• 한국전기화학회:학술대회논문집
• /
• 한국전기화학회 2003년도 전지기술심포지움
• /
• pp.141-151
• /
• 2003

The electrochemical activity of the olivine type $LiMPO_4$ (M=transition metals) cathodes strongly depends on various factors, e.g., the transition metal element M, perturbative doping of the supervalent cations into Li site, composite formation with conductive additives, state of charge/discharge, and particle size and its geometries, etc. This is, therefore, an important issue of interdisciplinary between electrochemistry and solid state science towards practical applications. In order to shed light on this interesting but complicated issue with the transport properties and crystallographic aspects, systematic discussion will be made with the review of our recent publications; (1) first principle derivation of the electronic structures, (2) crystallographic mapping of the selected solid solutions, (3) quantitative elucidation of the electron-lattice interaction, (4) spectroscopic detection of the local environment with Mossbauer and EXAFS, (5) synthetic optimization of the electrode composite, and (6) electrochemical evaluation of the reaction kinetics, particularly on M = Fe, Mn.

• 소성∙가공
• /
• 제28권3호
• /
• pp.123-129
• /
• 2019

Hypereutectic Al-Si alloys have been widely utilized for wear-resistant components in the automotive industry. In order to expand the application of Hypereutectic Al-Si alloys, the addition of alloying elements forming a stable precipitate at high temperature is required. Thermally stable inter metallic compounds can be formed through the addition of transition elements such as Fe, Ni to Al alloys. However, the amount of transition element to be added to Al alloys is limited due to their low solid solubility. Also, hypereutectic Al-Si-Fe alloys form coarse primary Si phases and needle-shaped intermetallic compounds during solidification in the general casting processes. In this study, the effects of the destruction of Intermetallic compound and Si phase are investigated via hot extrusion. Both the microstructure and mechanical properties are discussed under different extrusion conditions.

• 한국초전도ㆍ저온공학회논문지
• /
• 제23권3호
• /
• pp.1-4
• /
• 2021

Hydrogen, the lightest and the most abundant element in the universe becomes a mainstay of contemporary condensed matter physics, which is largely because its metallization is regarded as the holy grail of high-pressure physics and it is also due to recent observations of high Tc superconductivity in hydrogen-dense compounds at extremely high pressure. Contemporary static high-pressure technique is not enough to realize the metallization of solid hydrogen and hydrogen-dense compounds may significantly reduce the required transition pressure providing an excellent proxy study. In this brief review, I will introduce recent achievements of high-pressure study in solid hydrogen and hydrides.

• 대한기계학회논문집
• /
• 제10권5호
• /
• pp.625-634
• /
• 1986

본 연구에서는 알루미늄 합금인 알루미늄 2014와 6061의 이재를 V형 맞대기 이음을 한 후 정적인장하중을 가하여 모아레법에 광탄성 피복법을 조합한 방법에 의 해 변형율을 실시간(real time)에서 측정하고 유한요소법으로 해석한 결과와 비교검 토하였다.

• Structural Engineering and Mechanics
• /
• 제56권2호
• /
• pp.275-291
• /
• 2015

Adherence between reinforcement and the surrounding concrete is usually ignored in finite element analysis (FEA) of reinforced concrete (RC) members. However, load transition between the reinforcement and surrounding concrete effects RC members' behavior a great deal. In this study, the effects of bond-slip on the FEA of RC members are examined. In the analyses, three types of bond-slip modeling methods (perfect bond, contact elements and spring elements) and three types of reinforcement modeling methods (smeared, one dimensional line and three dimensional solid elements) were used. Bond-slip behavior between the reinforcement and surrounding concrete was simulated with cohesive zone materials (CZM) for the first time. The bond-slip relationship was identified experimentally using a beam bending test as suggested by RILEM. The results obtained from FEA were compared with the results of four RC beams that were tested experimentally. Results showed that, in FE analyses, because of the perfect bond occurrence between the reinforcement and surrounding concrete, unrealistic strains occurred in the longitudinal reinforcement. This situation greatly affected the load deflection relationship because the longitudinal reinforcements dominated the failure mode. In addition to the spring elements, the combination of a bonded contact option with CZM also gave closer results to the experimental models. However, modeling of the bond-slip relationship with a contact element was quite difficult and time consuming. Therefore bond-slip modeling is more suitable with spring elements.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2003년도 하계학술대회 논문집 Vol.4 No.2
• /
• pp.968-971
• /
• 2003

Due to a low efficiency of phosphor with large Stoke shift in Vacuum Ultra Violet (VUV) excitation environment, new PDP phosphors which can be excited in UV excitation environment need to be developed. In this study, $Zn_2SiO_4:Tb$ phosphor was synthesized by solid-state reaction method at $1300^{\circ}C$ with varying Tb concentration, and its cross relaxation effect was observed by Photoluminescence (PL) measurement. In order to decrease $^5D_3{\to}7F_j$ transition with blue emission in $Zn_2SiO_4:Tb$ phosphor, Dy, co-activator element, was added to $Zn_2SiO_4:Tb$ phosphor. In 254nm excitation environment, broad-emission peak was observed around 524nm, green emission.

