• 터널과지하공간
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• 제14권6호
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• pp.391-398
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• 2004

시추공에서 관찰된 절리면의 방향성과 위치자료를 이용하여 개착면에서의 trace 분포를 예측하는 대수학적 기법을 개발하였다. 절리 trace 예측은 절리면과 투영면의 3차원 평면식을 활용하여 대수학적으로 수행되며, 개별 불연속면의 영속성을 고려하여 투영 영역 내에서 trace가 표출되는 범위가 산정된다. 절리 예측기법을 활용하여 슬럼핑 현상에 의해 구조적으로 불안정한 김해 내삼사면의 안정성 및 보강 계획의 적정성을 분석하였다. DOM 시추작업을 수행하여 암반구조 특성을 조사하였으며, 사면 파괴를 유발시킬 수 있는 절리들을 추출하여 심도별 지반거동 특성을 분석하였다. 또한, 사면보강을 위하여 계획된 앵커 정착부에서의 절리분포 및 거동양상을 분석하고 앵커 보강의 효율성을 고찰하였다.

• Advances in nano research
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• 제10권3호
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• pp.295-312
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• 2021

A new ionic liquid functionalized magnetic silica nanoparticle was synthesized and characterized and tested as an adsorbent. The adsorbent was used for magnetic solid phase extraction on ICP-MS method. Simultaneous determination of precious metal Au has been addressed. The method is simple and fast and has been applied to standard water and surface water analysis. A new method for separation/analysis of trace precious metal Au by Magnetron Solid Phase Extraction (MSPE) combined with ICP-MS. The element to be tested is rapidly adsorbed on CoFe2O4@SiO2@[BMIM]PF6 composite nano-adsorbent and eluted with thiourea. The method has a preconcentration factor of 9.5-fold. This method has been successfully applied to the determination of gold in actual water samples. Hydrophobic Ionic Liquids (ILs) 1-butyl-3-methylimidazole hexafluorophosphate ([BMIM]PF6) coated CoFe2O4@SiO2 nanoparticles with core-shell structure to prepare magnetic solid phase extraction agent (CoFe2O4@SiO2@ILs) and establish a new method of MSPE coupled with inductively coupled plasma mass spectrometry for separation/analysis of trace gold. The results showed that trace gold was adsorbed rapidly by CoFe2O4@SiO2@[BMIM]PF6 and eluanted by thiourea. Under the optimal conditions, preconcentration factor of the proposed method was 9.5-fold. The linear range, detection limit, correlation coefficient (R) and relative standard deviation (RSD) were found to be 0.01~1000.00 ng·mL-1, 0.001 ng·mL-1, 0.9990 and 3.4% (n = 11, c = 4.5 ng·mL-1). The CoFe2O4@SiO2 nanoparticles could be used repeatedly for 8 times. This proposed method has been successfully applied to the determination of trace gold in water samples.

• 한국식품위생안전성학회지
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• 제12권4호
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• pp.328-332
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• 1997

In order to investigate the trace metals in Korean foods, the contents of Magnesium, Zinc, Manganese, Molybdenum and Selenium are studied in this paper. As show in the Table 1; a total of 250 samples of 25 species were analyzed by neutron activation analysis. The results obtained were as follows; 1. The overall ranges and mean (mg/100 g) were; Mg, 12.212∼151.346(55.164); Zn, 0.045∼38.180 (2.473); Mn, 0.003∼0.796 (0.225);Mo, ND∼0.035 (0.007); Se, ND∼0.069 (0.016). 2. The levels of all metals except Mo in shell fishes were high and the level of Mo in spices was higher than that in other foods. 3. The levels of Zn and Mo in oyster were higher than another spcies.

• 분석과학
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• 제11권6호
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• pp.499-504
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• 1998

An analytical method for the simultaneous measurement of trace Cu, Sn, and Bi in sea water has been investigated by Inductively Coupled Plasma-Mass Spectrometry. Amberlite IRC-718 resin was used as a solid phase in solid-liquid extraction technique for the removal of matrix interferences such as Na, S, P, and other polyatomic ion species. Recoveries of 99.8% for Cu, 99.6% for Sn, and 97.9% for Bi were obtained for the standard spiked sample. The developed method was applied to analysis of trace metals in sea water.

• 대한공간정보학회지
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• 제19권4호
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• pp.91-99
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• 2011

대규모 홍수가 빈발하여 홍수피해 규모가 천문학적으로 커지고 있는 현실에서 침수지역에 대한 침수흔적조사, 침수예상분석, 대피계획 수립 등 종합적인 검토 분석의 결과를 지도위에 표현하는 재해지도는 비구조적인 홍수방어 대책의 주요한 수단이 되고 있다. 특히, 태풍, 호우, 해일 등으로 인한 침수흔적을 조사하여 표시한 침수흔적도는 침수예상도, 재해정보지도 등과 유기적인 관계를 지니고 있는 방재 기본도임에도 불구하고 작성 예산 문제, 작성 시기 지연 및 침수흔적 표시 관리가 미흡하여 침수흔적도 작성이 불가능한 경우가 많다. 따라서 본 연구에서는 소방방재청에서 제시한 침수흔적도 제작 지침을 토대로 과거 홍수재해가 빈번하게 발생했던 지역을 대상으로 침수 피해정보와 3차원 정밀 지형정보(DEM)을 이용한 침수흔적도 작성을 통해 구축 정확도를 향상하는 방안을 제시하였다.

