• 제목/요약/키워드: trace analysis

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익산지역 가을철 대기 중 호흡성 및 흡입성 먼지입자의 화학조성 (Chemical Composition of Respirable PM2.5 and Inhalable PM10 in Iksan City during Fall, 2004)

  • 강공언
    • 한국환경보건학회지
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    • 제36권1호
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    • pp.61-71
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    • 2010
  • Intensive measurements of airborne respirable $PM_{2.5}$ and inhalable $PM_{2.5}$ were conducted in the downtown area of Iksan city. The $PM_{2.5}$ and $PM_{2.5}$ samples were collected twice a day in the Iksan city of Korea from October 17 to November 1, 2004. The purpose of the study was to determine the inorganic water-soluble components and trace elements of $PM_{2.5}$ and $PM_{2.5}$ in the atmospheric environment and estimate the contribution rate of major chemical components from a mass balance of all measured particulate species. The chemical analysis for PM samples was conducted for water-soluble inorganic ions using ion chromatography and trace elements using PIXE analysis. The mean concentrations of respirable $PM_{2.5}$ and inhalable $PM_{2.5}$ were $51.4{\pm}29.7$ and $79.5{\pm}39.6\;{\mu}g/m^3$, respectively, and the ratio was 0.62. The ion species of $NO_3$, $SO_4^2$, and $NH_4^+$ were abundant in both $PM_{2.5}$ and $PM_{2.5}$. These components predominated in respirable $PM_{2.5}$ fraction, while $Na^+$, $Mg^{2+}$, $Ca^{2+}$ mostly existed in coarse particle mode. Elemental components of S, Cl, K, and Si were abundant in both $PM_{2.5}$ and $PM_{2.5}$. These elements, except for Si, were considered to be emitted from anthropogenic sources, while Si, Al, Fe, Ca existed mainly in coarse particle mode and were considered to be emitted from crustal materials. The averaged mass balance analysis showed that ammonium nitrate, ammonium sulfate, crustal component, and other trace elements were composed of 18.4%, 13.2%, 4.8%, 3.5% for PM2.5 and 17.0%, 11.6%, 13.7%, 4.4% for $PM_{2.5}$, respectively.

3-Stage DRUM 샘플러를 이용한 광주 도심지역의 봄철과 여름철 PM2.5 원소적 조성 비교 (Elemental Composition of PM2.5 Particulate with a 3-Stage DRUM Sampler during Spring and Summer Seasons in Urban Area of Gwangju, Korea)

  • 류성윤;김영준
    • 한국대기환경학회지
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    • 제21권6호
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    • pp.699-708
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    • 2005
  • To characterize the elemental composition of fine particles in urban area, $PM_{2.5}$ was collected by a 3-stage DRUM impactor at Gwangju during spring and summer. Time and size resolved concentrations for 19 trace elements were obtained by synchrotron X-Ray fluorescence analysis. Trace elements in summer were distributed in smaller size range compared to those in spring. Almost trace element concentrations in fine particles were highly increased during the Asian dust. In spring, soil elements such as Si, K, Ca, Ti and Fe had low enrichment factors indicating the dominant influence of soil dust. However, all elements had high enrichment factors in summer implying that these elements could be emitted from the anthropogenic sources. Factor analysis was conducted with the elemental composition data in order to identify anthropogenic sources of aerosols in urban area during spring and summer. Fine particles in spring have several sources such as soil dust originating from China continental region, coal and oil combustion, biomass burning, sea salt, ferrous and nonferrous metal sources. On the other hand, fine particles in summer were influenced by road dust, gasoline vehicle as well as coal and oil combustion, sea salt, ferrous and nonferrous metal sources.

임계값 부트스트랩을 사용한 시뮬레이션 입력 시나리오의 생성 (Generation of Simulation input Stream using Threshold Bootstrap)

  • 김윤배;김재범
    • 경영과학
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    • 제22권1호
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    • pp.15-26
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    • 2005
  • The bootstrap is a method of computational inference that simulates the creation of new data by resampling from a single data set. We propose a new job for the bootstrap: generating inputs from one historical trace using Threshold Bootstrap. In this regard, the most important quality of bootstrap samples is that they be functionally indistinguishable from independent samples of the same stochastic process. We describe a quantitative measure of difference between two time series, and demonstrate the sensitivity of this measure for discriminating between two data generating processes. Utilizing this distance measure for the task of generating inputs, we show a way of tuning the bootstrap using a single observed trace. This application of the threshold bootstrap will be a powerful tool for Monte Carlo simulation. Monte Carlo simulation analysis relies on built-in input generators. These generators make unrealistic assumptions about independence and marginal distributions. The alternative source of inputs, historical trace data, though realistic by definition, provides only a single input stream for simulation. One benefit of our method would be expanding the number of inputs achieving reality by driving system models with actual historical input series. Another benefit might be the automatic generation of lifelike scenarios for the field of finance.

