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Assessment of direct glycerol alkaline fuel cell based on Au/C catalyst and microporous membrane

  • Yongprapat, Sarayut;Therdthianwong, Apichai;Therdthianwong, Supaporn
    • Advances in Energy Research
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    • v.2 no.1
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    • pp.21-31
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    • 2014
  • The use of a microporous membrane along with Au/C catalyst for direct glycerol alkaline fuel cell was investigated. In comparison with Nafion 112, the microporous Celgard 3401 membrane provides a better cell performance due to the lower ionic resistance as confirmed by impedance spectra. The single cell using Au/C as anode catalyst prepared by using PVA protection techniques provided a higher maximum power density than the single cell with commercial PtRu/C at $18.65mW\;cm^{-2}$ The short-term current decay studies show a better stability of Au/C single cell. The higher activity of Au/C over PtRu/C was owing to the lower activation loss of Awe. The magnitude of current decay indicates a low problem of glycerol crossover from anode to cathode side. The similar performance of single cell with and without humudification at cathode points out an adequate transport of water through the microporous membrane.

Topographic Variability during Typhoon Events in Udo Rhodoliths Beach, Jeju Island, South Korea (제주 우도 홍조단괴해빈의 태풍 시기 지형변화)

  • Yoon, Woo-Seok;Yoon, Seok-Hoon;Moon, Jae-Hong;Hong, Ji-Seok
    • Ocean and Polar Research
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    • v.43 no.4
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    • pp.307-320
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    • 2021
  • Udo Rhodolith Beach is a small-scale, mixed sand-and-gravel beach embayed on the N-S trending rocky coast of Udo, Jeju Island, South Korea. This study analyzes the short-term topographic changes of the beach during the extreme storm conditions of four typhoons from 2016 to 2020: Chaba (2016), Soulik (2018), Lingling (2019), and Maysak (2020). The analysis uses the topographic data of terrestrial LiDAR scanning and drone photogrammetry, aided by weather and oceanographic datasets of wind, wave, current and tide. The analysis suggests two contrasting features of alongshore topographic change depending on the typhoon pathway, although the intensity and duration of the storm conditions differed in each case. During the Soulik and Lingling events, which moved northward following the western sea of the Jeju Island, the northern part of the beach accreted while the southern part eroded. In contrast, the Chaba and Maysak events passed over the eastern sea of Jeju Island. The central part of the beach was then significantly eroded while sediments accumulated mainly at the northern and southern ends of the beach. Based on the wave and current measurements in the nearshore zone and computer simulations of the wave field, it was inferred that the observed topographic change of the beach after the storm events is related to the directions of the wind-driven current and wave propagation in the nearshore zone. The dominant direction of water movement was southeastward and northeastward when the typhoon pathway lay to the east or west of Jeju Island, respectively. As these enhanced waves and currents approached obliquely to the N-S trending coastline, the beach sediments were reworked and transported southward or northward mainly by longshore currents, which likely acts as a major control mechanism regarding alongshore topographic change with respect to Udo Rhodolith Beach. In contrast to the topographic change, the subaerial volume of the beach overall increased after all storms except for Maysak. The volume increase was attributed to the enhanced transport of onshore sediment under the combined effect of storm-induced long periodic waves and a strong residual component of the near-bottom current. In the Maysak event, the raised sea level during the spring tide probably enhanced the backshore erosion by storm waves, eventually causing sediment loss to the inland area.

An Optimization Algorithm of Gypsum Board Loss for Wall Finishing in Modular Construction System (모듈러건축 벽체마감 석고보드 손실 최적화 알고리즘 개발)

  • Lee, Dong-Min;Chin, Sangyoon
    • Korean Journal of Construction Engineering and Management
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    • v.15 no.1
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    • pp.101-110
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    • 2014
  • The ministry of Land, Infrastructure and Transport announced that they launched the pilot project to offer Happy House built with modular construction as part of the major projects of incumbent government in 2013. The market size of modular construction is getting increasingly enlarged together with strong will of government. The major challenges that current modular construction encounters can be summed up as lack of standardization of material on the stage of design and fabrication. The portion of material costs in modular construction marks 16 to 17% higher than the existing other construction method, and account for 60 % of total construction cost, which is why material management is the most important factor. However, the imperfect standardization and specification on design causes high loss of materials on fabrication, which makes the construction wastes and total construction cost increasing in accordance with the increase of material costs. This study has been conducted to verify major modules by developing optimization algorithm on gypsum board material among wall finishing materials. It is expected that this paper contributes not only to eco-friendly construction by minimizing the waste factors of materials through these efforts, but also to removing high cost issues which had been recognized as a setback of current modular construction.

