• 한국해양환경ㆍ에너지학회지
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• 제6권4호
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• pp.13-23
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• 2003

Organic carbon and nitrogen contents in suspended particulate matter (SPM) and surface sediments in seawater were measured in the Northern East China Sea in summer. The distribution of particulate organic carbon(POC) and particulate organic nitrogen(PON) were in the ranges of 54~481㎍/ℓ and 6~85㎍/ℓ, respectively, with relatively high level of concentrations in the western and southern sides of the study area. Also, there has been a significantly positive correlation between POC and PON, gradually increasing toward the deeper range of depth. Average C:N ratios of POC and PON of SPM were 6 in study area. The ratios of POC to PON of SPM increased as the range of depth increased, indicating nitrogen decomposes more rapidly than carbon and is considered to be influenced by the input of detritus from surface sediments. The distribution of total organic matter(TOM), total organic carbon(TOC) and total organic nitrogen(TON) in surface sediments were in the ranges of 3.1~9.6%, 0.282~0.635% and 0.022~0.069%, respectively, with relatively low range in the western and northern sides of the study area. The ratio of TOC to TON of surface sediments were in the range of 9.8~17.4(average of 13), strongly indicating the active role of the input from the terrestrial organic pollutants.

• 한국산업보건학회지
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• 제18권3호
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• pp.177-184
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• 2008

The purpose of this study was to compare the performance characteristics of Andersen and total suspended particulate (TSP) samplers in terms of particle size distribution (PSD) and mass sampling efficiency. In the present study, two Andersen and four TSP samplers were selected and tested to quantitatively estimate human exposure to fly ash representing industrial particulate matter (PM) in a carefully controlled chamber. The PSD characteristics, a mass median aerodynamic diameter and a geometric standard deviation, were found from the sampled PM of airborne samplers in the chamber. An Andersen sampler was compared with a TSP sampler quantified by a coulter counter multisizer, as a reference sampler, to describe the correlation of mass sampling efficiencies between two types of samplers. Overall results indicate that Andersen samplers overestimated small PM due to particle bounce phenomena between impaction stages. There was reasonably good correlation ($R^2$ = 0.89 and 0.91) between the mass sampling efficiencies of Andersen and TSP samplers during the two tests. However, the lower values of slope (0.71 and 0.72) in two tests showed that the Andersen sampler underestimated PM (> AD $10.1\;{\mu}m$) with sufficient inertia due to a relatively lower Andersen inlet velocity at 0.8 m/s comparing with the operating air velocity at 2.1 m/s in the sampling zone of a chamber.

• Journal of the korean society of oceanography
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• 제31권2호
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• pp.55-63
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• 1996

Distribution of suspended particulate matter, dissolved oxygen and major inorganic nutrients along a meridional section ($126^{\circ}$ 33' E) in the Cheju Strait is described along with the hydrographic and current data obtained during April 25-27, 1995. The current measurements was conducted using a vessel-mounted Acoustic Doppler Current Profiler (ADCP). Repeated coverage along an ADCP transect during 25 hours allows to calculate the daily mean along- and cross-strait currents. Measured material concentrations and the mean current speed were used to estimate the flux density (cencentration times current speed) of materials. Two types of depth distibution of flux densities were observed. for nitrate and suspended particulate matter, the depth distribution pattern of materials determines those of flux densities. However, flow patterns determine those of flux densities for dissolved oxygen, phosphate and silicic acid. The total along-strait water volume transport is about 0.3 Sv (1Sv $10^{6}$ $m^{3}/s^{-1}$). The total along-strait material transports are estimated to be 3.1 $${\times} $10^{5}$ $g/s^{-1},$ 2.4 ${\times}$ $10^{6}\;g/s^{-1},$ 7.I ${\times}$ $10^{2}\;mol/s^{-1},$ 3.I ${\times}$ $10\;mol/s^{-1},$ 1.7 ${\times}$ $10^{3}\;mol/s^{-1}$ for suspended particulate matter, dissolved oxygen, nitrate ion, silicic acid and phosphate ion, respectively.

• Journal of Preventive Medicine and Public Health
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• 제16권1호
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• pp.67-77
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• 1983

