• Proceeding of EDISON Challenge
• /
• 2014.03a
• /
• pp.251-262
• /
• 2014

최근 유기 발광 다이오드(Organic Light Emitting Diodes; OLED)가 각광받고 있어 이를 개발하기 위한 좀 더 효율적이고 실용적인 OLED 구조의 예측이 필요해지고 있다. 본 연구는 가장 기초적인 OLED dye의 형태인 $Ru(bpy){_3}^{2+}$와 그와 유사한 구조의 발광 물질이 전기화학발광(ECL) 현상을 통해 방출하는 빛의 특성을 계산하는 것을 목적으로 한다. EDISON 화학 서버의 GAMESS 프로그램을 사용하여 $Ru(bpy){_3}^{2+}$와 유도체들의 바닥상태(ground state)와 첫 번째 들뜬 상태(first excited state)를 계산하였다. Basis set으로는 MINI와 3-21G 혹은 SBKJC를 사용하였다. 들뜬 상태 계산은 configuration interaction with single excitation(CIS)을 이용하여 단일항(singlet)과 삼중항(triplet) 상태에서 바닥과 들뜬 상태의 최적 구조에 대한 계산을 수행하였다. 다양한 방법으로 방출 파장을 계산한 결과를 바탕으로 $Ru(bpy){_3}^{2+}$와 다양한 유도체들의 에너지 계산에 어떤 방법이 효율적으로 적용될 수 있을지 탐색하였다. 같은 계산방법들이 중심 금속이 이리듐(Ir)인 분자에도 적용이 될 수 있을지 알아보기 위해 $lr(mppy)_3$에도 적용하였다. 본 연구를 통하여 얻어진 방식은 시간을 절약하고 더 효율적인 $Ru(bpy){_3}^{2+}$ 유도체 계산에도 사용할 수 있을 것이다.

• Bulletin of the Korean Chemical Society
• /
• v.34 no.11
• /
• pp.3350-3356
• /
• 2013

Quasi-classical trajectory calculations have been carried out for the reaction H+HS by using the newest triplet 3A" potential energy surface (PES). The effects of the collision energy and reagent initial rotational excitation are studied. The cross sections and thermal rate constants for the title reaction are calculated. The results indicate that the integral cross sections (ICSs) are sensitive to the collision energy and almost independent to the initial rotational states. The ro-vibrational distributions for the product $H_2$ at different collision energies are presented. The investigations on the vector correlations are also performed. It is found that the collision energies play a postive role on the forward scatter of the product molecules. There is a negative influence on both the alignment and orientation of the product angular momentum for low collision energy at low energy region. Whereas the influence of collision energy is not obvious at high energy region.

• Journal of the Korean Chemical Society
• /
• v.21 no.6
• /
• pp.434-439
• /
• 1977

The electronic structures of 4-pyridone and lutidone are studied by the SCF MO-CI PPP method and by the configuration analysis method. The spectral data are consistent with the values calculated by the method. The polarization of $S_1({\pi},{\pi}^*)$ state is along the long molecular axis in both compounds. The lowest $({\pi},{\pi}^*)$1 state shows significant charge transfer (16∼18%) from ${\pi}$ bonding orbital of C=O moiety to ${\pi}^*$ antibonding orbital of divinyl amine moiety. The lowest triplet state shows much larger charge transfer (24∼29 %) but in opposite direction compared to that of $S_1({\pi},{\pi}^*)$ state.

• 한국정보디스플레이학회:학술대회논문집
• /
• 2009.10a
• /
• pp.843-845
• /
• 2009

A polymeric host for triplet emitters composed of N-alkylcarbazole and tetramethylbenzene units was successfully synthesized. Efficient energy transfer was observed between this polymeric host and green phosphorescent dyes. The device fabricated using 5 wt% green 1 in the polymeric host as the emitting layer showed the best performance. Thin films of this host-guest system, exhibiting clear stripe patterns could be prepared through the LITI process. The patterned films were then used to fabricate electrophosphorescent devices, which show performance characteristics similar to those of spin-coated devices. The new host material is a good candidate to be used in polymer-based full-color electrophosphorescent light-emitting displays.

