• Title/Summary/Keyword: toxic pollutants.

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Comparison Study of the Pulmonary Function and Serum Carboxyhemoglobin Level Between the Traffic Policmen and Clerk Policemen (교통경찰과 비 교통경찰의 폐기능과 혈중 Carboxyhemoglobin 수치에 대한 비교연구)

  • Kim, Sung Min;Cheon, Gyu Rak;Kim, Young Wook;Kim, Joon Hyung;Lee, Ho Hak;Hong, Soon Chang;Lee, Seung Hee;Park, Sang Joon;Chung, Joon Oh;Kim, Yun Kwon;Kim, So Yon;Kim, Young Jung;Cho, Min Koo;Lee, Gwon Jun;Lee, Kyung In
    • Tuberculosis and Respiratory Diseases
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    • v.55 no.6
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    • pp.560-569
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    • 2003
  • Background : A large number of pollutants such as sulfur dioxide, nitric oxide, carbon monoxide, particulate matter, and ozone influence on the body. These pollutants put a burden on the lung and the sequelae resulting from the oxidative stress are thought to contribute to the development of fibrotic lung disease, emphysema, chronic bronchitis and lung cancer. Also, carbon monoxide generated from the incomplete combustion of carbon-containing compounds is an important component of air pollution caused by traffic exhaust fumes and has the toxic effect of tissue hypoxia and produce various systemic and neurologic complications. The objective of this study is to compare the difference of pulmonary function and serum carboxyhemoglobin(CO-Hb) level between the traffic policemen and clerk policemen. Method : Three hundred and twenty-nine of traffic policemen, and one hundred and thirty clerk policemen were included between 2001 May and 2002 August. The policemen who took part in this study were asked to fill out a questionnaire which included questions on age, smoking, drinking, years of working, work-related symptoms and past medical history. The serum CO-Hb level was measured by using carboxyoximeter. Pulmonary function test was done by using automated spirometer. Additional tests, such as elecrocardiogram, urinalysis, chest radiography, blood chemistry, and CBC, were also done. Results : $FEV_1(%)$ was $97.1{\pm}0.85%$, and $105.7{\pm}1.21%$(p<0.05). FVC(%) was $94.6{\pm}0.67%$, and $102.1{\pm}1.09%$, respectively(p<0.05). Serum CO-Hb level was $2.4{\pm}0.06%$, and $1.8{\pm}0.08%$(p<0.05). After correction of confounding factors (age, smoking), significant variables were FVC(%), $FEV_1(%)$ and serum CO-Hb level(%)(p<0.05). Conclusion : Long exposure to air pollution may influence the pulmonary function and serum CO-Hb level. But, further prospective cohort study will be needed to elucidate detailed influences of specific pollutants on pulmonary function and serum carboxyhemoglobin level.

Isolation and Characteristics of a Phenol-degrading Bacterium, Rhodococcus pyridinovorans P21 (페놀분해세균 Rhodococcus pyridinovorans P21의 분리 및 페놀분해 특성)

  • Cho, Kwang-Sik;Lee, Sang-Mee;Shin, Myung-Jae;Park, Soo-Yun;Lee, Ye-Ram;Jang, Eun-Young;Son, Hong-Joo
    • Journal of Life Science
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    • v.24 no.9
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    • pp.988-994
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    • 2014
  • The effluents of chemical and petroleum industries often contain non-biodegradable aromatic compounds, with phenol being one of the major organic pollutants present among a wide variety of highly toxic organic chemicals. Phenol is toxic upon ingestion, contact, or inhalation, and it is lethal to fish even at concentrations as low as 0.005 ppm. Phenol biodegradation has been studied in detail using bacterial strains. However, these microorganisms suffer from substrate inhibition at high concentrations of phenol, whereby growth is inhibited. A phenol-degrading bacterium, P21, was isolated from oil-contaminated soil. The phenotypic characteristics and a phylogenetic analysis indicated the close relationship of strain P21 to Rhodococcus pyridinovorans. Phenol biodegradation by strain P21 was studied under shaking condition. The optimal conditions for phenol biodegradation by strain P21 were 0.09% $KNO_3$, 0.1% $K_2HPO_4$, 0.3% $NaH_2PO_4$, 0.015% $MgSO_4{\cdot}7H_2O$, 0.001% $FeSO_4{\cdot}7H_2O$, initial pH 9, and $20-30^{\circ}C$, respectively. When 1,000 ppm of phenol was added to the optimal medium, the strain P21 completely degraded it within two days. Rhodococcus pyridinovorans P21 could grow in up to 1,500 ppm of phenol as the sole carbon source in a batch culture, but it could not grow in a medium containing above 2,000 ppm. Moreover, strain P21 could utilize toxic compounds, such as toluene, xylene, and hexane, as a sole carbon source. However, no growth was detected on chloroform.

