• 한국공작기계학회:학술대회논문집
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• 한국공작기계학회 2005년도 춘계학술대회 논문집
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• pp.407-412
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• 2005

For micro electrochemical machining (ECM), tool electrodes with various sizes and shapes are necessary. In this paper, tool electrodes were fabricated by micro electrical discharge machining (EDM). Electrode material is tungsten carbide which has high rigidity and good conductivity for micro electrochemical machining. Disk-type and sphere-type electrodes were fabricated to prevent taper shape of side walls or to produce spherical features. Various 3D micro structures were fabricated by electrochemical milling with developed electrodes.

• Journal of Electrochemical Science and Technology
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• 제14권1호
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• pp.75-84
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• 2023

The accumulation of spent carbide (YG8), not only pollutes the environment but also causes waste of tungsten, cobalt and other rare metal resources. To better address this issue, we proposed a combined electrochemical separation process of low-temperature aqueous solution and high-temperature molten salt for tungsten and cobalt. H₂WO₄ was obtained from spent carbide in an aqueous solution, and we calcined it to obtain WO₃, which was used as a raw material to obtain tungsten by using molten salt electrodeposition. The influence of the current efficiency and the electrochemical behavior of the discharge precipitation of W(VI) were also studied. The calcination results showed that the morphology of WO₃ was regular and there were no other impurities. The maximum current efficiency of 82.91% was achieved in a series of electrodeposition experiments. According to XRD and SEM analysis, the recovered product was high purity tungsten, which belongs to the simple cubic crystal system. In the W(VI) reduction mechanism experiments, the electrochemical process of W(VI) in NaCl-Na₂WO₄-WO₃ molten salt was investigated using linear scanning voltammetry (LSV) and chronoamperometry in a three-electrode system. The LSV showed that W(VI) was reduced at the cathode in two steps and the electrode reaction was controlled by diffusion. The fitting results of chronoamperometry showed that the nucleation mechanism of W(VI) was an instantaneous nucleation mode, and the diffusion coefficient was 7.379×10^-10 cm²·s^-1.

• 한국생산제조학회지
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• 제19권3호
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• pp.370-375
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• 2010

본 연구에서는 전해가공을 이용해서 직경이 균일한 텅스텐 카바이드 미세축을 제작하는 실험을 수행하였다. 전해가공을 통해 미세축으로 사용 가능한 형상을 얻기 위한 최적의 가공 조건에 대해 고찰하였다 이 과정에서 미세축의 형상에 영향을 주는 여러 인자들을 적절하게 조절하여 최적의 형상을 얻을 수 있었다. 그리고 가공된 미세축을 이용하여 적절한 조건으로 2차, 3차 가공을 수행하여 초미세축을 가공할 수 있음을 보였다. 그리하여 실험 결과 직경 $30{\mu}m$, 길이 $500{\mu}m$의 텅스텐 카바이드 미세축을 제작하였다.

• 한국입자에어로졸학회지
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• 제13권1호
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• pp.11-16
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• 2017

Indoor air quality is of increasing concern because it is closely related human health. An air handling unit (AHU) can be used to control the indoor air quality related to particulate matters and $CO_2$ as well as air conditioning such as temperature and humidity of indoor air. An electrostatic precipitator has a high collection efficiency and low pressure drop, however, ozone can possibly generate from its chargers, which is one of drawbacks to apply it for indoor air control. Here we compared four charging electrodes such as a $50{\mu}m$ tungsten wire, a $100{\mu}m$ tungsten wire, a $16{\mu}m$-thickness Al foil and a carbon fabric comprised of $5-10{\mu}m$ fibers. The carbon fabric electrode showed a superior particle collection efficiency and a lower ozone generation at a given power consumption compared to tungsten wires of 50, $100{\mu}m$ and an Al foil electrode. This low ozone generating, micro-sized electrode can be applied to the electrostatic precipitator in AHU for indoor air control.

