• Journal of the Korean earth science society
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• v.40 no.5
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• pp.476-486
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• 2019

This study examines the controlling role of synoptic disturbances on $PM_{10}$ spring variability in the Korean Peninsula by using empirical orthogonal function (EOF) and back trajectory analyses. Three leading EOF modes are identified, and a lead-lag analysis suggests that $PM_{10}$ variabilities be closely related to the synoptic weather systems. The first EOF shows the spatially homogeneous distribution of $PM_{10}$, which is influenced by travelling anticyclonic disturbance with negative precipitation and descending motion. The second and third modes exhibit the dipole structures of $PM_{10}$, being associated with propagating cyclones. Furthermore, the back-trajectory analysis suggests that the transport of pollutants by anomalous winds associated with synoptic disturbances also contribute to the altered $PM_{10}$ concentration. Hence, a substantial synoptic control should be considered in order to fully understand the $PM_{10}$ spatiotemporal variability.

• Korean Journal of Occupational Health Nursing
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• v.31 no.4
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• pp.187-197
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• 2022

Background: This study explores the pathways of nurse turnover in long-term care hospitals (LTCHs) and its underlying conditions in Korea. Although the factors of staying or leaving of nurses in LTCHs have been reported, few studies have examined the trajectory and conditions of nurses staying in and leaving LTCHs. Methods: A qualitative study design with a grounded theory approach was conducted. Data were collected in one-to-one interviews. Purposive and theoretical sampling led to the inclusion of 20 registered nurses from 15 LTCHs in South Korea. Results: Seeking work-life balance was the core category of the nurses' turnover pathway. The consequences of the nurses' turnover pathway were categorized into three groups: thriving, surviving, and leaving. Thriving nurses found meaning in their work, fostered good relationships, and saw opportunities for growth. Surviving nurses were enduring their jobs in LTCHs, having a work-life balance, and supportive nursing leaders. Leaving group nurses wished to leave LTCHs due to a lack of professional growth, unappealing work, continued conflict, and social stigma. Conclusion: This study provided the trajectory and conditions for nurses to enter, stay, move, or leave. Understanding the pathways for staying or leaving can be used as a strategy for successful retention of registered nurses in LTCHs.

• Atmosphere
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• v.17 no.4
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• pp.407-420
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• 2007

Optical characteristics of aerosols in Seoul are investigated from the measurements of sky radiance by Skyradiometer at Yonsei University from December 2005 to November 2006. Aerosol optical depth (AOD) shows a maximum in June due to weak ventilation and particle growth by aging process and hygroscopic effect. Single scattering albedo (SSA) and Angstrom Exponent (AE) show the lowest value in spring due to the Asian dust. It is clear that coarse mode is dominant in spring and fine mode is dominant in summer from the volume size distribution measured in this study. The explanations on the changes of aerosol loadings are provided through the correlation between AOD and AE, while the pattern of wavelength dependency related to particle size is shown through the correlation between SSA and AE. Backward trajectory analysis by HYSPLIT provides information about origin of aerosol, which allows us to classify the case according to the source region and the path distance. Although the direction of backward trajectory traces back mostly to west, coarse mode particle is dominant in the case of long pathway and fine mode particle is dominant in the case of short pathway. This discrepancy is caused by the regional difference of emitted particles.

• Korean Journal of Health Education and Promotion
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• v.29 no.1
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• pp.59-72
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• 2012

Objectives: This study aimed to estimate the trajectory of depressive symptoms among aged 20 years adults and examine the direct and indirect pathway linking socioeconomic status(education attainment, household income, occupation), alcohol use and depressive symptoms. It particularly focused on whether alcohol use would mediate the relationship between socioeconomic status and depressive symptoms. Methods: This study analysed 13,763 households of Korean Welfare Panel Study 1st, 2nd, 3rd data using Latent Growth Curve Modeling. Results: The results showed that study participants tend to decrease depressive symptoms with years. Similar to the findings of the previous studies, education attainment and household income among the socioeconomic status factors effected directly depressive symptoms and indirectly by mediating alcohol volume controlling sex and age. Conclusions: Based on findings of this study, the policy and practical implications were discussed.

• Atmosphere
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• v.23 no.1
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• pp.93-102
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• 2013

Atmospheric transport pathway of an air mass is an important constraint controlling the chemical properties of the air mass observed at a designated location. Such information could be utilized for understanding observed temporal variabilities in atmospheric concentrations of long-lived chemical compounds, of which sinks and/or sources are related particularly with natural and/or anthropogenic processes in the surface, and as well as for performing inversions to constrain the fluxes of such compounds. The Lagrangian particle dispersion model FLEXPART provides a useful tool for estimating detailed particle dispersion during atmospheric transport, a significant improvement over traditional "single-line" trajectory models that have been widely used. However, those without a modeling background seeking to create simple back-trajectory maps may find it challenging to optimize FLEXPART for their needs. In this study, we explain how to set up, operate, and optimize FLEXPART for back-trajectory analysis, and also provide automatization programs based on the open-source R language. Discussions include setting up an "AVAILABLE" file (directory of input meteorological fields stored on the computer), creating C-shell scripts for initiating FLEXPART runs and storing the output in directories designated by date, as wells as processing the FLEXPART output to create figures for a back-trajectory "footprint" (potential emission sensitivity within the boundary layer). Step by step instructions are explained for an example case of calculating back trajectories derived for Anmyeon-do, Korea for January 2011. One application is also demonstrated in interpreting observed variabilities in atmospheric $CO_2$ concentration at Anmyeon-do during this period. Back-trajectory modeling information introduced in this study should facilitate the creation and automation of most common back-trajectory calculation needs in atmospheric research.

