• Title/Summary/Keyword: two temperatures theory

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Constitutive Analysis of the High-temperature Deformation Behavior of Two Phase Ti-6Al-4V Near-α Ti-6.85Al-1.6V and Single Phase-α Ti-7.0Al-1.5V Alloy (2상 Ti-6Al-4V 합금, 준단상 Ti-6.85Al-1.6V 및 단상 Ti-7.0Al-1.5V 합금의 고온 변형거동에 관한 연구)

  • Kim Jeoung Han;Yeom Jong Taek;Park Nho Kwang;Lee Chong Soo
    • Transactions of Materials Processing
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    • v.14 no.8 s.80
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    • pp.681-688
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    • 2005
  • The high-temperature deformation mechanisms of a ${\alpha}+{\beta}$ titanium alloy (Ti-6Al-4V), near-a titanium alloy (Ti-6.85Al-1.6V) and a single-phase a titanium alloy (Ti-7.0Al-1.5V) were deduced within the framework of inelastic-deformation theory. For this purpose, load relaxation tests were conducted on three alloys at temperatures ranging from 750 to $950^{\circ}C$. The stress-versus-strain rate curves of both alloys were well fitted with inelastic-deformation equations based on grain matrix deformation and grain-boundary sliding. The constitutive analysis revealed that the grain-boundary sliding resistance is higher in the near-${\alpha}$ alloy than in the two-phase ${\alpha}+{\beta}$ alloy due to the difficulties in relaxing stress concentrations at the triple-junction region in the near-${\alpha}$ alloy. In addition, the internal-strength parameter (${\sigma}^*$) of the near-${\alpha}$ alloy was much higher than that of the ${\alpha}+{\beta}$ alloy, thus implying that dislocation emission/ slip transfer at ${\alpha}/{\alpha}$ boundaries is more difficult than at ${\alpha}/{\beta}$ boundaries.

Design of a Solar Thermal Storage System Employing Heat Pipes and Molten Salts (히트파이프와 용융염을 사용하는 태양열 축열조의 설계)

  • Lee, Jung-Ryun;Boo, Joon-Hong
    • 한국태양에너지학회:학술대회논문집
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    • 2011.04a
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    • pp.86-91
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    • 2011
  • Thermal design was conducted for a solar thermal storage system in a medium-temperature range between $200^{\circ}C$ and $400^{\circ}C$. The system was composed of heat pipes as heat carrier and molten salts as phase-change storage material. Each heat pipe penetrated through the storage system and had two heat-exchanging sections at both ends to interact with high-and low-temperature steams, while it exchanged heat with molten salts in the middle section. During a heat-storage mode, the heat pipes transferred heat from the hot steam at one side to the molten salts and it transferred heat from the molten salt to the cold steam at the other side during the heat-dissipating mode. A tube-bank type heat exchanger theory was applied to this design task to meet the required inlet and outlet temperatures of the steams depending on the operation modes. Several design variables were considered including the lengths of evaporator and condenser of a heat pipe, traverse and longitudinal pitches of the pipe, and the number of rows of the heat pipes for two different molten salt baths. An optimum design results were presented with discussion.

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Evaluation of Thermal Conductivity for Grout/Soil Formation Using Thermal Response Test and Parameter Estimation Models (열응답 시험과 변수 평가 모델을 이용한 그라우트/토양 혼합층의 열전도도 산정)

  • Sohn Byong Hu;Shin Hyun Jun;An Hyung Jun
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.17 no.2
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    • pp.173-182
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    • 2005
  • The Performance of U-tube ground heat exchanger for geothermal heat Pump systems depends on the thermal properties of the soil, as well as grout or backfill materials in the borehole. In-situ tests provide a means of estimating some of these properties. In this study, in-situ thermal response tests were completed on two vertical boreholes, 130 m deep with 62 mm diameter high density polyethylene U-tubes. The tests were conducted by adding a monitored amount of heat to water over a $17\~18$ hour period for each vertical boreholes. By monitoring the water temperatures entering and exiting the loop and heat load, overall thermal conductivity values of grout/soil formation were determined. Two parameter estimation models for evaluation of thermal response test data were compared when applied on the same temperature response data. One model is based on line-source theory and the other is a numerical one-dimensional finite difference model. The average thermal conductivity deviation between measured data and these models is of the magnitude $1\%$ to $5\%$.