Effect of Heavy Metal Ions on the Oocyte Maturation of Frog, Rana dybowskii in vitro (중금속 이온이 산개구리 난자성숙에 미치는 영향에 관한 연구)

  • 고선근;이두표
    • Korean Journal of Environment and Ecology
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    • v.11 no.3
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    • pp.310-315
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    • 1997
  • In oreder to know the effect of the oocyte maturation with several heavy metal ions(Cd$^{2+}$, Hg$^{2+}$, Cu$^{2+}$, Pb$^{2+}$) on frog(Rana dybowskii) by FPH(Frog pituitary homogenate: 0.1 p.e./ml) in vitro, oocytes were cultured for 20 hours and exanimed the maturation rates with exposure of various comcentrations of those ions. The results showed that Cd$^{2+}$ at concentration of 0.1 ppm suppressed the maturation of the oocytes, while Hg$^{2+}$, Cu$^{2+}$ and Pb$^{2+}$ suppressed them significantly at 1 and 5 ppm respectively. To examine the reversibility of the inhibitory effects, the oocutes were exposed to the metal ions only for 3 hours and transferred to plain medium and cultured further for 17 hours. The oocytes were recovered from the toxic effect of the ions when they were exposed to 1 ppm of Cd$^{2+}$ for 3 hours and not available to 2.5 ppm. The effect of 2.5 ppm of Hg$^{2+}$, Cu$^{2+}$, Pb$^{2+}$ were also reversible and not available to 5 ppm for 3 hours exposure. From the abave results, it reveal that heavy metal ions in this study suppressed the maturation of oocytes at relatively low concentration. Therefore the oocyte culture system can be used as a useful tool to evaluate the toxicity of the pollutants in envirment.

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Toxicity Evaluation of Chemicals using Black-spotted Pond Frog Embryos, Rana nigromaculata (참개구리 배아를 이용한 화학물질의 독성평가 연구)

  • Ko, Sun-Kun
    • Korean Journal of Environmental Biology
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    • v.30 no.3
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    • pp.231-237
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    • 2012
  • Toxicity of $Ni^{2+}$ and Tebuconazole were investigated via FETAX (Frog Embryo Teratogenesis Assay-Xenopus) protocol using domestic frog embryos. Embryos of Black-spotted pond frog, Rana nigromaculata, were incubated and toxic effects of $Ni^{2+}$ and Tebuconazole were investigated by probit analysis. As a result, mortality and malformation rates were increased and larval body length was decreased in a dose dependant manner of $Ni^{2+}$ and Tebuconazole. The half maximal effective concentration ($EC_{50}$) of $Ni^{2+}$ and Tebuconazole were 0.07, $12.7mg\;L^{-1}$, respectively and the half maximal lethal concentration ($LC_{50}$) of $Ni^{2+}$ and Tebuconazole were 4.2, 39.1, respectively. The teratogenic index (TI) were 61.4 in $Ni^{2+}$ and 3.1 in Tebuconazole, respectively. These results reveals that $Ni^{2+}$ and Tebuconazole suppress the development of Black-spotted pond frog embryos at the low concentration as showing teratogenic effects in other assay system. Therefore, teratogen assay system using the Rana nigromaculata embryos could be useful as a tool to evaluate the toxicity of the pollutants in environment.

