• Title/Summary/Keyword: trace gas

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The Role of Fronts on the Vertical Transport of Atmospheric Pollutants (2-D model)

  • Nam, Jae-Cheol
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2003.11a
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    • pp.65-68
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    • 2003
  • A quantitative study of the amount of air transported between the boundary layer and the free atmosphere is important for understanding air quality and upper tropospheric ozone, which is a greenhouse gas. Frontal systems are known to be an effective mechanism for the vertical transport of pollutants. Numerical experiments have been performed with a simple two-dimensional front model to simulate vertical transport of trace gases within developing cold fronts. Three different trace gases experiments have been done numerically according to the different initial fields of trace gases such as aerosol, ozone and $H_2O_2$. Trace gas field tilts to the east while the front tilts to the west. Aerosol simulation shows that pollutants can be transported out of the boundary to altitudes of about 10 km. The stratospheric ozone is brought downwards in a tropopause fold behind of the frontal surface. The meridional gradient in trace gas ($H_2O_2$) can cause a complicate structure in the trace field by the meridional advection.

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Estimation of influening factors for efficient anaerobic digestion of high strength ammonia-nitrogen wastewater (고농도 암모니아성 질소 폐수의 효과적인 혐기성 처리를 위한 영향 인자 평가)

  • Park, Seyong;Park, Junghoon;Na, Hoysung;Kim, Moonil
    • Journal of Korean Society of Water and Wastewater
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    • v.26 no.5
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    • pp.649-658
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    • 2012
  • In this study, the influencing factors for efficient anaerobic digestion of high strength ammonia-nitrogen wastewater removal were investigated by testing biochemical methane potential test. In the influencing factors, the trace metals which could increase activity of anaerobic microorganisms, microbial concentration and types were evaluated. In the results, trace metals supplementation showed gas production amount higher than those without addition of trace metals. Among the tested trace metals, B, Ni, and Se were preferable to gas production. In the result of gas production according to the microbial concentration, the amount of gas production was proportional to the microbial concentration. In addition, the shortest lag time and the fastest gas production rate were achieved when the highest microbial concentration was tested. granule-type microorganism produced more gas than suspended-type microorganism. In conclusion, the efficient anaerobic digestion for high strength ammonia-nitrogen wastewater removal could be achieved by applying necessary trace metals injection and high concentration granule type microorganism.

Photoacoustic Effect of Ethene: Sound Generation due to Plant Hormone Gases

  • Ide, David W.;Park, Han Jung
    • Journal of the Korean Chemical Society
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    • v.61 no.4
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    • pp.139-142
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    • 2017
  • Ethene ($C_2H_4$), which is produced in plants as they mature, was used to study its photoacoustic properties using photoacoustic spectroscopy. Detection of trace amounts, with $N_2$ gas, of $C_2H_4$ gas was also applied. The gas was tested in various conditions-temperature, concentration of the gas, gas cell length, and power of the laser- to determine their effect on the photoacoustic signal, the ideal conditions to detect trace gas amounts, and concentration of $C_2H_4$ produced by an avocado and a banana. A detection limit of 10 ppm was determined for pure $C_2H_4$. A detection of 5% and 13% (by volume) concentration of $C_2H_4$ was produced for a ripening avocado and banana, respectively, in closed space.

Determination of trace impurities of HFC-134a by gas chromatograph with atomic emission detector (GC/AED) (GC/AED를 이용한 HFC-134a의 미량 불순물 분석)