• 대한화학회지
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• 제38권12호
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• pp.885-890
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• 1994

텅스텐 전극을 작업전극으로 사용하여 산성수용액에서 아닐린의 전기화학적 중합을 순환 전압-전류법으로 연구하였다. 아닐린 분자는 2전자 전이에 의하여 탈수소 아닐린이온으로 산화하고, 중성아닐린을 공격하여 중합체를 만든다. 그러나 백금전극의 경우와는 다르게 중합과정은 주로 아닐린의 산화에 의해서 일어난다. 성장속도는 백금전극의 경우와 비교하여 느린 것으로 나타났다. 분해생성물은 벤조퀴논이 아니라 p-phenylenediamine(p-PDA)으로 확인 되었는데 이것은 1.0 V 이하의 전위에서 p-PDA의 산화가 관측되지 않은 결과와도 일치한다.

• 한국입자에어로졸학회지
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• 제14권3호
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• pp.81-88
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• 2018

The market for improving the indoor air quality is continuously increasing, and air cleaners are the representative products. As interest in indoor air quality increases, so are the ultrafine particle which are harmful to the human body. Despite its many advantages, electrostatic precipitators are less used in indoor air due to ozone production. In this study, the carbon fiber sheet was applied to the discharge electrode and compared with the conventional tungsten wire discharge electrode. The particle collection efficiency and the amount of ozone generation were measured for 10-100 nm particles. Furthermore, it was applied to commercial air purifier with electrostatic precipitator to compare particle removal performance. The carbon fiber sheet type discharge electrode generates a small amount of ozone, and thus it can be applied to improve indoor air quality.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2003년도 춘계학술대회 논문집
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• pp.682-685
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• 2003

In this paper, we propose the method to measure the Young's modulus of carbon nano tube which was manufactured by chemical vapor deposition. We also made the tungsten tip by electrochemical etching process and the carbon nano tube which was detangled through ultra-sonication with isopropyl alcohol was attached to the tungsten tip. This tip which was composed of tungsten tip and carbon nano tube can be used in Young's modulus measurement by applying DC voltage with counter electrode. The attachment process and measurement of the deflection of carbon nano tube was done under optical microscope.

• 한국정밀공학회지
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• 제19권3호
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• pp.80-87
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• 2002

Tungsten carbide microshaft is used as micro-punch, electrode of MEDM (micro-electro-discharge machining), and micro-tool because it has high hardness and high rigidity. In this study, the tungsten carbide microshaft was fabricated using electrochemical machining. Concentration of material removal at the sharp edge and metal corrosion layer affect the shape of the microshaft. Control of microshaft shape was possib1e through conditioning the machining voltage and electrolyte concentration. By applying periodic voltage, material removal rate increased and surface roughness improved. The fabricated microshaft in $H_2 SO_4$ electrolyte maintained sharper end edge and better surface finish than those fabricated by other electrolytes.

• 한국표면공학회지
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• 제30권2호
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• pp.121-127
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• 1997

Vanadium tungsten oxide thin films were formed by RF magnetron sputtering and the effects of tungsten addition on the crystallinity and on the electrochemical behavior were investigated. X-ray analysis revealed that amorphized films could be obtained by tungase addition. In order to investigate the electrochemical behavior of the vanadium tungsten oxide films, electrochemical insertion and extraction of lithium were out in 1m $LiCIO_4$-PC-DME electrolyte using litium metal as a counter electrode. When the tungsten was added to the $V_2O_5$ films, cycling reversibility was considerably improved. Electrochemical test showed the cell capacity of about $70\mu\;Ah/\textrm{cm}^2-\mu\textrm{m}$ when the amount of additive tungseten reached 30 atomic percent. No appreciable degradation of the cell capacity could be observed after hundred cycles of insertion and extration od Li.

• 한국재료학회지
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• 제10권9호
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• pp.624-628
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• 2000

표면 탄성과 디바이스의 전극재료로 사용되는 Al-%Cu(4000$\AA$)/tungsten nitride 박막을 magnetron sputtering 법으로 제조하고 전기저항을 평가한 비정질상의 tungsten nitride 박막을 제조할 수 있었고, 비정질 형성을 위해 질소비(R =$N_2$/(Ar+$N_2$)가 10~40% 정도 필요하다. Tungsten nitride 박막의 잔류응력은 비정질이 형성되면서 급격히 감소되었다. 이러한 비정질 박막위에 Al-1%Cu 합금막이 형성되었다. 다층막은 453K에서 4시간 동안 열처리함으로써 $3.6{\mu}{\Omega}-cm$의 저항을 나타냈는데, 이는 박막내 결정립 성장과 결함의 감소에 기인하였다.