• Title/Summary/Keyword: transition rate

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Structural Changes in Isothermal Crystallization Processes of Synthetic Polymers Studied by Time-Resolved Measurements of Synchrotron-Sourced X-Ray Scatterings and Vibrational Spectra

  • Tashiro, Kohji;Hama, Hisakatsu
    • Macromolecular Research
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    • v.12 no.1
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    • pp.1-10
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    • 2004
  • The structural changes occurring in the isothermal crystallization processes of polyethylene (PE), poly-oxymethylene (POM), and vinylidene fluoridetrifluoroethylene (VDFTrFE) copolymer have been reviewed on the basis of our recent experimental data collected by the time-resolved measurements of synchrotron-sourced wide-angle (WAXS) and small-angle X-ray scatterings (SAXS) and infrared spectra. The temperature jump from the melt to a crystallization temperature could be measured at a cooling rate of 600-1,000 $^{\circ}C$/min, during which we collected the WAXS, SAXS, and infrared spectral data successfully at time intervals of ca. 10 sec. In the case of PE, the infrared spectral data clarified the generation of chain segments of partially disordered trans conformations immediately after the jump. These segments then became transformed into more-regular all-trans-zigzag forms, followed by the formation of an orthorhombic crystal lattice. At this stage, the generation of a stacked lamella structure having an 800-${\AA}$-long period was detected in the SAXS data. This structure was found to transfer successively to a more densely packed lamella structure having a 400-${\AA}$-long period as a result of the secondary crystallization of the amorphous region in-between the original lamellae. As for POM, the formation process of a stacked lamella structure was essentially the same as that mentioned above for PE, as evidenced from the analysis of SAXS and WAXS data. The observation of morphology-sensitive infrared bands revealed the evolution of fully extended helical chains after the generation of lamella having folded chain structures. We speculate that these extended chains exist as taut tie chains passing continuously through the neighboring lamellae. In the isothermal crystallization of VDFTrFE copolymer from the melt, a paraelectric high-temperature phase was detected at first and then it transferred into the ferroelectric low-temperature phase at a later stage. By analyzing the reflection profile of the WAXS data, the structural ordering in the high-temperature phase and the ferroelectric phase transition to the low-temperature phase of the multi-domain structure were traced successfully.

Kinetic Studies on Halogen Exchange of Substituted Benzenesulfonylbromides

  • Kim, Jaerok
    • Nuclear Engineering and Technology
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    • v.5 no.4
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    • pp.321-333
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    • 1973
  • The rates and activation parameters for the halide exchange reactions of substituted benzenesulfonylbromides (R-C$_{6}$H$_4$SO$_2$Br, R=p-MeO, p-$CH_3$, p-H, p-NO$_2$) in dry acetone at two temperatures were determined. It was found that the nucleophilicity order of Cl->I-$\geq$Br- for strong electron withdrawing-, and mild electron donating group, and of I-$\geq$Cl->Br- for strong electron donating group, Hammett plots showed slightly convoked characteristics which is similar to the plots of substituted benzenesulfonylchlorides, but contrary to the concaved nature for the halide exchange reactions of substituted benzyl chlorides. The rate of halogen exchange between benzenesulfonylbromide and lithium bromide decreased in the order of solvent : ($CH_3$)$_2$CO>$CH_3$CN》MeOH. The rates and activation parameters were also compared with those already known in the substituted benzenesulfonylchlorides. Theses were explained in terms of the structural properties of the transition state, and discussed the reaction mechanisms.s.

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Validation of Neurotensin Receptor 1 as a Therapeutic Target for Gastric Cancer

  • Akter, Hafeza;Yoon, Jung Hwan;Yoo, Young Sook;Kang, Min-Jung
    • Molecules and Cells
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    • v.41 no.6
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    • pp.591-602
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    • 2018
  • Gastric cancer is the fifth most common type of malignancy worldwide, and the survival rate of patients with advanced-stage gastric cancer is low, even after receiving chemotherapy. Here, we validated neurotensin receptor 1 (NTSR1) as a potential therapeutic target in gastric cancer. We compared NTSR1 expression levels in sixty different gastric cancer-tissue samples and cells, as well as in other cancer cells (lung, breast, pancreatic, and colon), by assessing NTSR1 expression via semi-quantitative real-time reverse transcription polymerase chain reaction, immunocytochemistry and western blot. Following neurotensin (NT) treatment, we analyzed the expression and activity of matrix metalloproteinase-9 (MMP-9) and further determined the effects on cell migration and invasion via wound-healing and transwell assays. Our results revealed that NTSR1 mRNA levels were higher in gastric cancer tissues than non-cancerous tissues. Both of NTSR1 mRNA levels and expression were higher in gastric cancer cell lines relative to levels observed in other cancer-cell lines. Moreover, NT treatment induced MMP-9 expression and activity in all cancer cell lines, which was significantly decreased following treatment with the NTSR1 antagonist SR48692 or small-interfering RNA targeting NTSR1. Furthermore, NT-mediated metastases was confirmed by observing epithelial-mesenchymal transition markers SNAIL and E-cadherin in gastric cancer cells. NT-mediated invasion and migration of gastric cancer cells were reduced by NTSR1 depletion through the Erk signaling. These findings strongly suggested that NTR1 constitutes a potential therapeutic target for the inhibition of gastric cancer invasion and metastasis.

