the other hand, with decomposition of connecting ring between the main floored-space(Maru) and the kitchen, rationalization of women circulations and introduction of family-centered spaces had been resolved the demands of modern society. It had greate effect on settlement of the current double-row Maru plan type. Third, in Korea most of plan types for the public residential houses were proposed in between 1945 and 1965. Forth, the location of kitchen and relation between Maru and the master bedroom were arranged visually on the corner and center of the rear row with the micro change characteristics of the public residential houses. In this process, the front row was similar with traditional residential houses but the rear row was differentiated and developed with expansion of Maru and Ondol rooms, increase of closet spaces, and introduction of kitchen that divided spaces for sleeping and eating.

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The Effect of Barrel Vibration Intensity to the Plating Thickness Distribution

  • Lee, Jun-Ho;Roselle D. Llido
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 1999.10a
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    • pp.15-15
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    • 1999
  • In chip plating, several parameters must be taken into consideration. Current density, solution concentration, pH, solution temperature, components volume, chip and media ratio, barrel geometrical shape were most likely found to have an effect to the process yields. The 3 types of barrels utilized in chip plating industry are the conventional rotating barrel. vibrational barrel (vibarrel), and the centrifugal type. Conventional rotating barrel is a close type and is commonly used. The components inside the barrel are circulated by the barrel's rotation at a horizontal axis. Process yield has known to have higher thickness deviation. The vibrational barrel is an open type which offers a wide exposure to electrolyte resulting to a stable thickness deviation. It rotates in a vertical axis coupled with multi-vibration action to facilitate mixed up and easy transportation of components, The centrifugal barrel has its plated work centrifugally compacted against the cathode ring for superior electrical contact with simultaneous rotary motion. This experiment has determined the effect of barrel vibration intensity to the plating thickness distribution. The procedures carried out in the experiment involved the overall plating process., cleaning, rinse, Nickel plating, Tin-Lead plating. Plating time was adjusted to meet the required specification. All other parameters were maintained constant. Two trials were performed to confirm the consistency of the result. The thickness data of the experiment conducted showed that the average mean value obtained from higher vibrational intensity is nearer to the standard mean. The distribution curve shown has a narrower specification limits and it has a reduced variation around the target value, Generally, intensity control in vi-barrel facilitates mixed up and easy transportation of components, However, it is desirable to maintain an optimum vibration intensity to prevent solution intrusion into the chips' internal electrode. A cathodic reaction can occur in the interface of the external and internal electrode. $2HD{\;}+{\;}e{\;}{\rightarrow}20H{\;}+{\;}H_2$ Hydrogen can penetrate into the body and create pressure which can cause cracks. At high intensity, the chip's motion becomes stronger, its contact between each other is delayed and so plating action is being controlled. However, the strong impact created by its collision can damage the external electrode's structure thereby resulting to bad plating condition. 1 lot of chip was divided into two equal partion. Each portion was loaded to the same barrel one after the other. Nickel plating and tin-lead plating was performed in the same station. Portion A maintained the normal barrel vibration intensity and portion B vibration intensity was increased two steps higher. All other parameters, current, solution condition were maintained constant. Generally, plating method find procedures were carried out in a best way to maintained the best plating condition. After plating, samples were taken out from each portion. molded and polished. Plating thickness was investigated for both. To check consistency of results. 2nd trial was done now using different lot of another characteristics.

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Classification of Fishing Gear (어구의 분류)