산업 도시의 산업단지 부지와 주거 지역의 대기 중 호흡성 분진과 구성 미량 원소의 특성 (Characteristics of Atmospheric Respirable Particulate Matters and Trace Elements within Industrial Complex and Residential Sites in an Industrial City)

  • 김모근;신승호;조완근
    • Environmental Analysis Health and Toxicology
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    • 제25권1호
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    • pp.27-40
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    • 2010
  • The current study was designed to scientifically evaluate the atmospheric particulate pollution in residences relative to their proximity to a Korean major iron/metal industrial complex (IMIC). This objective was achieved by measuring the concentrations and elemental composition of particulate matter with aerodynamic diameters equal to or less than 10 ${\mu}m$(PM10) in industrial ambient air from IMIC and residential ambient air with relative proximities to IMIC. The trace metals were analyzed using an inductively coupled plasma-atomic emission spectroscopy (ICP-AES). The industrial mean values exceeded the Korean year/70-${\mu}g/m^3$ standard for PM10, whereas the residential mean values did not. However, the maximum residential values did exceed or were close to the Korean PM10 year standard. For individual elements, the ambient concentrations ranged widely from values in the order of a few $ng/m^3$ to thousands of $ng/m^3$. The residential mean mass concentrations in the PM10 measured in the present study were higher than or similar to those reported in earlier studies. This study suggests that residents in neighborhoods near the IMIC are exposedto elevated particulate levels compared to residents living further away from such a source.

고온고습 전원인가 시험에서 Cl에 의한 이온 마이그레이션 불량 (Chlorine effect on ion migration for PCBs under temperature-humidity bias test)

  • 허석환;신안섭
    • Journal of Welding and Joining
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    • 제33권3호
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    • pp.47-53
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    • 2015
  • By the trends of electronic package to be more integrative, the fine Cu trace pitch of organic PCB is required to be a robust design. In this study, the short circuit failure mechanism of PCB with a Cl element under the Temperature humidity bias test ($85^{\circ}C$/85%RH/3.5V) was examined by micro-structural study. A focused ion beam (FIB) and an electron probe micro analysis (EPMA) were used to polish the cross sections to reveal details of the microstructure of the failure mode. It is found that $CuCl_x$ were formed and grown on Cu trace during the $170^{\circ}C$/3hrs and that $CuCl_x$ was decomposed into Cu dendrite and $Cl_2$ gas during the $85^{\circ}C$/85%RH/3.5V. It is suggested that Cu dendrites formed on Cu trace lead to a short circuit failure between a pair of Cu traces.

수용액 중 극미량 니켈(II)과 아연(II)의 흡착농축 및 ICP-AES 정량에 관한 연구 (Adsorptive Preconcentration and ICP-AES Determination for Trace Amount of Ni(II) and Zn(II) in Aqueous Solution)

  • 최종문;최선도
    • 한국환경보건학회지
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    • 제31권1호
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    • pp.73-78
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    • 2005
  • A determination method of trace Ni(II) and Zn(II) in aqueous solution was studied and developed by adsorbing on titanium dioxide. For this purpose, several conditions were optimized such as the pH of sample solution, adsorption time, the types and concentration acid, and desorption time. The titanium dioxide was added in sample solution which was pH adjusted. Then, the sample solution was stirred for 5 minutes. This mixture was stored in room temperature for 30 minutes to allow adsorption. After filtering and washing the titanium dioxide, the analytes were dissolved from the titanium dioxide on membrane filter by an ultrasonic vibration for 10 minutes in 1.0 M $HNO_3$ solution. Then, this sample solution was analysed using ICP-AES. The adsorption equilibrium was achieved in 30 minutes. The desorption was the most of effective with 1.0 M(mol/l) nitric acid solution, and desorption time was 10 minutes. This procedure was applied for the analysis of two real samples, i.e., brown seaweed and tangle. The recoveries of Ni(II) and Zn(II) in spiked samples were 89.4${\sim}$98.9% for analytes.