  • Kim, Myeongja;Lim, Jeongsik;Lee, Jinbok;Lee, Jeongsoon
    • Analytical Science and Technology
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    • v.30 no.5
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    • pp.240-251
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    • 2017
  • 1,1,1,2-Tetrafluoroethane (HFC-134a), which is used as refrigerant in air conditioners, has been recently regulated as a greenhouse gas and is recommended for reuse by refining. It is very important to quantitatively analyze trace impurities present in the refrigerant to evaluate the criteria for reuse. In this study, trace impurities including C, H, Cl, and F, which are difficult to quantify because there are no reference materials, were quantitatively analyzed by a gas chromatograph-atomic emission detector (GC/AED); for this analysis, this was preceded by a qualitative analysis with a GC-mass selective detector (GC/MSD). In addition, the AED response was investigated using a hydrocarbon mixed reference material, which was proportional to the number of atoms in the component. Fifteen refrigerant components were detected as trace impurities in HFC-134a by qualitative analysis of trace impurities including C, H, Cl, and F in the samples. Based on the results of the qualitative analysis, quantitative analysis of trace impurities using AED showed that the highest mole fractions were for the $CHClF_2$ component ($45438.38{\mu}mol/mol$) in one sample and for the $C_2H_2ClF_3$ component ($1311.47{\mu}mol/mol$) in another sample. From this study, it has been shown that it is possible for this analytical method to be applied to the qualitative and quantitative analysis of trace compounds in refrigerants, which are difficult to quantify because of the absence of reference materials.

Assessment of clothing ventilation by a trace gas method (Trace gas법에 의한 의복의 환기 양상의 평가)

  • 추미선
    • Journal of the Korean Society of Clothing and Textiles
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    • v.21 no.8
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    • pp.1387-1395
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    • 1997
  • Effects of the ambient air temperature and the opening position on the pattern of the clothing ventilation of a thermal manikin wearing an impermeable blouse were investigated by the trace gas method. Under an isothermal condition, the ventilation was governed by diffusion, and the ventilation rate through the wrist-openings was greatly affected by the distance from the openings. Under non-isothermal conditions, however, the ventilation was accelerated by the convection driven by the temperature gradient between the clothing microclimate and the surrounding air; the greater the temperature gradient, the greater the ventilation. Even though it was certainly affected by the ambient air temperature, the ventilation rate was more significantly influenced by the position of openings. The ventilation patterns at the arm and the body were distinctive.

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A study on particles flow through gas injection in pot (가스분사를 통한 Pot내에서의 입자 거동연구)

  • Kim Sungsu;Baek Jehyun;Choi Minsuk
    • 한국전산유체공학회:학술대회논문집
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    • 2002.10a
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    • pp.144-149
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    • 2002
  • This paper presents the result of numerical simulation of particles trace following melted zinc movement with nitrogen gas injection. The code of the computational fluid dynamics for numerical analysis was performed using FLUENT related to CFD. As application model, there was applied Eulerian multiphase model for simulation of melted zinc movement at first and then was used stochastic tracking technique for particles trace secondarily. Numerical simulation results are shown that particles move to the same direction as the movement of melted zinc.

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Effect of Swirling Flow by Normal Injection of Secondary Air on the Gas Residence Time and Mixing Characteristics in a Lab-Scale Cold Model Combustor

  • Shin, D.;Park, S.;Jeon, B.;Yu, T.;Hwang, J.
    • Journal of Mechanical Science and Technology
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    • v.20 no.12
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    • pp.2284-2291
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    • 2006
  • The present study investigates gas residence time and mixing characteristics for various swirl numbers generated by injection of secondary air into a lab-scale cylindrical combustor. Fine dust particles and butane gas were injected into the test chamber to study the gas residence time and mixing characteristics, respectively. The mixing characteristics were evaluated by standard deviation value of trace gas concentration at different measurement points. The measurement points were located 25 mm above the secondary air injection position. The trace gas concentration was detected by a gas analyzer. The gas residence time was estimated by measuring the temporal pressure difference across a filter media where the particles were captured. The swirl number of 20 for secondary air injection angle of 5$^{\circ}$ gave the best condition: long gas residence time and good mixing performance. Numerical calculations were also carried out to study the physical meanings of the experimental results, which showed good agreement with numerical results.