  • 김대안
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.32 no.1
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    • pp.33-41
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    • 1996
  • In order to obtain the most favourable classification system for fishing gears, the problems in the existing systems were investigated and a new system in which the fishing method was adopted as the criterion of classification and the kinds of fishing gears were obtained by exchanging the word method into gear in the fishing methods classified newly for eliminating the problems was established. The new system to which the actual gears are arranged is as follows ; (1)Harvesting gear \circled1Plucking gears : Clamp, Tong, Wrench, etc. \circled2Sweeping gears : Push net, Coral sweep net, etc. \circled3Dredging gears : Hand dredge net, Boat dredge net, etc. (2)Sticking gears \circled1Shot sticking gears : Spear, Sharp plummet, Harpoon, etc. \circled2Pulled sticking gears : Gaff, Comb, Rake, Hook harrow, Jerking hook, etc. \circled3Left sticking gears : Rip - hook set line. (3)Angling gears \circled1Jerky angling gears (a)Single - jerky angling gears : Hand line, Pole line, etc. (b)Multiple - jerky angling gears : squid hook. \circled2Idly angling gears (a)Set angling gears : Set long line. (b)Drifted angling gears : Drift long line, Drift vertical line, etc. \circled3Dragged angling gears : Troll line. (4)Shelter gears : Eel tube, Webfoot - octopus pot, Octopus pot, etc. (5)Attracting gears : Fishing basket. (6)Cutoff gears : Wall, Screen net, Window net, etc. (7)Guiding gears \circled1Horizontally guiding gears : Triangular set net, Elliptic set net, Rectangular set net, Fish weir, etc. \circled2Vertically guiding gears : Pound net. \circled3Deeply guiding gears : Funnel net. (8)Receiving gears \circled1Jumping - fish receiving gears : Fish - receiving scoop net, Fish - receiving raft, etc. \circled2Drifting - fish receiving gears (a)Set drifting - fish receiving gears : Bamboo screen, Pillar stow net, Long stow net, etc. (b)Movable drifting - fish receiving gears : Stow net. (9)Bagging gears \circled1Drag - bagging gears (a)Bottom - drag bagging gears : Bottom otter trawl, Bottom beam trawl, Bottom pair trawl, etc. (b)Midwater - drag gagging gears : Midwater otter trawl, Midwater pair trawl, etc. (c)Surface - drag gagging gears : Anchovy drag net. \circled2Seine - bagging gears (a)Beach - seine bagging gears : Skimming scoop net, Beach seine, etc. (b)Boat - seine bagging gears : Boat seine, Danish seine, etc. \circled3Drive - bagging gears : Drive - in dustpan net, Inner drive - in net, etc. (10)Surrounding gears \circled1Incomplete surrounding gears : Lampara net, Ring net, etc. \circled2Complete surrounding gears : Purse seine, Round haul net, etc. (11)Covering gears \circled1Drop - type covering gears : Wooden cover, Lantern net, etc. \circled2Spread - type covering gears : Cast net. (12)Lifting gears \circled1Wait - lifting gears : Scoop net, Scrape net, etc. \circled2Gatherable lifting gears : Saury lift net, Anchovy lift net, etc. (13)Adherent gears \circled1Gilling gears (a)Set gilling gears : Bottom gill net, Floating gill net. (b)Drifted gilling gears : Drift gill net. (c)Encircled gilling gears : Encircled gill net. (d)Seine - gilling gears : Seining gill net. (e)Dragged gilling gears : Dragged gill net. \circled2Tangling gears (a)Set tangling gears : Double trammel net, Triple trammel net, etc. (b)Encircled tangling gears : Encircled tangle net. (c)Dragged tangling gears : Dragged tangle net. \circled3Restrainting gears (a)Drifted restrainting gears : Pocket net(Gen - type net). (b)Dragged restrainting gears : Dragged pocket net. (14)Sucking gears : Fish pumps.

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Time-encoded Near-infrared (NIR) Spectroscopic Comparison of Absorbance Measurement Using an Acousto-optic NIR Swept Laser Source (음향광학 파장선택 필터 기반 파장훑음 레이저를 이용한 시간-인코딩 된 근적외선 흡광도 측정 비교 연구)

  • Jang, Hansol;Kim, Gyeong Hun;Han, Ga-Hee;Cho, Jaedu;Kim, Chang-Seok
    • Korean Journal of Optics and Photonics
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    • v.28 no.1
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    • pp.22-27
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    • 2017
  • Time-encoded near-infrared spectroscopy (NIRS) system is proposed, based on a near-infrared (NIR) swept laser source, for comparison to the conventional NIRS method using a detector-type spectrometer. The cavity of the NIR swept laser source consists of a semiconductor optical amplifier (SOA) with a gain region around 800 nm, and several fiber-optic components. To change the output wavelength in time using an applied electric radio-frequency signal, an acousto-optic tunable filter (AOTF) is introduced in the fiber ring cavity configuration. To demonstrate the feasibility of an NIR swept laser source for NIRS imaging, the spectroscopic comparison of two kinds of absorbance-measuring systems a detector-type spectrometer using a white light source, and a source-type spectrometer using an NIR swept laser is successfully performed with an NIR-absorbing dye.