• 한국자기학회지
• /
• 제5권5호
• /
• pp.753-757
• /
• 1995

Systematic studies on the crystal structure and magnetic properties of light rare earth element(RE) compounds with Pb, $REPb_{2}$, have been carried out. Their crystal structure has been identified to be a $MoSi_{2}$-type. The values of the effective magnetic moment for $CePb_{2},\;PrPb_{2}\;and\;NdPb_{2}$ are respectively very close to the theoretical values of $RE^{3+}$. These three compounds are antiferromagnetic and exhibit a metamagnetic transition. The magnitude of the Neel temperature is proportional to two-thirds of the de Gennes factor. The magnetic entropy change for $NdPb_{2}$ is contrast to the value for $CePb_{2}$ heavy-fermion compound, comparable to the theoretical value. The magnetic contribution to the temperature dependence of resistivity for $PrPb_{2}$ is given by a form of -lnT in a wide temperature range, implying the Kondo system in analogy with $Cepb_{2}$.

• Steel and Composite Structures
• /
• 제51권4호
• /
• pp.363-375
• /
• 2024

Within the optimization field, addressing the intricate posed by fluidic pressure loads on functionally graded structures with frequency-related designs is a kind of complex design challenges. This paper thus introduces an innovative density-based topology optimization strategy for frequency-constraint functionally graded structures incorporating Darcy's law and a drainage term. It ensures consistent treatment of design-dependent fluidic pressure loads to frequency-related structures that dynamically adjust their direction and location throughout the design evolution. The porosity of each finite element, coupled with its drainage term, is intricately linked to its density variable through a Heaviside function, ensuring a seamless transition between solid and void phases. A design-specific pressure field is established by employing Darcy's law, and the associated partial differential equation is solved using finite element analysis. Subsequently, this pressure field is utilized to ascertain consistent nodal loads, enabling an efficient evaluation of load sensitivities through the adjoint-variable method. Moreover, this novel approach incorporates load-dependent structures, frequency constraints, functionally graded material models, and polygonal meshes, expanding its applicability and flexibility to a broader range of engineering scenarios. The proposed methodology's effectiveness and robustness are demonstrated through numerical examples, including fluidic pressure-loaded frequency-constraint structures undergoing small deformations, where compliance is minimized for structures optimized within specified resource constraints.

• 자원환경지질
• /
• 제35권6호
• /
• pp.533-544
• /
• 2002

주요 및 미량원소들의 함량을 조절하는 반응들 동안 용존 원소들의 상대적인 유동성을 알아보기 기존에 발표된 강원도 지역 탄산수와 화강암에 대한 자료로부터 주·부·미량원소의 함량을 다시 살펴보았다. 탄산수내에 용존되어 있는 원소들의 상대적인 유동성은 Na으로 평균화한 탄산수-화강암간의 비로부터 계산하였다 계산결과는 탄산수 대수층내로 마그마에서 기원한 휘발성을 지닌 금속원소들의 가스에 의한 유입은 강원도 지역에서 무시할 만하며, 이런 유입은 상승하는 유체의 냉각에 의해 조절된다 이산화탄소가 유입된 약산성의 물에 의한 화강암의 용해반응이 금속원소들의 주요 공급원이다 유동성이 매우 낮은 원소 (Al)는 고체의 풍화산물 내에 우선적으로 잔류하는 반면, 알칼리 및 알칼리 토금속들과 OHA원소들 중 As과 U은 유동성이 있으며, 따라서 수용액계 내로 방출된다. 전이금속원소들은 중간정도의 유동특성을 보이는데, Fe와 Mn은 산화환원조건 또는 V, Zn과 Cu는 고체표면과 연관된 반응(흡착이나 침전)의해 주로 영향을 받는다.

• Journal of Microbiology
• /
• 제38권4호
• /
• pp.239-244
• /
• 2000

The cats gene encodes the major catalase in Sreptomyces coelicolor, whose production increases upon H$_2$O$_2$treatment. Besides the previously identified primary promoter (catApl), a minor promoter (catAp2) was newly assigned by S1 nuclease mapping. The catAp2 transcript was observed transiently upon entry into the stationary phase in liquid culture and upon differentiation on solid plates, whereas the level of catApl transcription did not chance significantly during this growth transition. ThecatApl promoter was transcribed by the major vegetative RNA polymerase holoenzyme containing $\sigma$$\^$HrdB/, whereas the catAp2 was transcribed in vitro by the holoenzyme containing $\sigma$$\^$R/ that is activated under oxidative conditions. The cia-element regulating the H$_2$O$_2$-inducibility of catApl was identified within the 23 bp inverted repeat sequence located between -65 and -43 of the catApl promoter. We roamed this sequence HRE (H$_2$O$_2$-responsive Element). The distal half of the inverted repeat was more crucial for H$_2$O$_2$-dependent induction of the catApl transcript than the proximal half. HRE most likely serves as a binding site for the H$_2$O$_2$-responsive repressor CatR.