• Journal of Environmental Science International
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• v.22 no.8
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• pp.1043-1052
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• 2013

This study was conducted to investigate the correlations between the $PM_{10}$ concentration trend and meteorological elements in the Gimhae region and analyze the transportation routes of air pollutants through back-trajectory analysis. Among the air quality measuring stations in the Gimhae regions, the $PM_{10}$ concentration of the Sambangdong station was higher than that of the Dongsangdong station. Also, an examination of the relationships between $PM_{10}$ concentration and meteorological elements showed that the greater the number of yellow dust occurrence days was and the lower the temperature and precipitation were, the higher the $PM_{10}$ concentration appeared. Furthermore, a cluster analysis through the HYSPLIT model showed that there were 4 clusters of trajectories that flowed into the Gimhae region and most of them originated in China. The meteorological characteristics of the four clusters were analyzed and they were similar to those of the air masses that influence South Korea. These analyses found that meteorological conditions affect the $PM_{10}$ concentration.

• Asian Journal of Atmospheric Environment
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• v.7 no.2
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• pp.114-119
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• 2013

The characteristics of Asian dust (AD) in Korea between 1997 and 2005 were investigated, focusing on peak 1-hour $PM_{10}$ concentrations during AD events at seven cities over the Korean Peninsula. The frequency of AD events decreased from Seoul to Busan, indicating the major pathway of AD in Korea was from northwest to southeast. AD events were most frequent in 2001 while peak concentrations during AD events were much higher in 2002. Recent works show that the trajectories from northerly directions increased during the 2000s and later (Chun, 2009; Kim, 2008). In this work, the fraction of trajectories from the northwest was the largest on the whole, although trajectories from each direction varied by city and year. It is presumed that high concentrations of $PM_{10}$ during AD events are generally associated with trajectories from the northwest rather than from the source region.

• Bulletin of the Korean Chemical Society
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• v.22 no.8
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• pp.889-896
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• 2001

The reaction of gas-phase atomic bromine with highly covered chemisorbed hydrogen atoms on a silicon surface is studied by use of the classical trajectory approach. It is found that the major reaction is the formation of HBr(g), and it proceeds th rough two modes, that is, direct Eley-Rideal and hot-atom mechanism. The HBr formation reaction takes place on a picosecond time scale with most of the reaction exothermicity depositing in the product vibration and translation. The adsorption of Br(g) on the surface is the second most efficient reaction pathway. The total reaction cross sections are $2.53{\AA}2$ for the HBr formation and $2.32{\AA}2$ for the adsorption of Br(g) at gas temperature 1500 K and surface temperature 300 K.

• Bulletin of the Korean Chemical Society
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• v.23 no.2
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• pp.205-214
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• 2002

The reaction of gas-phase atomic hydrogen with hydrogen atoms chemisorbed on a silicon surface is studied by use of the classical trajectory approach. Especially, we have focused on the mechanism changes with the hydrogen surface coverage difference. On the sparsely covered surface, the gas atom interacts with the preadsorbed hydrogen atom and adjacent bare surface sites. In this case, it is shown that the chemisorption of H(g) is of major importance. Nearly all of the chemisorption events accompany the desorption of H(ad), i.e., adisplacement reaction. Although much less important than the displacement reaction, the formation of $H_2(g)$ is the second most significant reaction pathway. At gas temperature of 1800 K and surface temperature of 300 K, the probabilities of these two reactions are 0.750 and 0.065, respectively. The adsorption of H(g) without dissociating H(ad) is found to be negligible. In the reaction pathway forming $H_2$, most of the reaction energy is carried by $H_2(g)$. Although the majority of $H_2(g)$ molecules are produced in sub-picosecond, direct-mode collisions, there is a small amount of $H_2(g)$ produced in multiple impact collisions, which is characteristic of complex-mode collisions. On the fully covered surface, it has been shown that the formation of $H_2(g)$ is of major importance. All reactive events occur on a subpicosecond scale, following the Eley-Rideal mechanism. At gas temperature of 1800 K and surface temperature of 300 K, the probability of the $H_2(g)$ formation reaction is 0.082. In this case, neither the gas atom trapping nor the displacement reaction has been found.

• Journal of the Korean Chemical Society
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• v.67 no.6
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• pp.407-414
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• 2023

The present study uses quasi-classical trajectory procedures to examine the vibrational relaxation and dissociation of the methyl and ring C-H bonds in excited methylpyrazine (MP) during collision with either N₂ or O₂. The energy-loss (-ΔE) of the excited MP is calculated as the total vibrational energy (E_T) of MP is increased in the range of 5,000 to 40,000cm^-1. The results indicate that the collision-induced vibrational relaxation of MP is not large, increasing gradually with increasing E_T between 5,000 and 30,000 cm^-1, but then decreasing with the further increase in E_T. In both N₂ and O₂ collisions, the vibrational relaxation of MP occurs mainly via the vibration-to-translation (V→T) and vibration-to-vibration (V→V) energy transfer pathways, while the vibration-to-rotation (V→R) energy transfer pathway is negligible. In both collision systems, the V→T transfer shows a similar pattern and amount of energy loss in the ET range of 5,000 to 40,000cm^-1, whereas the pattern and amount of energy transfer via the V→V pathway differs significantly between two collision systems. The collision-induced dissociation of the C-H_methyl or C-H_ring bond occurs when highly excited MP (65,000-72,000 cm^-1) interacts with the ground-state N₂ or O₂. Here, the dissociation probability is low (10^-4-10^-1), but increases exponentially with increasing vibrational excitation. This can be interpreted as the intermolecular interaction below E_T = 71,000 cm^-1. By contrast, the bond dissociation above E_T = 71,000 cm^-1 is due to the intramolecular energy flow between the excited C-H bonds. The probability of C-H_methyl dissociation is higher than that of C-H_ring dissociation.