To investigate the an air pollution by particulate matter and its dispersion, a cement plant produceing portland cement 600,000 ton/year and its vicinity were surveyed from Obtober, 1980 to April, 1983. The survey was mainly focused on main stack emmission rate of the cement plant and particle size distribution in the dust, dustfall and total suspended particulate concentration in the area by month and distance from the stack. The results of the study were as follows; 1. The main stack emission rate was surveyed before and after the spray tower was additionally installed to the original E.P bag filter. Before the spray tower installed, the main stack emission rate was higher ($0.64g/Nm^3$) than the emission standard of Korean Environmental Preservation Law's ($0.59g/Nm^3$, amended to $0.4g/Nm^3$ on April 1983), but after the spray tower was installed, its main stack emission rate was markedly decreased to the standard ($0.43g/Nm^3$). 2. $2{\sim}3{\mu}m$ of the particle size was the largest portion (20.8%) of the dust particulate from the main stack and 50% of the frequency distribution was $1.5{\mu}m$ of the size. Most particle size was below $10{\mu}m$. 3. The spray tower reduced the dustfall to $37.81{\sim}9.76\;ton/km^2/month$ while dustfall appeared at $45.29-15.45ton/km^2/month$, in the vicinity of plant before spray tower installed 4. Mean concentrations of total suspended particulate for 24 hours of the various stations were determined in $20.6-200.0{\mu}g/m^3$, 3 stations of tham were higher than the value of Harry and William's arthmetic average standard $130{\mu}g/m^3$. 5. Linear regression between dustfall [X] and total suspended particulate[Y] concentration was an equation, Y=4.024X+11.479.[r=0.91] 6. During the whole seasons in the opposite area 100m apart from the omission source the prevailing wind direction was with estimated more than $30ton/km^2/month$, and the concentration of total suspended particulate for 24 hours averaging time was more than $140{\mu}g/m^3$ in the same area and direction. 7. Assuming the wind direction were constant through the day dustfalls for a day were estimated at $13.40ton/km^2/day,\;10.79ton/km^2/day$ and $4.55ton/km^2/day$ at various distances of 100m, 500m and 1,500m from the emission source respectively. 8. In the simutalion of dustfall and suspended dust by area, Gaussian dispersion model modified by size distribution of particulate matter was not applicated since the emission of dust were from multi sources other them stack. From the above results, it could be applied that the dispersion of dust from the cement plant is estimated and regulated for the purpose of environmental protection.

• 한국환경과학회지
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• 제20권11호
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• pp.1357-1371
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• 2011

Suspended and sinking particles were collected during ODP Leg 119 to the Indian Ocean sector of the Antarctic Ocean. Field work was carried out at four sampling sites in Prydz Bay. Two of these sites were located in the Outer Bay, and two in the Inner Bay. At the four locations, a total of ten deployments of a sediment trap array were made. The concentrations of carotenoids both in suspended and sinking particulate matter in Prydz Bay were analyzed using HPLC. Fucoxanthin was the dominant carotenoid pigments both in suspended and sinking particles. The present study also indicates that 19'-hexanoyoxyfucoxanthin-containing prymesiophytes (Phaeocystis spp.) was abundant in the study area. The flux rates of carotenoids were generally highest at 50 m, and approximately double the flux rates at deeper horizons, however, at Inner Bay sites, the mean flux rates of carotenoids were greatest at 200 m, and 3 times greater than that of 50 m. Such anomalous high fluxes at 200 m imply that grazers were locally abundant between 100 m and 200 m at these sites close to land, and this hypothesis is supported by visual evidence of lots of fecal pellets in the 200 m trap. Integrates standing stocks versus sinking pigments data support that particulate material in Prydz Bay was not recycled rapidly.

• Journal of Preventive Medicine and Public Health
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• 제33권3호
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• pp.306-312
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• 2000

Background : Polycyclic aromatic hydrocarbons (PAH) are well known environmental pollutants. The measurement of PAH in ambient air is not commonly used, because it is quite difficult to perform and is unreliable. Using biomarkers of PAH can be an alternative approach to this problem. The PAH in ambient air is absorbed in particulate matter. Total suspended particulate(TSP) or particulate matter of less than $10{\mu}m$ in diameter (PM10) can be easily measured. Therefore, TSP or PM10 can be used as a surrogate measurements of ambient air PAH. Objectives : We investigated whether the urinary concentration of two biomarkers of PAH, 1-hydroxypyrene (1-OHP) and 2-naphthol, could reflect the total suspended particulate in the general population. Methods : In order to exclude the effects of occupational exposure and smoking, first grade middle school students were included in this study. Four middle schools within a one kilometer boundary of ambient air monitoring stations were selected. Total suspended particulate was regarded as the marker of airborne PAH. Diet and smoking data were collected by self administered questionnaires, and spot urine samples were collected. Urinary 1-OHP and 2-naphthol were analyzed by high performance liquid chromatography. Results : The correlation between urinary 1-OHP, 2-naphthol and passive smoking was not statistically significant. The correlation between urinary 1-OHP and TSP indices was not statistically significant. The correlations between urinary 2-naphthol and TSP of two lag days, one lag day, and zero lag days were statistically significant. The statistical significance of two lag days was the strongest (p=0.001), one lag day was the next (p=0.0275), and zero lag days was the weakest (p=0.0349). Conclusion : Our results imply that the urinary concentration of 2-naphthol can be applied as a PAH exposure marker for the general population with low PAH exposure.