Agriculture Pollution and its Countermeasures with Special Consideration of Pesticides (작물생산과 농업공해 및 그 대책)

  • Li, Gwo-Chen
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.27 no.4
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    • pp.340-360
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    • 1982
  • Because of the continuing rapid increase in pesticide usage in Taiwan, much attention has been focus on pesticide contamination of food and effect of pesticides on human and environmental health. The Plant Protection Center (PPC) conducts safety evaluation of pesticides usee! in Taiwan. The pesticides are classified into different groups based on their acute toxicities. Pesticides which are classified into extremely toxic group are not allow to used on short term crops or the continuously harvest crops. The acute toxicity of pesticides to the beneficial insects are also studied, special attention has been paid to the two predators of rice brown planthopper. 60% of cultivated land in Taiwan are paddy field; therefore, acute fish toxicity was taken into consideration when a pesticide was applied for registration to be used in the paddy. Fish toxicities were evaluated by the dangerous rating value which is the amount of pesticide residue in the field water over the TLM value. Mutagenicity of pesticides was continuously evaluated by using Arne's microbial testing method. Island wide survey of residual levels of pesticides of known pollutants such as chlorinated hydrocarbon . insecticides, mercurial compounds in soil, water and biological samples were carried out constantly. The potential of a new1y Imported esticides to pollute the environment were studied by using model ecosystem. Ecological magnification (EM) of a chemical was calculated from model ecosystem. A chemical was considered as a pollutant when its EM value over 5000. In order to ensure the levels of pesticides residue of the crop within the safety limit. The 'tolerance' of pesticides on different crop groupings were established base on 1) acceptable daily intake value of individual pesticides, 2) average daily consumption of each crop groupings by Chinese person, 3) Actual residues of pesticides. on different crops obtained from supervised trials. Total about 79 pesticides for which the tolerances have been established on different crop groupings. Because the intensive agricultural system was adopted in Taiwan. The phytotoxicity of pesticides to the non-target crops was therefore become one of the important factor in the safety evaluation of pesticide usage. These will include 1) direct injury, 2) injury caused by pesticide polluted irrigation water, 3) injury caused by the pesticide polluted soil, 4) reduction of growth caused by the effect of pesticide on the soil microorganisms. This paper will reviewed all the aspects mentioned in the previous .paragraphs. Most the works have done in Taiwan by the PPC.y the PPC.

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Study on the Contamination Characteristics of Pollutants at Various type of Abandoned Metal Mines (폐금속 광산의 유형별 오염특성에 관한 연구)

  • Lee, Jong-Deuk;Kim, Tae Dong;Kim, Sun Gu;Kim, Hee-Joung
    • Journal of Soil and Groundwater Environment
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    • v.18 no.3
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    • pp.93-108
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    • 2013
  • This study is aimed to prepare the effective detail survey methods(Phase II) of abandoned metal mines through the contamination assessment for mine types and facilities in the abandoned metal mine areas. The study sites of 12 abandoned mines are located in Gyeonggi-do and Gangwon-do and those were chosen among 310 sites that the Phase II survey was conducted from 2007 to 2009 after considering the results of Phase I for abandoned mines scattered all over the country. 12 study sites were classified into four types; Type I sites only have pit mouth. Type II sites have pit mouth and mine-waste field. Type III sites have pit mouth and tailing sorting field. Type IV sites have pit mouth, tailing sorting field and concentrator(s). In forest land, paddy soil and farm land of Type I, As and Cd were showed average concentration, and Cu and Pb were high on the pit mouth area in one mines where the pit mouth was developed within 500 m. In the mines of Type II, Cu and Pb were showed average concentration too, but As and Cd were slightly high in pit mouth and mine-waste field. The mines of Type III which had grinding particle process through physical separation milling or hitting showed similar tendency with Type II. However, mines of Type IV pit mouth, mine-waste field and showed various results depending on defining the contamination sources. For example, if contamination source was pit mouth, the mixed results of Type I, II, II were showed. In tailing sorting field which was regarded as the most important source and having high mobility, however, if there were no facilities or it was difficult to access directly, field sampling was missed occasionally during phase I and phase II survey. For that reason, the assessment for tailing sorting field is missed and it leads to completely different results. In the areas of Type I mines, the concentration of heavy metals exceeded precautionary standards of soil contamination or not within 1,000 meters of pit mouth. Nickel(Ni) was the largest factor of the heavy metal contamination in this type. The heavy metals except Arsenic(As) were shown high levels of concentration in Type II areas, where pit mouth and mine-waste field were operated for making powder in upriver region; therefore, to the areas in the vicinity of midstream and downstream, the high content of heavy metals were shown. The tendency of high level of heavy metals and toxic materials contained in flotation agent used during sorting process were found in soil around sorting and tailing field. In the abandoned-pit-mouth area, drygrinding area and tailing sorting field area, the content of Cupper(Cu) and Zinc(Zn) were higher than other areas. Also, the contaminated area were larger than mine reclamation area(2,000 m) and the location of tailing sorting field was one of the important factors to estimate contaminated area.