Tracing the growth of the supermassive black holes with halo mergers

  • Byeon, Woowon;Kim, Juhan;Park, Myeong-Gu
    • The Bulletin of The Korean Astronomical Society
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    • v.40 no.2
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    • pp.47.1-47.1
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    • 2015
  • The formation mechanism of supermassive black holes (SMBHs) at the center of galaxies remains an open fundamental question. Black holes (BHs) are believed to grow by accretion of gas or by merging with other BHs. Motivated by the observation of luminous quasar around redshift z ~ 7 with SMBH mass up to 109 solar mass, we follow the growth of the early assembly of SMBHs that trace the hierarchical evolution of dark matter halos derived from large cosmological simulations. The initial masses of BH seeds in the first halos were set up according to the BH mass - halo mass relation. We assume that mergers of host galaxies cause loss of angular momentum of gas and trigger episodes of gas accretion onto BHs for available durations and at the end of each episode of accretion, BHs merge immediately. We trace the evolution of BH masses for various scenarios for central gas properties in halos. We estimate the BH to halo mass ratio and BH mass function at each redshift.

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Use of In-Situ Optical Emission Spectroscopy for Leak Fault Detection and Classification in Plasma Etching

  • Lee, Ho Jae;Seo, Dong-Sun;May, Gary S.;Hong, Sang Jeen
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.13 no.4
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    • pp.395-401
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    • 2013
  • In-situ optical emission spectroscopy (OES) is employed for leak detection in plasma etching system. A misprocessing is reported for significantly reduced silicon etch rate with chlorine gas, and OES is used as a supplementary sensor to analyze the gas phase species that reside in the process chamber. Potential cause of misprocessing reaches to chamber O-ring wear out, MFC leaks, and/or leak at gas delivery line, and experiments are performed to funnel down the potential of the cause. While monitoring the plasma chemistry of the process chamber using OES, the emission trace for nitrogen species is observed at the chlorine gas supply. No trace of nitrogen species is found in other than chlorine gas supply, and we found that the amount of chlorine gas is slightly fluctuating. We successfully found the root cause of the reported misprocessing which may jeopardize the quality of thin film processing. Based on a quantitative analysis of the amount of nitrogen observed in the chamber, we conclude that the source of the leak is the fitting of the chlorine mass flow controller with the amount of around 2-5 sccm.

Importance of Extracellular Enzyme Activities in Northern Peatland Biogeochemistry-Possible Coupling with Trace Gas Emission and DOC Dynamics (북구 이탄습지의 생지화학적 반응에 있어서 체외효소의 중요성-미량기체 발생량 및 용존유기탄소 동태와의 연관성에 대하여)

  • Freeman, Chris;Park, Seok-Soon;Kang, Ho-Jeong
    • Korean Journal of Ecology and Environment
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    • v.39 no.4 s.118
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    • pp.435-444
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    • 2006
  • A suite of extracellular enzyme activities involved in organic carbon decomposition were determined in three northern peatlands (a bog, a fen, and a swamp) over a 12 month period along with trace gas ($CO_2$ and $N_2O$) flux and DOC dynamics in the wetlands. The activities varied $0.008-0.066\;{\mu}mole\;g^{-1}\;min^{-1}$, $0.003-0.021\;{\mu}mole\;g^{-1}\;min^{-1}$, $0.003-0.016\;{\mu}mole\;g^{-1}\;min^{-1}$, $0.004-0.047\;{\mu}mole\;g^{-1}\;min^{-1}$, for ${\beta}-glucosidase$, cellobiohydrolase, ${\beta}-xylosidase$, and N-acetylglucosaminidase, respectively. In general, the activities were highest in the forested swamp followed by the fen and the bog. When the data from three wetlands are combined, the enzyme activities exhibited significant positive correlations with trace gas emission and available carbon. Further, the average activity of 4 enzymes explained about 20-40% of the variations of trace gas emssion and available carbon. The results indicate that enzymes related to the mineralization of organic carbon may play an important role in trace gas flux and DOC dynamics in northern peatlands.