• Transactions on Electrical and Electronic Materials
• /
• v.10 no.6
• /
• pp.208-211
• /
• 2009

The authors have demonstrated the various characteristics of hybrid white organic light-emitting diodes (HWOLED) using fluorescent blue and phosphorescent red emitters. We also demonstrated that two devices showed different characteristics in accordance with thickness of the 4,4′-N,N′-dicarbazole-biphenyl (CBP) spacer (CS) inserted between the blue and the red emitting layer. It was found that the device with a CS thickness of 70 $\AA$ showed a current efficiency 2.5 times higher than that of the control device with a CS thickness of 30 $\AA$ by preventing the triplet Dexter energy transfer from the red to the blue emitting layer. The HWOLED with the CS thickness of 70 $\AA$ exhibited a maximum luminance of 24500 cd/$m^2$, a maximum current efficiency of 42.9 cd/A, a power efficiency of 37.5 lm/W, and Commission Internationale de I'Eclairage coordinates of (0.37, 0.42).

• Clinical and Experimental Reproductive Medicine
• /
• v.17 no.2
• /
• pp.145-151
• /
• 1990

This study was carried out to elevating the pregnancy rate in infertile patient by Gamete intrafallopian transfer (GIFT). The GIFT program was performed from July 1988 to June 1990. Of the 131 cycles, the mean age of patient was 31.6 years and the mean duration of infertility was 5.3 years. 41 patients became pregnant, for a pregnancy rate of 31.3%. 5 preclinical abortions and 6 clinincal abortion was occured. 2 ectopic pregnanices and 1 combined pregnancy were occured. 7 twin pregnancies and 1 triplet were occured (multiple pregnancy rate;22.2%). 11 pregnancies were term delivered, 17 are ongoing pregnancies. GIFT may be considered as an alternative to in vitro fertilazation in infertility cases in which at least one fallopian tube is patent.

• The Bulletin of The Korean Astronomical Society
• /
• v.37 no.2
• /
• pp.167.2-167.2
• /
• 2012

경희대학교와 UC Berkeley, Imperial College London에서 공동으로 진행하는 TRIO-CINEMA Mission(TRiplet Ionosphere Observatory-Cubesat for Ion, Neutral, Electron and MAgnetic fields)은 총 3기의 초소형 위성으로 구성되어 있다. 3기의 위성은 고도 650~800km 상공의 태양동주기 궤도운동을 예상하고 있으며, 지구 근접공간의 입자 검출과 자기장 측정의 과학 임무를 맡게 된다. TRIO-CINEMA 비행 모델(Flight Model)의 환경시험은 진동시험과 열진공시험으로 진행되었다. 진동시험은 X, Y, Z 세 축에 대해 Sine 과 Random 모드로 진행되었다. TRIO-CINEMA가 탑재 될 러시아의 드네프르 로켓의 요구사항은 각 축에서 20Hz 이상의 고유진동수, Sine의 경우 최대 0.8G와 4oct/min Sweep Rate, Random의 경우 5.2Grms 와 35초의 지속시간에서의 안정성을 만족하는 것이다. 시험 결과 TRIO-CINEMA가 요구사항을 모두 만족시키는 것을 확인하였다. 또한, 열 주기 시험(Thermal Cycling Test)을 진행하여 우주공간에서 위성 시스템이 정상 동작하는지에 대한 신뢰성을 검증하였다. 열주기 시험은 미국 MIL표준 값을 참고하여 $10^{-6}Torr$에서 $-20{\sim}30^{\circ}C$의 온도를 주었으며, 시험을 진행하는 동안과 시험 후에 위성이 정상작동 함을 확인하였다. 이에 본 연구의 시험 방법과 그 결과를 기술하였다.