Content-based Configuration Management System for Software Research and Development Document Artifacts

  • Baek, Dusan;Lee, Byungjeong;Lee, Jung-Won
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • 제10권3호
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    • pp.1404-1415
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    • 2016
  • Because of the properties of software such as invisibility, complexity, and changeability, software configuration management (SCM) for software artifacts generated during software life-cycle has been used for guarantee of the quality of the software. However, the existing SCM system has only focused on code artifacts and software development document artifacts such as Software Requirements Specification (SRS), Software Design Description (SDD), and Software Test Description (STD). Moreover, software research-oriented project comes out late the code artifacts and the software development document artifacts. Therefore, there is a need for trace and management of software research document artifacts composed of highly abstracted non-functional requirements like 'the purpose of the project', 'the objectives', and 'the progress' before generation of the code artifacts and the software development document artifacts for a long time. Nevertheless, the existing SCM system cannot trace and manage them. In this paper, we propose content-based configuration management system comprised of the relevance link generation phase and content-based testing phase to trace and manage them. The preliminary application results show applicability and feasibility of the proposed system.

농산물 중의 미량금속함량 분석 (Analysis of Trace Metal in Agricultural Products)

  • 박정숙;나환식
    • 한국식품영양학회지
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    • 제13권6호
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    • pp.595-601
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    • 2000
  • 광주광역시에서 생산·유통되고 있는 농산물 총 80개 품목(양파, 파, 마늘, 상치, 배추, 고추, 시금치. 무, 배, 복숭아)을 구입하여 중금속 및 미량금속 함유량을 조사한 결과 다음과 같은 결과를 얻었다. 수은은 모든 검체에서 검출되지 않았으며, 비소는 0.001 ppm이하의 결과를 보였다. 카드뮴과 납의 경우 각각 N.D.∼0.088 ppm과 N.D.∼0.096 ppm으로 검출되어 자연 함유량 수준으로 판단된다. 또한 농산물의 생육에 필수 원소로 작용하는 구리, 망간과 아연의 함유량은 0.109∼1.072 ppm, 0.829∼6.195 ppm, 0.731 ∼6.176 ppm으로 검출되었다.

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Effect of Oxytocin Administration on Certain Minerals in the Milk of Buffaloes (Bubalus bubalis)

  • Singh, Mahendra;Aggarwal, Anjuli
    • Asian-Australasian Journal of Animal Sciences
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    • 제14권11호
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    • pp.1523-1526
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    • 2001
  • To study the secretion of trace elements during early lactation, twelve lactating Murrah buffaloes were selected from the herd of the institute. The buffaloes were divided into two groups of six each. Buffaloes of group I were not injected and served as control. Buffaloes of group II received oxytocin injection (2.5 I.U.) intramuscularly for a period of five days for let down of milk. Milk samples were collected from both groups of buffaloes five days before, during and after the administration of oxytocin. Aliquots of milk samples from each buffalo were composited in proportion to their milk yield and used for analysis of trace elements in milk. In both the groups of buffaloes Cu, Mg, Fe, Zn and Mn contents did not vary significantly between animals. However, Ca levels varied significantly (p<0.01) between animals. Administration of oxytocin influenced (p<0.01) Cu, Mg, Zn, Fe and Mn secretion in milk. However, Ca secretion was not affected by oxytocin administration. Secretion of these elements also varied significantly during different days of the study. Zinc content of milk in the control group also varied significantly (p<0.01) during different days and periods of study indicating thereby no effect of oxytocin. The study indicated that administration of oxytocin increases Cu and Mn content and decreases Mg, Fe and Zn content without altering the Ca concentration of milk.

Matrix Modification for Graphite Furnace Atomic Absorption Spectrophotometric Determination of Volatile Elements(III) Trace Bismuth

  • Kim, Young-Sang;Choi, Jong-Moon;Kim, Young-Man
    • 분석과학
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    • 제8권4호
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    • pp.435-442
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    • 1995
  • A matrix modification was studied for the determination of trace bismuth in water samples by graphite furnace atomic absorption spectrophotometry. The type and quantity of modifiers as well as the use of auxiliary modifiers were investigated to realize the efficient modification. Palladium was chosen as a single modifier. By the addition of palladium($5{\mu}g/mL$) to 100 ng/mL bismuth solution, the temperatures could be raised from $500^{\circ}C$ to $1,300^{\circ}C$ for the charring and from $2,000^{\circ}C$ to $2,200^{\circ}C$ for the atomization as well as the sensitivity and reproducibility were improved. The absorbance of bismuth was maximum and not changed in the range of Pd $3-25{\mu}g/mL$. And several materials were examined as an auxiliary modifier. The mixed solution of $1{\mu}g/mL$ palladium and $200{\mu}g/mL$ nickel have raised the temperatures as with $5{\mu}g/mL$ palladium only. The maximum absorbance of bismuth was shown in the nickel concentration range of $100-300{\mu}g/mL$ in $1{\mu}g/mL$ palladium modified system. With such optimum conditions, the trace amount of bismuth in several water samples could be determined by a calibration curve method, and good recoveries were also obtained.

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