• 분석과학
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• 제32권6호
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• pp.233-242
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• 2019

Substance identification is the first step of the REACH registration. It is essential in terms of Classification, Labelling and Packaging (CLP) regulation and because even trace amounts of impurities or additives can affect the classification. In this study, a scheme for the screening, quantification, and interpretation of trace amounts of hazardous inorganic substances is proposed to detect the presence of more than 0.1% hazardous inorganic substances that have been affecting the hazard classification. An exemplary list of hazardous inorganic substances was created from the substances of very high concern (SVHCs) in REACH. Among 201 SVHCs, there were 67 inorganic SVHCs containing at least one or ~2-3 heavy metals, such as As, Cd, Co, Cr, Pb, Sb, and Sn, in their molecular formula. The inorganic SVHCs are listed in excel format with a search function for these heavy metals so that the hazardous inorganic substances, including each heavy metal and the calculated ratio of its atomic weight to molecular weight of the hazardous inorganic substance containing it, can be searched. The case study was conducted to confirm the validity of the established scheme with zinc oxide (ZnO). In a substance that is made of ZnO, Pb was screened by XRF analysis and measured to be 0.04% (w/w) by ICP-OES analysis. After referring to the list, the presence of Pb was interpreted just as an impurity, but not as an impurity relevant for the classification. Future studies are needed to expand on this exemplary list of hazardous inorganic substances using proper regulatory data sources.

• 한국자기학회:학술대회 개요집
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• 한국자기학회 2007년도 The 1st International Symposium on Advanced Magnetic Materials
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• pp.8.2-8.2
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• 2007

• Bulletin of the Korean Chemical Society
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• 제16권8호
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• pp.748-754
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• 1995

• 펄프종이기술
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• 제35권1호
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• pp.7-12
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• 2003

The test results for water repellency of paper and paperboard according to KS M 7057 can readily be influenced by an operator's bias. In order to discard such bias, the automatic analysis program of water repellency was developed based on different shape features of a liquid trace formed on a specimen. That is, the shape of a liquid track flowing down on the specimen with an angle of $45^{\circ}$ was evaluated according to width variation between head and tail of the trace($S_{Hr}$), uniformity of a liquid flow($S_{d}$), length of long traces($L_{SHr}$), eccentricity of liquid traces($E_{i}$), and then was recognized as a specific degree of water repellency. Finally, the automatic analysis system of water repellency based upon KS M 7057 made it possible to readily measure water resistance of paper and paperboards classified into R0 to R10.

• 분석과학
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• 제11권4호
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• pp.311-315
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• 1998

Ultra trace metal impurities of high-purity sulfuric acid for semiconductor process have been determined in the concentration of lower than ppb (ng/g) level using high resolution inductively coupled plasma mass spectrometer (HR-ICP-MS).The acid samples were evaporated and concentrated by the factor of 20. No clement in the acids exceeded 1ppb level and most of the clements were determined below 10ppt (pg/g). Elements without spectral interference in mass spectrum, such as In, V, Mn, etc, were determined in the concentration of below 1 ppt level The recoveries in the range of 72% to 127.2% for 0.5 ppb spiked sample were obtained.

• Nuclear Engineering and Technology
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• 제19권4호
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• pp.242-248
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• 1987

레이저를 이용한 형광분석 방법과 형광의 세기를 증대시켜주는 'Fluran' 용액을 가함으로써 용액속에 존재하는 미량의 우라늄을 정착하고 신속하게 분석할 수 있는 새로운 장치를 개발하였다. 표준용액의 첨가 방법을 이용하여 시료의 조성 변화에 따른 형광의 방해효과를 보정할 수 있었고 5%이내의 정밀도를 갖는 0.1ppb의 측정 하한치를 얻을 수 있었다. 또한 여러 종류의 시료에 대하여 레이저를 이용한 형광분석 방법의 결과와 다른 측정 방법에 의한 결과를 상호 비교, 분석하였다.

• 한국자동차공학회논문집
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• 제4권3호
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• pp.73-82
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• 1996

Vehicle movement detection by high order correlation analysis of optical sensor array signals is introduced. The optical sensors observe the road which is assumed to be a non-uniform speckle-like texture. The measurement system is applicable to general robotic movement detection because : 1) It employs a non-contact measurement method, 2) The system can be made very compact, and 3) It enables approximation of the movement trace with a sequence of arcs instead of the conventional connection of simple line segments. In this work, we have looked into estimation of running trace of an autonomous vehicle by observing the ground pattern.

• 디지털산업정보학회논문지
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• 제16권1호
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• pp.67-78
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• 2020

Typical security solutions such as intrusion detection system are not suitable for detecting advanced persistent attack(APT), because they cannot draw the big picture from trivial events of security solutions. Researches on techniques for detecting multiple stage attacks by analyzing the correlations between security events or alerts are being actively conducted in academic field. However, these studies still use events from existing security system, and there is insufficient research on the structure of the entire security system suitable for advanced persistent attacks. In this paper, we propose an attack path and intention recognition system suitable for multiple stage attacks like advanced persistent attack detection. The proposed system defines the trace format and overall structure of the system that detects APT attacks based on the correlation and behavior analysis, and is designed with a structure of detection system using deep learning and big data technology, etc.

• 분석과학
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• 제18권6호
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• pp.520-528
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• 2005

Two biological Certified Reference Materials (CRMs), KRISS 108-04-001 (oyster tissue) and 108-05-001 (water dropwort stem), were prepared by Korea Research Institute of Standards and Science (KRISS)during FY '01. The certified values of these materials had been determined by Isotope Dilution Mass Spectrometry (IDMS) for six elements (Cd, Cr, Cu, Fe, Pb and Zn). Additional analytical works are now progressing to certify the concentrations of a number of the environmental and nutrimental elements in these CRMs. The certified values in a CRM are usually determined by using a single primary method with confirmation by other method(s) or using two independent critically-evaluated methods. Instrumental Neutron Activation Analysis (INAA) plays an important role in the determination of certified values as it can eliminate the possibility of common error sources resulting from sample dissolution. In this study INAA procedure was used in determination of 23 elements in these two biological CRMs to acquire the concentration information and the results were compared with KRISS certified values.

• Bulletin of the Korean Chemical Society
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• 제20권8호
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• pp.910-916
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• 1999

A current interest in chemistry concerns traceability of analytical measurements to the International System of Units (SI) and the proper estimation of their uncertainties in accordance with the internationally agreed guide provided by the International Organization for Standardization (ISO). Isotope dilution mass spectrometry (IDMS) is regarded as a primary method, which make the measurement results traceable to SI units without significant empirical correction factors. Our laboratory, as the national standards institute of Korea, participated in an intercomparison of environmental analysis, pp'-DDE in corn oil, which was organized by the CCQM under supervision of the CIPM to test feasibility of IDMS as a primary method for the trace analysis of organic compounds. In this report, we provide basic equations used for the calculation of the concentration of the analyte in a sample and a precise description of the processes for the evaluation of the uncertainties of the measurement results. Also, we report the experimental conditions adopted to improve the accuracy of the IDMS measurement. The principles contained in ？？Guide to the Expression of Uncertainty in Measurement'' provided by ISO are followed for the uncertainty evaluation.