The effects of face velocity and path length on the uptake rates of volatile organic compounds measured by diffusive samplers (확산포집기로 공기중 ppb 농도수준의 휘발성유기물질 포집시 확산길이와 기류변화가 시료포집속도에 미치는 영향)

  • Byeon, Sang-Hoon;Stock, Thomas H.;Morandi, Maria T.;Afshar, Masoud;Cross, Jay
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.11 no.1
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    • pp.34-41
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    • 2001
  • Passive samplers have been used for personal, indoor, and outdoor air monitoring of VOCs at ppb concentrations in community and office environments. The path length of modified passive sampler was shortened, so it was intended to increase an uptake rate. The performance of the modified 3M 3500 organic vapor monitor(OVM) as a tool for assessing exposures to toxic air pollutants in nonoccupational community environments was evaluated using combined controlled test atmospheres of six selected target volatile organic compounds(VOCs): benzene, methyl tert-butyl ether(MTBE), chloroform, 1,4-dichlorobenzene, tetrachloroethylene, and toluene. The experiments were conducted by exposing the dosimeters to concentrations of $50{\sim}100{\mu}g/m^3$ on six face velocity(0.00, 0.02, 0.06, 0.12, 0.20, 0.30 m/sec) for 24 hours. If the uptake rate was increased, that means that we could use the passive sampler more effectively. The uptake rates were increased linearly according to reduce the path length. Although the diffusion path length was shortened, the change of uptake rate was within ${\pm}25%$ of theoretical value, indicating that the modified passive sampler(TM) can be effectively used over the range of concentrations and environmental conditions tested with a 24-h sampling period if the face velocities were over 0.12 m/s for 6 components of VOCs. But when the face velocities were less than 0.12 m/s, uptake rates were reduced more than expected values. So, the passive sampler with the shortened path length should be used at indoor or outdoor environment where the face velocity should be over about 0.10 m/s. If the path length was shortened more, the uptake rate was more effected by starvation.

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Sedimentary Geochemical Characteristics and Environmental Impact of Sediments in Tamjin River and Doam Bay (탐진강 및 도암만 지역 퇴적물의 퇴적지구화학적 특성과 환경영향)