• The Bulletin of The Korean Astronomical Society
• /
• v.37 no.2
• /
• pp.75.1-75.1
• /
• 2012

Narrow-Line Seyfert 1 galaxies are arguably the most important AGN subclass in investigating the origin of the black hole mass-galaxy stellar velocity dispersion (MBH-${\sigma}$) relation because of their high accretion rates close to the Eddington limit. Currently, it is still under discussion whether NLS1s are off from the local MBH-${\sigma}$ relation. We select a sample of 325 NLS1 at relatively low redshift (z<0.1) from the SDSS DR7 by constraining FWHM of $H{\beta}$ in the range of 800-2,200 km/s. Among them, we measured stellar velocity dispersion of 40 objects which show strong stellar absorption lines, e.g. Mg b triplet(${\sim}5175{\AA}$), Fe($5270{\AA}$). In contrast, the other 285 objects show too weak stellar absorption lines to measure velocity dispersion. Using the sample of 40 objects with stellar velocity dispersion measurements, we investigate whether NLS1s follow the same MBH-${\sigma}$ relation as normal galaxies and broad line AGNs. We also test the reliability of the width of narrow lines as a surrogate of stellar velocity dispersion by comparing directly measured stellar velocity dispersion with ${\sigma}$ inferred from [O III], [N II], [S II] line widths, respectively. We will discuss the connection between AGN activity in NLS1s and galaxy evolution based on these results.

• The Bulletin of The Korean Astronomical Society
• /
• v.37 no.2
• /
• pp.128.2-128.2
• /
• 2012

Spectro-polarimetry is the most powerful technique for deducing the magnetic structure of the Sun. Stokes vector allow us to infer the physical conditions in the solar atmosphere prevailing during the line formation. Inversion codes are the main tool to extract this information from the Stokes spectra. This study will focus on measurements of the chromospheric He I 1083.0 nm triplet and the photospheric Si I 1082.7 nm line. A spectropolarimetric data set of sunspots, obtained with the German Vacuum Tower Telescope (VTT) at the Teide observatory on Tenerife, is analyzed using an inversion technique. We will introduce the German Vacuum Tower Telescope and the inversion code HeLix, and will show data sets that are analyzed by HeLix. Finally I made variety plots and maps for understanding photospheric and chromospheric layers of sunspots.

• The Bulletin of The Korean Astronomical Society
• /
• v.37 no.2
• /
• pp.199.1-199.1
• /
• 2012

TRIO-CINEMA(TRiplet Ionospheric Observatory-Cubesat for Ion, Neutron, Electron & MAgnetic field)는 지구근접공간에서의 미세 자기장 변화 및 중성입자의 검출을 목적으로 경희대학교와 UC Berkeley가 공동 개발하는 초소형위성이다. 초소형위성은 내부 공간이 협소하여 효율적인 공간배치 및 위성체발사 시 진동에도 견딜 수 있도록 harness가 제작되어야 한다. CINEMA는 OBC, EPS, 배터리, 수신기, IIB(Instrument Interface Board), MAGIC(MAGnetometer Imperial College) board, HVPS(High Voltage Power Supply)로 구성된 avionics bus와 MAGIC, STEIN(Supra Thermal Electron, Ion, Neutral)의 payload, Solar panel, UHF와 S-band 안테나로 구성되어 있다. Solar panel에서 생산된 전력은 EPS를 통해 배터리에 저장되고 PC104를 통해 avionics stack의 각 board로 전력이 분배된다. IIB는 탑재체 파트와 연결되어 이를 제어하고 HVPS에서 STEIN에 공급되는 고전압은 특수 와이어를 통해 연결되며 UHF 안테나와 S-band 안테나는 RF 케이블로 수신기와 송신기가 연결되어 있다. 각각의 harness는 케이블타이와 lacing tape로 위성체와 고정되며 커넥터는 고정 지지대를 제작하여 나사로 체결하였다. CINEMA에 적용된 harness는 진동시험과 열진공시험을 통해 harness와 시스템의 안정성이 검증 되었다.