• Bulletin of the Korean Chemical Society
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• 제16권7호
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• pp.619-624
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• 1995

Oxidation of triphenylphosphine to triphenylphosphine oxide by [(tpy)(bpy)Ru(O)]2+ (tpy is 2,2':6',2"-terpyridine and bpy is 2,2'-bipyridine) in CH3CN has been studied. Experiments with the 18O-labeled oxo complex show that transfer of oxygen from [(tpy)(bpy)RuⅣ=O]2+ to triphenylphosphine is quantitative within experimental error. The reaction is first order in each reactant with k (25.3 ℃)=1.25 × 106 M-1s-1. The inital product, [(tpy)(bpy)RuⅡ-OPPh3]2+, is formed as an observable intermediate and undergoes slow k (25 ℃)=6.7 × 10-5 s-1 solvolysis. Activation parameters for the oxidation step are ΔH≠=3.5 kcal/mol and ΔS≠=-23 eu. The geometry at ruthenium in the complex cation, [(tpy)(bpy)RuⅡ(OH2)]2+, is approximately octahedral with the ligating atoms being the three N atoms of the tpy ligand, the two N atoms of the bpy ligand, and the oxygen atom of the aqua ligand. The Ru-O bond length is 2.136(5) Å.

• Bulletin of the Korean Chemical Society
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• 제12권6호
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• pp.678-681
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• 1991

The Wittig-oxy-Cope rearrangements of deprotonated diallyl ether, I, $CH_2={\bar{C}}H-CH-O-CH_2-CH=CH_2$, have been investigated theoretically by the AM1 method. A two step mechanism forming a Wittig product ion, II, $(CH_2=CH)$ $(CH_2=CH-CH_2)$ $CHO^-$, through a radical-pair intermediate was found to provide the most favored reaction pathway in the Wittig rearrangement. The subsequent oxy-Cope rearrangement from species II also involves a two step mechanism through a biradicaloid intermediate. The intramolecular proton transfer in I (to form $CH_2=CH-CH_2-O-{\bar{C}}H-CH=CH_2$) is a higher activation energy barrier process compared to the Wittig and oxy-Cope rearrangements and is considered to be insignificant. These results are in good agreement with the condensed-phase as well as gas-phase experimental results.

• Journal of the Korea Safety Management & Science
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• 제3권4호
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• pp.181-191
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• 2001

Integrated Supply Chain Management is a important subject for all enterprise activities as include logistics/sales, transfer and storage, manufacturing, purchasing of materials. A recent customer wants to receive high level service of all parts as Qualify, Delivery, Cost and Product. Therefore, Enterprise effort to supply for customers needs use some techniques like Data Mining, POS, MIS. Inventory and Logistics cost is the highest expense of all cost from first supplier to final customer on supply routine. So, SCM's basic purpose is reduce to that cost. So that this paper explain necessary, background, concept of SCM, analyze several using methodology and function of main SCM solution, after propose to ATP model include arithmetic procedure, functions, input data for determines available due date.

• The Korean Journal of Archival Studies
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• 제2호
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• pp.103-128
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• 2000

The classification of records is basically different from that of librarian materials because records have a nature of spontaneous and correlated product made during the process of work, as well as a value of proof and information. Hence the main task of archival management institute is to classify those records through the process of transfer and receipt for the purpose of reservation and utilization of their value. Therefore, the records should be classified by the manner, which reflects the function and organization of producing institute, and in turn, the principles of producing site and original record order should be maintained for this purpose. The characteristics of librarian materials and records and the tasks of management institutes form the basis of very different principles. The records can present the characteristics of producing institute and maintain the value made by the correlated nature as they are classified, managed and preserved by the above principles, In addition, it is known how and why they were produced and utilized, as well as they can be preserved in original form and effectively arranged, recorded and managed.

• Bulletin of the Korean Chemical Society
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• 제17권3호
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• pp.269-273
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• 1996

Alkyl halides were reduced to the corresponding alkanes by the homonuclear bridging hydride, (μ-H)[(η5-MeCp)Mn(CO)2]2-PPN+ in THF at the elevated temperatures (40-60 ℃) under the pseudo first order reaction conditions where excess of alkyl halide was employed under nitrogen atmosphere. The reaction is of overall second order; first order with respect to [bridging hydride] and first order with respect to [alkyl halide] with the activation parameters, ΔH≠=28.93 kcal/mol and ΔS≠=17.95 e.u. The kinetic data, the ESR evidence and the reaction with cyclopropyl canbinyl bromide ensure that two possible reaction pathways are operable in this reaction: (1) concerted mechanism, and (2) single electron transfer pathway are in competition leading to the same product, the corresponding alkane.