The Free Energy of Mixing for a Binary Lattice Solution Consisting of Two Identical Interpenetrating Sublattices (두개의 동등한 상호침투 부격자로 구성된 이성분 격자 용액의 혼합자유에너지)

  • Jung, Hae-Young
    • Journal of the Korean Chemical Society
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    • v.66 no.4
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    • pp.278-283
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    • 2022
  • Using the Kirkwood's method, the free energy of a binary lattice solution consisting of two identical interpenetrating sublattices, such as a simple cubic lattice or a body-centered cubic lattice, was calculated up to the tenth order of the reciprocal of absolute temperature. Using this, liquid-liquid coexistence curves and critical solution temperatures for the binary lattice solutions were calculated to quantitatively investigate the effect of non-random mixing of molecules. And it was shown that the coexistence curve of the simple cubic lattice solution was in good agreement with the Monte-Carlo computer simulation result.

Mechanical Stability Analysis of PCB and Component for Launch and On-orbit Environment based on Fatigue Failure Theory and FEM (피로파괴 이론과 FEM에 기초한 발사 및 궤도 환경에서의 기판 및 소자의 구조건전성 분석)

  • Jeong, Suk-Yong;Oh, Hyun-Ung;Lee, Kyung-Joo;Kim, Byoung-Soo
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.39 no.10
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    • pp.952-958
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    • 2011
  • On-board IR calibration device has been developed for calibration of spaceborne image sensor. It is composed of a blackbody to provide two different radiance temperatures, tilt mirror with a function of stow and deploy to view the blackbody during the calibration and on-board calibration control unit to control the function of the blackbody and tilt mirror. In this paper, to guarantee the structural safety of the unit, the structural and thermal analysis including a thermo-elastic analysis for verifying structural safety on the soldered part of chips have been performed. In addition, safety margin of the chips on the PCB obtained from the conventional analytical method has been compared to the results from the FEM analysis.

Electronic Spectroscopy and Ligand Field Analysis of cis-$>[Cr(cycb)Cl_2]$Cl

  • Choi, Jong-Ha;Oh, In-Gyung;Subodh Kumar;Ryoo, Keon-Sang
    • Journal of Photoscience
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    • v.11 no.1
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    • pp.19-23
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    • 2004
  • The sharp-line absorption spectrum of microcrystalline samples of cis-[Cr(cycb)$Cl_2$]Cl (cycb=rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane) has been measured between 13000 and $16000 cm^{-1}$ at temperatures down to 5K. The 77K emission and excitation spectra, and 298 K infrared and visible absorption spectra have also been measured. The nine electronic bands due to spin-allowed and spin-forbidden transitions were assigned. Using the observed transitions, a ligand field analysis has been performed to probe the ligand field properties of coordinated atoms in the title chromium(III) complex. The zero-phonon line in the sharp-line absorption spectrum splits into two components by $240 cm^{-1}$ , and the $large ^2$$_E{g}$ splitting can be reproduced by the modem ligand field theory. It is confirmed that nitrogen atoms of the macrocyclic cycb ligand have a strong $\sigma$-donor character, but chloride ligand has weak $\sigma$- nd $\pi$-donor properties toward chromium(III) ion.n.

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PERFORMANCE EVALUATION OF BUBBLE PUMP USED IN A PASSIVE SOLAR WATER HEATER SYSTEM

  • Xuesong, Li;Park, Gi-Tae;Chung, Han-Shik;Jeong, Hyo-Min
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.2309-2314
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    • 2007
  • The application analysis of bubble pump on the domestic solar water heater system is presented. The system investigated in this study is a passive device, self pumping and self regulating. It was test to use the bubble pump on solar water heater system. The test experiment has been taken on the existed vacuum tube about the efficiency, working fluid temperature and pressure and circulated power. In order to check the working temperature and working pressure effectively, the bubble pump was test separated from the solar water heater. The equipment consists of the bubble pump, heater and heat exchanger. The main structure of bubble pump was design depend on the character of two phase flow. The complete system was instrumented to measure pressures, temperatures and flow-rates at various locations. The theory analysis of design bubble pump has been given and the experiment design has been included in the paper.