Study on Transient Response of a Unit Proton Exchange Membrane Fuel Cell with an Aged Gas Diffusion Layer (내구성능저하된 기체확산층이 고분자전해질 연료전지의 과도응답성능에 미치는 영향 연구)

  • Cho, Junhyun;Ha, Tahun;Park, Jaeman;Oh, Hwanyeong;Min, Kyoungdoug;Jyoung, Jy-Young;Lee, Eunsook
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.76.2-76.2
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    • 2010
  • The gas diffusion layer is the key component of the proton exchange membrane fuel cell because it directly affect to the mass transport mechanism and dynamic behavior of the cell. In this study, the effects of GDL aging on the transient response of the PEM fuel cell is systematically investigated using current step transient response analysis under different stoichiometric ratios and humidity conditions. With GDLs aged by the accelerated stress test, the effects of hydrophobicity and structural changes due to carbon loss in the GDL on the transient response of PEM fuel cells are determined. The degraded GDLs that had uneven hydrophobicity distributions cause local water flooding inside the GDL and induce lower and unstable voltage responses after load changes.

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MC Design Standards and Practices for Design Standardization of Domestic Modular Housing (국내 모듈러주택의 설계표준화를 위한 구조대 모듈정합 설계기준 및 사례)

  • Chung, Joon-Soo;Lim, Seok-Ho;Baek, Cheong-Hoon;Seol, Wook-Je
    • Journal of the Architectural Institute of Korea Planning & Design
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    • v.34 no.4
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    • pp.19-25
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    • 2018
  • At present, there are many companies that can produce modular housing. However, if the housing projects are conducted without design standards and principles, each company will supply housing according to its own design standards, resulting in a loss of opportunity to promote standardization at a national level. Korea's modular construction technology is still in its infancy, and there is a lack of MC design applications due to the limited construction market. In recent years, however, related R&D has been carried out by the Ministry of Land, Infrastructure and Transport in order to activate modular construction. As a result, test-beds for public rental housing are currently being built, and the public rental housing applied with the modular construction method is expected to spread in the near future. In this regard, this study seeks to promote more economical and efficient production and supply of modular housing. To this end, it investigates the current status of modular construction, analyzes the problems and proposes a serious of MC design standards as part of the design standardization and open system for modular housing industry to solve the problems.

A Mobile IP Handoff Protocol for Performance Enhancement of Transport Protocol over Wireless LAN (무선 LAN에서 트랜스포트 프로토콜 성능 향상을 위한 이동 IP 핸드오프 프로토콜)

  • Park, Jee-Hyun;Jin, Hyun-Wook;Yoo, Hyuck
    • Journal of KIISE:Information Networking
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    • v.29 no.3
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    • pp.242-252
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    • 2002
  • When a Mobile IP handoff occurs, the packets in flight can be lost because they are tunneled based on out-of-date location information. In this parer, we propose an enhanced handoff protocol that achieves no packet loss during Mobile IP handoff over a wireless LAN. Our handoff protocol predicts the next foreign agent that a mobile host is to visit by using: the information from the data link layer of wireless LAN. After that, when a Mobile IP handoff occult, the current foreign agent forwards the packets destined to a mobile host to the predicted foreign agent which buffers them. This eliminates packet loss and reduces the packet forwarding delay. Our handoff protocol is simulated using the Network Simulator-2 (ns-2) and shows the substantial performance enhancement of TCP with much less overhead up to 6.2 times compared to standard Mobile IP.

Minimization of Wave-making Resistance for "Inclined Keel" Containership ("Inclined Keel" 컨테이너선의 조파저항 최소화를 위한 선형최적화)

  • Seo, Kwang-Cheol;Atlar, Mehmet;Kim, Hee-Jung;Chun, Ho-Hwan
    • Journal of the Society of Naval Architects of Korea
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    • v.46 no.2
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    • pp.97-104
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    • 2009
  • Ever increasing fuel prices, almost doubled in the last three years, and global pressure to reduce their environmental impact have been enforcing commercial vessel operators and designers to re-assess current vessel designs with emphasis on their propulsion systems and operational practices. In this paper the "Inclined Keel Hull (IKH)" concept, which facilitates to use larger propeller diameter in combination with lower shaft speed rates and hence better transport efficiency, is explored for a modern 3600 TEU container vessel with the aim of fitting an 13 % larger diameter propeller (and hence resulting 20% lower rpm) to gain further power saving over the similar size basis container ship with conventional "level keel" configuration. It appears that successful application of the "inclined keel Hull" concept is a fine balance amongst the maximum gain in propulsive efficiency, minimum increase in hull resistance and satisfaction of other naval architectural and operational requirements. In order to make the concept economically more viable, this paper concentrates on the fore body design with the possible combination of increase of volume in its fore body to recover the expected volume loss in the aft body due to the space for larger propeller and its low wave-making resistance to minimize the efficiency loss using a well-established optimization software.