• International conference on construction engineering and project management
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• The 6th International Conference on Construction Engineering and Project Management
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• pp.26-27
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• 2015

In the trend of globalization and location transfer of existing production bases is still characterized by an extremely unstable status between different countries and different regions. The results are negative impacts on cost, quality and speed of project implementation, especially automobile industry which is one of the most complex manufacturing sectors. In order to overcome problems from Global Standardization of Production Line and its Localization, it is highly required comprehensive coordination among design of production equipment, production technology, space and interfaces. It is necessary to set up standard of production equipment and building for parallel progress, in order to complete production line in shortest time for launching product. In addition, this standard should keep flexibility with consideration of local situation which means "Glocalization."

• Proceedings of the Korea Information Processing Society Conference
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• 한국정보처리학회 2023년도 춘계학술발표대회
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• pp.334-335
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• 2023

본 논문에서는 이미지 데이터와 각종 텍스트 기반의 데이터를 적절히 결합하여 유용한 데이터를 만들어 내는 방법을 제안한다. 그 사례로 편의점 상품 이미지와 편의점 프로모션 데이터, 사용자 위치정보 데이터를 적절히 결합하여 사용자가 편의점 상품 전면 이미지를 제공했을 때, 해당 상품이 어떤 편의점 브랜드에서 어떤 프로모션을 진행하고 있는지, 그리고 현재 위치에서 가까운 점포가 어디인지를 사용자에게 제공하는 시스템을 구현한다. 이미지를 어떤 데이터와 결합하는지에 따라 다양한 요구사항에 대응할 수 있다.

• ETRI Journal
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• 제45권4호
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• pp.690-703
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• 2023

Multistage amplifiers have become appropriate choices for high-speed electronics and data conversion. Because of the large number of high-impedance nodes, frequency compensation has become the biggest challenge in the design of multistage amplifiers. The new compensation technique in this study uses two differential stages to organize feedforward and feedback paths. Five Miller loops and a 500-pF load capacitor are driven by just two tiny compensating capacitors, each with a capacitance of less than 10 pF. The symbolic transfer function is calculated to estimate the circuit dynamics and HSPICE and TSMC 0.18 ㎛. CMOS technology is used to simulate the proposed five-stage amplifier. A straightforward iterative approach is also used to optimize the circuit parameters given a known cost function. According to simulation and mathematical results, the proposed structure has a DC gain of 190 dB, a gain bandwidth product of 15 MHz, a phase margin of 89°, and a power dissipation of 590 ㎼.

• Design & Manufacturing
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• 제17권3호
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• pp.1-7
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• 2023

Blow molding is a manufacturing process in which thermoplastic preforms are preheated and then pneumatically expanded within a mold to produce hollow products of various shapes. The two-step process, a type of blow molding method, requires the output of multiple infrared lamps to be adjusted individually, so the process of finding initial conditions hinders productivity. In this study, digital twin technology was applied to solve this problem. A blow molding simulation technique was established and simulation-based metadata was generated. A response surface ROM (Reduced Order Model) was built using the generated metadata. Then, a dynamic ROM was constructed using the results of 3D heat transfer analysis. Through this, users can quickly check the product wall thickness uniformity according to changes in the control value of the heating lamp for products of various shapes, and at the same time, check the temperature distribution of the preform in real time.

• Journal of Dairy Science and Biotechnology
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• 제42권1호
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• pp.18-22
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• 2024

In this study, we performed whole-genome sequencing of Levilactobacillus brevis KL251 (KL251) isolated from kimchi. The KL251 genome, characterized by a circular chromosome spanning 2,345,062 base pairs with a GC content of 45.78%, was analyzed. KL251 contains 2,275 coding DNA sequences (CDSs), 56 transfer RNAs (tRNAs), and 4 ribosomal RNAs (rRNAs). Genes associated with gamma-aminobutyric acid (GABA) production and CRISPR-Cas systems were identified and could potentially be used for GABA synthesis and defense against foreign DNA. Additionally, the presence of functional genes involved in isoprenoid biosynthesis, glutathione generation, and redox sensing showed that cellular metabolism and stress responses were important characteristics of this genome. These genomic findings suggest that the KL251 strain could potentially have several applications, including food fermentation, probiotics, dairy product starters, and the development of health-enhancing products.