  • Hong, Jin-Taek;Na, Bum-Soo;Kim, Joo-Yong;Koh, Yeong-Koo;Youn, Seok-Tai;Shin, Sang-Eun;Kim, Hai-Gyoung;Moon, Byoung-Chan;Oh, Kang-Ho
    • Journal of Environmental Impact Assessment
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    • v.16 no.6
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    • pp.393-405
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    • 2007
  • To examine the sedimentary geochemical characteristics of sediment in the Tamjin River and Doam bay, the analysis was conducted, using the sample obtained in February 2000, on the grain size and the contents of metallic elements and organic carbon. The factors that influence the geochemical behavior of metallic elements in the surface sediment are grain size, organism, surrounding soil and $CaCO_3$. To find out the pollution level of metallic elements, the enrichment factor (EF) and the index of geoaccumulation ($I_{geo}$) were researched. The majority of metallic elements sustain their values in natural state. The elements such as K, Ba, Zr, etc. appear to be rich in some places. The EF and $I_{geo}$ of P, Cu, Zn, and Pb, which belong to toxic heavy metals, are partly related with man-made pollution. P and Cu have a high EF, Pb has a high $I_{geo}$ and Zn is high in both EF and $I_{geo}$. The low contents of P and Cu are not likely to be related with the pollution of water environment. However, given the development of relative pollution, the research and the management regarding the pollutants are needed. Because Pb, naturally enriched by geological characteristics, has a large influence on water environment along with Zn, the adequate measures against man-made pollution should be worked out.

Optimization of Manufacturing Method for a Fiber Type of Biosorbent from Sludge Waste (폐슬러지로부터 섬유형 생체흡착제 제조방법의 최적화)

  • Seo, Ji Hae;Kim, Namgyu;Park, Munsik;Lee, Sunkyung;Park, Donghee
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.9
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    • pp.641-647
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    • 2014
  • In this study, sludge waste which has a difficulty in treating it was used to manufacture a fiber type of biosorbent. To solve the problems such as the release of organic pollutants and the difficulty in separating solid from treated water, entrapment method using Ca-alginate was used to immobilize sludge waste. Considering ease of manufacture as well as improvement of adsorptive ability, the biosorbent was manufactured in the form of fiber type. Optimum immobilization condition for minimizing the amount of alginate used and maximizing the performance of biosorbent was determined to be 10 g/L alginate concentration, 40 g/L sludge concentration, and 0.3-0.4 mm fiber diameter. The maximum Cd(II) uptake of the biosorbent was 60.73 mg/g. Pseudo-second-order kinetic model and Langmuir isotherm model adequately described the dynamic and equilibrium behaviors of Cd(II) biosorption onto the biosorbent, respectively. In conclusion, sludge waste generated from wastewater treatment process is a cheap raw material for the manufacture of biosorbent which can be used to remove toxic heavy metals from industrial wastewaters efficiently.

Current Status and Perspective of Biological Assessments of Water Environment in Korea (우리나라 생물학적 물환경평가의 현황과 미래)

  • Hwang, Soon-Jin;Kim, Nan-Young;Won, Doo Hee;An, Kwang Kuk;Lee, Jae Kwan;Kim, Chang Soo;Shin, Jae-Ki
    • Journal of Korean Society on Water Environment
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    • v.22 no.5
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    • pp.757-767
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    • 2006
  • Biological assessments are the primary tool for evaluating the biological condition of a water body and makes it possible to understand accumulative and long-term effect of stressors. They also provide reliable biological information for which disturbed systems are to be restored. Sustainable water environment is not enough with attaining only the clean water, but it should sustain healthy and diverse aquatic life. Aquatic organisms are affected by various factors, including not only water quality but also habitat condition and stressors, and thus good condition of both physical and chemical water quality is prerequisite for sustaining healthy organisms. Therefore, biological assessment, along with other physical and chemical assessments, are crucial for evaluating the health of a water body. Overall, sustainability of water environment demands the attainment and maintenance of ecological integrity, which is resulted from the combination of physical, chemical and biological integrity. The biological criteria will play very important role in the water resource management and policy issues, and thus bioassessment program should be fully implemented and supported eventually by the law. To keep ecosystem health of water environment safely from the toxic pollutants and other stressors, the following suggestions need to be considered in environmental quality standards in Korea. For the first step, the biological indicators need to be introduced in evaluating river quality condition; they provide a qualitative description of biological condition of water body. Secondly, the biological water quality standards using biotic indices should be developed and implemented under the consideration of characteristics of Korean river systems. Lastly, the ecological status classification regime (ESCR) should be developed and introduced; it could be used in quality assessment of the water environment in general. In developing ESCR, integration of physico-chemical, biological, and habitat parameters should be taken into account.