• 한국염색가공학회지
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• 제35권3호
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• pp.137-150
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• 2023

This paper investigated the applicability of polyester yarn coating using ther- moplastic polyester elastomer (TPEE) to replace polyvinyl chloride (PVC) coated yarn for blinds fabric. For this purpose, suitable TPEE for yarn coating was selected by measuring thermal and rheological properties and the yarn coating process conditions were investigated by changing variables such as extrusion temperature, die and nipple dimensions, take-up speed, and core yarn denier. TPEE coated yarns with a diameter of 0.3 and 0.4 mm were prepared, respectively. Tensile properties and cross-section uniformity revealed by a scanning electron microscopy (SEM) of the TPEE coated yarn were analyzed. Among several candidates, TPEE having a melt index of 35 and melting temperature of 153℃ was the most suitable for replacing PVC, and the opti- mum coating conditions for the TPEE coating yarn were a head temperature of 170℃ and core yarn denier of 420 denier. The selected TPEE coated yarns have enough ten- sile strength and uniformity to replace present PVC coated yarns, certified by SEM photograph.

• 한국염색가공학회지
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• 제33권3호
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• pp.120-130
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• 2021

The condition of covering process using thermoplastic polyetherester elastomeric fibers(TPEE) was established. Two types of core yarn(TPEE, Spandex) and one type of effect yarn(PET) were used as materials to confirm the change in physical properties of covering yarn under various covering conditions. In addition, the effects of the treatment temperature on the elongation at break of covering yarn after heat treatment was analyzed. Through this analysis, it was confirmed that the elastic recovery of TPEE which is used as the core yarn was increased with the draw ratio, but decreases when it exceeds 1:2.5. And the elongation at break of the covering yarn could be increased by increasing the twist per meter of it. Additionally, it was confirmed that the elastic recovery of TPEE which is used as a core yarn, could be increased by applying heat treatment.

• Elastomers and Composites
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• 제48권1호
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• pp.67-75
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• 2013

E-TPE(Engineering Thermoplastic Polyether Ester)는 Ester 관능기를 갖는 Elastomer 소재로서 리사이클이 가능하며 빠른 가공성을 지닌다. 또한 경량성이 뛰어나 자동차의 경우 연비향상에 도움을 주는 친환경 소재로 부각되고 있다. 고무와 엔지니어링 플라스틱의 특성을 모두 가지고 있는 E-TPE는 사용 가능한 온도영역이 넓고, 내열성 및 내유성이 우수하여 자동차 부품소재분나 전기전자분야의 신소재로 주목받고 있으나 국내에서는 원천기술이 부족하여 전량 수입에 의존하고 있는 실정이므로 연구개발이 시급하다. 본 연구에서는 하드 세그먼트로 폴리에스터계(TPEE)를 base로 하여 소프트 세그먼트로 Ethylen-prophylene-Copolymer와 CSM(Choloro sulphonated polyethylene Rubber), VAMAC(Ethylene Acrylic Rubber), NBR(Acrylonitrin Butadiene Rubber)의 탄성체를 1,3-Phenylene-bisoxazoline 가교제로 동적가교 시켜 함량과 첨가된 고무에 따른 물성을 관찰하였다. 그 결과 NBR 첨가된 동적가교물의 물성이 다른 고무에 비해 내열성 및 내유성 향상에 되었음을 확인하였다.

• Elastomers and Composites
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• 제57권4호
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• pp.215-221
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• 2022

In this study, high-penetration asphalt with low greenhouse gas emissions was used in the asphalt mixing process to reduce the carbon emissions during the reaction due to its capacity to be produced even at low temperatures. In effect, cationic, anionic, and non-ionic dispersants were added and mixed in different feeding ratios, seeking an effective dispersion of the modifiers (SIS, PS, TPEE, and SEBS) into the high-penetration asphalt matrix and forming an asphalt binder with a melting point of 120 ℃. The compatibility of the modifiers and the high-penetration asphalt was examined using SEM and DSC techniques, and the role of NDP-1 as a dispersant was carefully investigated with respect to dissolution time. The analyses showed that: (1) the dispersibility of the asphalt binder is good when the non-ionic dispersant is used; (2) as the concentration of the non-ionic dispersant increases, the dissolution time decreases and the domain size contracts; (3) the ND70-PS has the shortest dissolution time, the lowest agglomeration rate, and a single Tg value.

• 한국안광학회지
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• 제6권1호
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• pp.119-124
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• 2001

디메틸 테레프탈레이트 (DMT), 1.4-부탄디올 (1.4-BD) 그리고 분자량이 2000인 폴리테트라 메틸렌 에테르 글리콜 (PTMG)로 부터 폴리에스터계 열가소성 탄성체 (TPEE)를 합성할 수 있었다. 열적 안정성 및 기계적 물성을 증대시킬 목적으로 열처리를 하였으며, 이에 따라 결정성 hard segmen의 보다 규칙적인 배열로 인한 향상된 물성을 확인 할 수 있었다. 본 실험에서 합성된 공중합체는 soft segment의 함량이 증가함에 따라 융점 및 결정화도가 감소함을 보여 주었다. 기계적 물성의 경우, soft segment의 함량이 35%인 공중합체가 soft segment와 hard segment간 최적의 물리적 가교점 형성으로 인하여 가장 우수함이 관찰되었다.