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Thermohydrodynamic Analysis and Pad Temperature Measurement of a Tilting Pad Journal Bearing for a Turbine Simulator (터빈 시뮬레이터용 틸팅패드 저널베어링의 열윤활 해석 및 패드 온도 측정)

  • Lee, Donghyun;Sun, Kyungho
    • Tribology and Lubricants
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    • v.33 no.3
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    • pp.112-118
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    • 2017
  • Tilting pad journal bearings(TPJBs) are widely used for high speed rotating machinery owing to their rotordynamic stability and thermal management feature. With increase in the rotating speed of such machinery, an increasingly important aspect of TPJB design is the prediction of their thermal behaviors. Researchers have conducted detailed investigations in the last two decades, which provided design tools for the TPJBs. Based on these previous studies, this paper presents a thermohydrodynamic(THD) analysis model for TPJBs. To calculate pressure distribution, we solve the generalized Reynolds equation and to predict the lubricant temperature, we solve the 3D energy equation. We employ the oil mixing theory to calculate pad inlet temperature; further, to consider heat conduction via the pad, we solve the heat conduction equation for the pads. We assume the shaft temperature as the averaged oil film temperature and apply natural convection boundary conditions to the pad side and back surfaces. To validate the analysis model, we compare the predicted pad temperatures with those from previous research. The results show good agreement with previous research. In addition, we conduct parametric studies on a TPJB which was used in a gas turbine simulator system. The predicted results show that film temperature largely depends on the rotating speed and oil supply condition.

Conformational Lock and Dissociative Thermal Inactivation of Lentil Seedling Amine Oxidase

  • Moosavi-Nejad, S. Zahra;Moosavi-Movahedi, Ali-Akbar;Rezaei-Tavirani, Mostafa;Floris, Giovanni;Medda, Rosaria
    • BMB Reports
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    • v.36 no.2
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    • pp.167-172
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    • 2003
  • The kinetics of thermal inactivation of copper-containing amine oxidase from lentil seedlings were studied in a 100 mM potassium phosphate buffer, pH 7, using putrescine as the substrate. The temperature range was between $47-60^{\circ}C$. The thermal inactivation curves were not linear at 52 and $57^{\circ}C$; three linear phases were shown. The first phase gave some information about the number of dimeric forms of the enzyme that were induced by the higher temperatures using the "conformational lock" pertaining theory to oligomeric enzyme. The "conformational lock" caused two additional dimeric forms of the enzyme when the temperature increased to $57^{\circ}C$. The second and third phases were interpreted according to a dissociative thermal inactivation model. These phases showed that lentil amine oxidase was reversibly-dissociated before the irreversible thermal inactivation. Although lentil amine oxidase is not a thermostable enzyme, its dimeric structure can form "conformational lock," conferring a structural tolerance to the enzyme against heat stress.

Corrosion Inhibition of Copper-nickel Alloy: Experimental and Theoretical Studies

  • Khadom, Anees A.;Yaro, Aprael S.;Musa, Ahmed Y.;Mohamad, Abu Bakar;Kadhum, Abdul Amir H.
    • Journal of the Korean Chemical Society
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    • v.56 no.4
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    • pp.406-415
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    • 2012
  • The corrosion inhibition of copper-nickel alloy by Ethylenediamine (EDA) and Diethylenetriamine (DETA) in 1.5M HCl has been investigated by weight loss technique at different temperatures. Maximum value of inhibitor efficiency was 75% at $35^{\circ}C$ and 0.2 M inhibitor concentration EDA, while the lower value was 4% at $35^{\circ}C$ and 0.01 M inhibitor concentration DETA. Two mathematical models were used to represent the corrosion rate data, second order polynomial model and exponential model respectively. Nonlinear regression analysis showed that the first model was better than the second model with high correlation coefficient. The reactivity of studied inhibitors was analyzed through theoretical calculations based on density functional theory (DFT). The results showed that the reactive sites were located on the nitrogen (N1, N2 and N4) atoms.