Compression Strength Size Effect on Carbon-PEEK Fiber Composite Failing by Kink Band Propagation

  • Kim, Jang-Ho
    • KCI Concrete Journal
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    • v.12 no.1
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    • pp.57-68
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    • 2000
  • The effect of structure size on the nominal strength of unidirectional fiber-polymer composites, failing by propagation of a kink band with fiber microbuckling, is analyzed experimentally and theoretically. Tests of novel geometrically similar carbon-PEEK specimens, with notches slanted so as to lead to a pure kink band (without shear or splitting cracks), are conducted. The specimens are rectangular strips of widths 15.875, 31.75. and 63.5 mm (0.625, 1.25 and 2.5 in and gage lengths 39.7, 79.375 and 158.75 mm (1.563, 3.125 and 6.25 in.). They reveal the existence of a strong (deterministic. non-statistical) size effect. The doubly logarithmic plot of the nominal strength (load divided by size and thickness) versus the characteristic size agrees with the approximate size effect law proposed for quasibrittle failures in 1983 by Bazant This law represents a gradual transition from a horizontal asymptote, representing the case of no size effect (characteristic of plasticity or strength criteria), to an asymptote of slope -1/2 (characteristic of linear elastic fracture mechanics. LEFM) . The size effect law for notched specimens permits easy identification of the fracture energy of the kink bandand the length of the fracture process zone at the front of the band solely from the measurements of maximum loads. Optimum fits of the test results by the size effect law are obtained, and the size effect law parameters are then used to identify the material fracture characteristics, Particularly the fracture energy and the effective length of the fracture process zone. The results suggest that composite size effect must be considered in strengthening existing concrete structural members such as bridge columns and beams using a composite retrofitting technique.

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Fail-over Mechanisms based on Anycast for Stable IPv6 Recursive DNS Services (안정적인 IPv6 리커시브 DNS 서비스를 위한 애니캐스트 기반의 실패 복구 방안 연구)

  • Suh, Yu-Hwa;Kim, Kyung-Min;Shin, Yong-Tae;Song, Kwang-Ho;Kim, Weon;Park, Chan-Ki
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.32 no.2B
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    • pp.108-117
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    • 2007
  • Recursive DNS is configured as primary or secondary DNS on user PC and performs domain name resolution corresponding user's DNS query. At present, the amount of DNS traffic is occupied high rate in the total internet traffic and the internet traffic would be increased by failure of IPv6 DNS queries and responses as IPv6 transition environment. Also, existing Recursive DNS service mechanisms is unstable on malicious user's attack same as DoS/DDoS Attack and isn't provide to user trust DNS service fail-over. In this paper, we propose IPv6 Recursive DNS service mechanisms for based on anycast for improving stability. It is that fail-over Recursive DNS is configured IPv6 Anycast address for primary Recursive DNS's foil-over. this mechanisms increases reliability and resiliency to DoS/DDoS attacks and reduces query latency and helps minimize DNS traffic as inducing IPv6 address.

A Study on Energy Savings in a Network Interface Card Based on Optimization of Interrupt Coalescing (인터럽트 병합 최적화를 통한 네트워크 장치 에너지 절감 방법 연구)

  • Lee, Jaeyoul;Han, Jaeil;Kim, Young Man
    • Journal of Information Technology Services
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    • v.14 no.3
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    • pp.183-196
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    • 2015
  • The concept of energy-efficient networking has begun to spread in the past few years, gaining increasing popularity. A common opinion among networking researchers is that the sole introduction of low consumption silicon technologies may not be enough to effectively curb energy requirements. Thus, for disruptively boosting the network energy efficiency, these hardware enhancements must be integrated with ad-hoc mechanisms that explicitly manage energy saving, by exploiting network-specific features. The IEEE 802.3az Energy Efficient Ethernet (EEE) standard is one of such efforts. EEE introduces a low power mode for the most common Ethernet physical layer standards and is expected to provide large energy savings. However, it has been shown that EEE may not achieve good energy efficiency because mode transition overheads can be significant, leading to almost full energy consumption even at low utilization levels. Coalescing techniques such as packet coalescing and interrupt coalescing were proposed to improve energy efficiency of EEE, but their implementations typically adopt a simple policy that employs a few fixed values for coalescing parameters, thus it is difficult to achieve optimal energy efficiency. The paper proposes adaptive interrupt coalescing (AIC) that adopts an optimal policy that could not only improve energy efficiency but support performance. AIC has been implemented at the sender side with the Intel 82579 network interface card (NIC) and e1000e Linux device driver. The experiments were performed at 100 M bps transfer rate and show that energy efficiency of AIC is improved in most cases despite performance consideration and in the best case can be improved up to 37% compared to that of conventional interrupt coalescing techniques.