• 한국시뮬레이션학회논문지
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• 제18권4호
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• pp.185-195
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• 2009

최근 시스템들이 복잡해지면서 시뮬레이션을 통한 시스템의 분석이 주목을 받고 있다. 시뮬레이션 분석에서 가장 핵심적인 부분 중의 하나가 시뮬레이션 모델의 검증이며, 이 과정을 통하여 시뮬레이션 모델이 얼마나 실제 시스템을 대변할 수 있는지를 판단한다. 모델의 검증에서 시뮬레이션 모델과 실제시스템의 데이터를 비교할 때 발생하는 차이는 입력 데이터의 차이에 의한 영향도 있으며, 이를 통한 모델의 검증 결과는 높은 신뢰성을 보장하지 못한다. 따라서 이 논문에서는 실제와 동일한 입력 데이터를 바탕으로 하는 Trace-Driven 시뮬레이션을 기반으로 모델을 설계하였다. 한편, 출력데이터들을 하나의 통계량을 통한 검증이 아닌 클래스 별 검증을 하기 위해 데이터마이닝 분야에서 분류기의 성능을 판단하는 F 척도를 응용하여 시뮬레이션 모델의 검증을 수행하였다. 그 결과, 제안된 검증 방법은 정밀한 모델의 검증을 가능하게 하고, 검증 시에 피드백을 제공함으로써 용이한 수정 작업을 가능하게 한다.

• 한국지하수토양환경학회지:지하수토양환경
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• 제15권1호
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• pp.9-18
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• 2010

In this study, Solid-phase micro-extraction (SPME) with Gas Chromatograph using Flame Ionization Detector (GC/FID) was studied as a possible alternative to liquid-liquid extraction for the analysis of Methyl tert-butyl ether (MTBE) and Tertiary-butyl ether (TBA) in water and an optimization condition of trace analysis of MTBE and TBA using the design of experiment (DOE) was described. The aim of our research was to apply experimental design methodology in the optimization condition of trace analysis of fuel oxygenated compounds in soil-phase microextraction with GC/FID. The reactions of SPME were mathematically described as a function of parameters of Temp ($X_1$), Volume ($X_2$), Time ($X_3$) and Salt ($X_4$) being modeled by the use of the partial factorial designs, which was used for fitting 2nd order response surface models and was alternative to central composite designs. The model predicted agreed with the experimentally observed result ($Y_1$(MTBE, $R^2$ = 0.96, $Y_2$ (TBA, $R^2$ = 0.98)). The estimated ridge of the expected maximum responses and optimal conditions for MTBE and TBA were 278.13 and (Temp ($X_1$) = $48.40^{\circ}C$, Volume ($X_2$) = 73.04 mL, Time ($X_3$) = 11.51 min and Salt ($X_4$) = 12,50 mg/L), and 127.89 and (Temp ($X_1$) = $52.12^{\circ}C$, Volume ($X_2$) = 88.88mL, Time ($X_3$) = 65.40 min and Salt ($X_4$) = 12,50 mg/L), respectively.

• 대한임상검사과학회지
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• 제41권1호
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• pp.31-36
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• 2009

The exposure of human beings to toxic trace metals (Cu, Zn) continues to be an important public health issue and concern. This study was conducted to assess the exposure to trace metals (Cu, Zn) in the general Korean population by inductively coupled plasma mass spectrometry (ICP-MS) and Atomic absorption spectrometry (AAS). Serum samples were obtained from 40 healthy volunteers. Specimens were collected in special container and we applied sample processing to minimize contamination. We used ICP-MS and AAS to analyze simultaneously the concentration of metals including copper, zinc. Distribution of trace metal levels in the general healthy population showed lower values. The results in this study can provide background data for clinical studies associated with trace metal exposure in the korean population.

• 한국대기환경학회지
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• 제12권1호
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• pp.67-77
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• 1996

Total suspended particulate matters (TSP) were collected based on a size segregation method by a cascade impactor for 6 consecutive years (form Dec. 1989 to sep. 1994) in the Kyung Hee University-Suwon Campus, and 6 trace metals (Ca, Si, Fe, Pb, Cu, Zn) were determined by an x-ray fluorescence spectroscopy. Total number of samples collected during the study are 118 sets and each set of sample comsists of 9 filters. The levels of TSP and 6 trace metals were then used to examine seasonal and annual variations with respects to their size distributions. For statistical analyses, raw data were initially transformed by both logarithmic and root transformating to approximately normalize them, and then size distribution functions for each trace element were separately developed season-to-season by a regression analysis in order to obtain maximum amount of physical information, Subsequently, each developed model was verified by comparing with supervised data collected on 1994. The result showed that each prediction model was in good agreement except the fall, partly due to lack of the data collected on fall, 1994.

• Bulletin of the Korean Chemical Society
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• 제19권1호
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• pp.50-56
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• 1998

A solvent sublation was studied for the determination of trace Cd, Co, Cu and Ni in water samples. Ammonium pyrrolidine dithiocarbamate (APDC) was used as a complexing agent. Experimental conditions such as pH of solution, amounts of APDC, the type and amount of surfactant, the type of solvent, etc. were optimized for the effective sublation of analytes. After metal-PDC complexes were formed in sample solutions of pH 2.5, the precipitate-type complexes were floated in a flotation cell with an aid of sodium lauryl sulfate as a surfactant and by bubbling with nitrogen gas. The precipitates were dissolved and separated into the surface layer of methyl iso-butyl ketone (MIBK). The analytes preconcentrated were determined by a graphite furnace atomic absorption spectrophotometry (GF-AAS). Extractability of each element was 88% for Cd(Ⅱ), 86% for Co(Ⅱ), 95% for Cu(Ⅱ) and 76% for Ni(Ⅱ), respectively. And this procedure was applied to the analysis of real samples. From the recoveries of more than 92%, it was concluded that this method could be simple and applicable for the determination of trace elements in various water samples of a large volume.