Numerical Analysis on Performance Characteristics of PEMFC with Parallel and Interdigitated Flow Channel (평행류와 Interdigitated 유로를 가진 교분자 전해질 연료전지(PEMFC)의 성능특성에 대한 수치해석)

  • Lee, Pil-Hyong;Cho, Son-Ah;Choi, Seong-Hun;Hwang, Sang-Soon
    • Journal of the Korean Electrochemical Society
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    • v.9 no.4
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    • pp.170-177
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    • 2006
  • Optimum design of flow channel in the separation plate of Proton Exchange Membrane Fuel Cell is very prerequisite to reduce concentration over potential at high current region and remove the water generated in cathode effectively. In this paper, fully 3 dimensional computational model which solves anode and cathode flow fields simultaneously is developed in order to compare the performance of fuel cell with parallel and interdigitated flow channels. Oxygen and water concentration and pressure drop are calculated and i-V performance characteristics are compared between flows with two flow channels. Results show that performance of fuel cell with interdigitated flow channel is hi민or than that with parallel flow channel at high current region because hydrogen and oxygen in interdigitated flow channel are transported to catalyst layer effectively due to strong convective transport through gas diffusion layer but pressure drop is larger than that in parallel flow channel. Therefore Trade-off between power gain and pressure loss should be considered in design of fuel cell with interdigitated flow channel.

Se Incorporation in VTD-SnS by RTA and Its Influence on Performance of Thin Film Solar Cells

  • Yadav, Rahul Kumar;Kim, Yong Tae;Pawar, Pravin S.;Heo, Jaeyeong
    • Current Photovoltaic Research
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    • v.10 no.2
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    • pp.33-38
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    • 2022
  • Planner configuration thin film solar cells (TFSCs) with SnS/CdS heterojunction performed a lower short-circuit current (JSC). In this study, we have demonstrated a path to overcome deficiency in JSC by the incorporation of Se in the SnS absorber. We carried out the incorporation of Se in VTD grown SnS absorber by rapid thermal annealing (RTA). The diffusion of Se is mostly governed by RTA temperature (TRTA), also it is observed that film structure changes from cube-like to plate-like structure with TRTA. The maximum JSC of 23.1 mA cm-2 was observed for 400℃ with an open-circuit voltage (VOC) of 0.140 V for the same temperature. The highest performance of 2.21% with JSC of 18.6 mA cm-2, VOC of 0.290 V, and fill factor (FF) of 40.9% is observed for a TRTA of 300℃. In the end, we compare the device performance of Se- incorporated SnS absorber with pristine SnS absorber material, increment in JSC is approximately 80% while a loss in VOC of about 20% has been observed.

Ionic currents elicited by the hypotonic solution in hamster eggs (저장성 용액에 노출된 햄스터 난자에 관찰되는 이온전류의 변화)

  • Choi, Won-yeong;Kim, Yang-mi;Haan, Jae-hee;Huh, Il-oh;Park, Choon-ok;Hong, Seong-geun;Pyu, Pan-dong;Kim, Jong-shu
    • Korean Journal of Veterinary Research
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    • v.36 no.2
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    • pp.305-312
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    • 1996
  • Cell volume regulatory mechanisms are usually disclosed by exposure of cell to anisotonic media. If a cell is suddenly exposed to hypotonic media, it swells initially like an osmometer but within minutes regains its original cell volume. This behavior has been labelled as regulatory cell volume decrease(RVD). RVD is believed to result from the loss of permeable ions through the membrane. In this study, we examined hypotonically induced changes in the membrance currents involved in RVD by using whole cell voltage clamp technique in the unfertilized hamster egg. At -40mV of the holding potential, the stationary current was maintained in the hamster egg exposed to isotonic solution composed of, mainly, 115mM NaCl and 40mM mannitol. Hypotonic solution was prepared by removing mannitol. Therefore, the concentrations of $Na^+$ and $Cl^-$ in this hypotonic media were the same as those in the isotonic solution. Following 30 to 60 sec after applying the hypotonic media to the egg, the inward current was evoked. This inward current was eliminated by $100{\mu}M$ 4-acetamido-4'-isothiocyanostil-bene-2,2'-disulfonic acid(SITS), an anion channel blocker, leaving the small outward current component. Further addition of 2mM $Ba^{2+}$, a broad $K^+$ channel blocker, completely abolished the small outward current left even in the presence of SITS during hypotonic stress. These results suggest that $K^+$ and $Cl^-$ move out of cells, resulting in RVD. To test the involvement of $Na^+$ in RVD, 20mM Na-isethionate was substituted for mannitol in isotonic media(135mM $Na^+$) and Na-isethionate (20mM) was freed the hypotonic solution. Only $Cl^-$ concentration in both isotonic and hypotonic media was kept constant at 115mM, whereas concentration of $Na^+$ was lowered in hypotonic solution to 115mM from 135mM in isotonic solution. Hypotonic medium induced the outward current in the egg equilibrated isotonically. This current was reduced by $100{\mu}M$ SITS but was augmented by 2 mM $Ba^{2+}$. In terms of RVD, these results imply that $Cl^-$ efflux is coupled with $K^+$, maybe for electroneutrality during hypotonic stress and/or with $Na^+$ via unknown transport mechanism(s). From the overall results, the hypotonic stress facilitates the movement of $Cl^-$ and $K^+$ out of the hamster egg to regain cellular volume with electroneutrality. If there exist a difference in $[Na^+]_0$ between isotonic and hypotonic solution, another transport mechanism concerned with $Na^+$ may, at least partly, participate in regulatory volume decrease.

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