Reliability Improvement Method of the Electrical Door System for the Railway Vehicles (철도차량의 전기식 출입문 시스템의 신뢰도 개선 방안)

  • Yang, Yong Joon;Lee, Hi Sung
    • Journal of Energy Engineering
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    • v.24 no.1
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    • pp.17-23
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    • 2015
  • Electrical door system is one of the most essential items for the successful commercial operation of the railway vehicles. Nowadays, reliability values of electrical door system have a tendency to be included in technical requirements for design and manufacturing of rolling stocks. Manufacturer shall meet the reliability target values of electrical door system which is proposed by railway operator in procurement contract book. Railway operator shall approve the supplier's the reliability target values based on maintenance operation data. Railway operators are in the transition stage from the framework of maintenance interval based on time to the framework of maintenance interval based on distance. In this study, failure rates of the electrical door system currently used in railway vehicles are collected from maintenance field data. Failure rates are analyzed by using Minitab. Several kinds of plan for improving reliability are also suggested. It is necessary to keep studying on reliability prediction methodology, applying it in the field and implementing on improvement of reliability through feedback as well. Further, it will be useful for determining new maintenance policies or changing maintenance intervals for existing railway vehicles.

Structure and Motion Estimation with Expectation Maximization and Extended Kalman Smoother for Continuous Image Sequences (부드러운 카메라 움직임을 위한 EM 알고리듬을 이용한 삼차원 보정)

  • Seo, Yong-Duek;Hong, Ki-Sang
    • Journal of KIISE:Software and Applications
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    • v.31 no.2
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    • pp.245-254
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    • 2004
  • This paper deals with the problem of estimating structure and motion from long continuous image sequences, applying the Expectation Maximization algorithm based on extended Kalman smoother to impose the time-continuity of the motion parameters. By repeatedly estimating the state transition matrix of the dynamic equation and the parameters of noise processes in the dynamic and measurement equations, this optimization gives the maximum likelihood estimates of the motion and structure parameters. Practically, this research is essential for dealing with a long video-rate image sequence with partially unknown system equation and noise. The algorithm is implemented and tested for a real image sequence.

Evaluation of ZSM-5 supported metal catalyst for NOx removal (NOx 제거를 위한 금속 담지 ZSM-5 촉매 평가)

  • Kim, Jin-Gul;Yoo, Seung-Joon;Kim, Seong-Soo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.10 no.8
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    • pp.2015-2020
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    • 2009
  • $NO_x$ reduction of stationary exhaust was performed at atmospheric condition and the temperature ranging from $200^{\circ}C$ to $500^{\circ}C$ over ZSM-5 supported metal catalyst. The characteristics of the prepared catalysts were investigated using the analytical techniques such as SEM, XRD, EDX, ICP and ITR. The results of EDX and ICP analysis demonstrated that the most part of transition metal existed on the exterior surface of support. Maximum de-$NO_x$ yield over Fe/ZSM-5 shown between $380^{\circ}C$ and $400^{\circ}C$ was presumed to be due to the maximum H2 reduction rate at $400^{\circ}C$ of ITR.

Magnetic Properties of $GdBa_2Cu_3O_{7-y}$ Bulk Superconductors Fabricated by a Top-seeded Melt Growth Process (종자 결정 성장법으로 제조된 $GdBa_2Cu_3O_{7-y}$ 벌크 초전도체의 자기적 특성)

  • Kim, K.M.;Park, S.D.;Jun, B.H.;Ko, T.K.;Kim, C.J.
    • Progress in Superconductivity
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    • v.14 no.1
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    • pp.39-44
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    • 2012
  • The fabrications condition and superconducting properties of top-seeded melt growth (TSMG) processed $GdBa_2Cu_3O_{7-y}$ (Gd123) bulk superconductors were studied. Processing parameters (a maximum temperature ($T_{max}$), a temperature for crystal growth ($T_G$) and a cooling rate ($R_G$) through a peritectic temperature ($T_P$) for the fabrication of single grain Gd123 superconductors were optimized. The magnetic levitation forces, trapped magnetic fields, superconducting transition temperature ($T_c$) and critical current density ($J_c$) of the Gd123 bulks superconductors were estimated. Single grain Gd123 bulk superconductors were successfully fabricated at the optimized processing condition. The $T_c$ of a TSMG processed Gd123 sample was 92.5 K and the $J_c$ at 77 K and 0 T was approximately $50kA/cm^2$. The trapped magnetic field contour and magnetic levitation forces were dependent on the top surface morphology of TSMG processed Gd123 samples. The single grain Gd123 samples, field-cooled at 77 K using a Nd-B-Fe permanent magnet with 5.27 kG and 30 mm dia., showed the trapped magnetic field contour of a single grain with a maximum of 4 kG at the sample center. The maximum magnetic levitation forces of the single grain Gd123 sample, field-cooled or zero field-cooled, were 40 N and 107 N, respectively.