• 환경위생공학
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• 제9권1호
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• pp.53-61
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• 1994

Sungnam city, as a major satellite town, is located in the southeast of Seoul. Atmospheric conditions are so stable that air pollutants from various emissions are tend to resist change because Sungnam city is located in the Namhansansung valley. The industrial distribution of Sungnam city are composed of various manufactories such as foods, fibers, chemicals, machinery and electronics etc. The heavy metal concentrations and size distribution are the most important parameters influencing among the way in which respirable suspended particulate matter interact with the human respiratory system. Respirable suspended particulate matter was collected on glass fiber filters from April 1993 to February 1994 according to particle size using Anderson sampler during 10 days per month at Sungnam city. 6 heavy metals, Fe, Zn, Pb Mn, Cu and Cd, were analyzed by particle size with atomic absorption spectrophotometry . The results could be summarized as follows: 1. The annual arithmetic mean concentration of total suspended particulate was 116.3$\mu $g/m$^{3}$ m', seasonal variation was the highest in spring season(196.5$\mu $g/m$^{3}$) and the lowest in Summer Season(72.9$\mu $g/m$^{3}$). 2. The ratio of airborne particulate concentrations respirable to nonrepairable( Res/Non- Res) of annual arithmetic mean value was 5.8'1, seasonal variation was highest in the spring season(6.3 : 1) and lowest in the summer season(4.6 : 1). 3. During the spring season the shape of the size distribution was trimodal which showed peaks at 3 size groups, which were below of 0.43$\mu $m, 3.3∼4.7$\mu $m and above of 11.0$\mu $g/m$^{3}$ respectively. 4. Respirable suspended particulate matter concentrations of Zn, Pb Cu and Cd were the highest in below of 0.43$\mu $m as follows; 0.517$\mu $g/m$^{3}$, 0.411 $\mu $g/m$^{3}$, 0.062$\mu $g/m$^{3}$ and 0.0310$\mu $g/m$^{3}$ , respectively, Fe and Mn were the highest in the particle size range of 4.7 ∼ 7.0$\mu $m as follows; 2.504$\mu $g/m$^{3}$ and 0.095$\mu $g/m$^{3}$, respectively. 5. The Pt Cd, Zn, Cu, Fe and Mn concentrations of annual arithmetic mean value respirable to non- respirable( Res/Non- Res ) were 33.65, 19.27, 17.74, 10.54, 3.20 and 5.20, respectively.

• 한국항해항만학회지
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• 제35권4호
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• pp.323-334
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• 2011

Suspended and sinking particles were collected in austral summer during ODP Leg 119 to the Indian Ocean sector of the Antarctic Ocean. Field work was carried out at four sampling sites in Prydz Bay. Two of these sites were located in the Outer Bay, and two in the Inner Bay. At the four locations, a total of ten deployments of a sediment trap array were made. The concentrations of chlorophylls and their degradation products both in suspended and sinking particulate matter in Prydz Bay were analyzed using HPLC. Chlorophylls a and c were the dominant algal pigments both in suspended and sinking particles. Because of the abundance of fecal pellets at Site 740, the mean fluxes at 200 m averaged 6 fold greater than that at 50 m. This implies that a dense swarm of zooplankters, presumably large copepods and/or salps, may "feed and excrete" mainly in between 100-200 m depths at this site, closest to land in Prydz Bay. Interestingly, The flux of phaeophorbide a was generally similar in magnitude to that of chlorophyll a throughout the study areas. This is an evidence that materials escaping from near-surface regions in austral summer derive mainly from the gazing of zooplankters. "New production" from sediment-trapped CHL pigment fluxes in Prydz Bay was estimated using f-ratio of 0.15, ranging from 520 to $1,605\;{\mu}gC\;m^{-2}\;day^{-1}$.

• 한국환경보건학회지
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• 제46권6호
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• pp.719-725
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• 2020

Objectives: With the growth of national interest in fine particulate matter, many complaints about pollutants emitted from air pollution emitting facilities have arisen in recent years. In particular, it is thought that a large volume of particulate pollutants are discharged from workplaces that use Solid Refuse Fuel (SRF). Therefore, particulate contaminants generated from SRF were measured and analyzed in this study in terms of respective particle sizes. Methods: In this study, particulate matter in exhaust gas was measured by applying US EPA method 201a using a cyclone. This method measures Filterable Particulate Matter (FPM), and does not consider the Condensable Particulate Matter (CPM) that forms particles in the atmosphere after being discharged as a gas in the exhaust gas. Results: The mass concentration of Total Suspended Particles (TSP) in the four SRF-using facilities was 1.16 to 11.21 mg/Sm3, indicating a very large concentration deviation of about 10 times. When the fuel input method was the continuous injection type, particulate matter larger than 10 ㎛ diameter showed the highest particle size fraction, followed by particulate matter smaller than 10 ㎛ and larger than 2.5 ㎛, and particulate matter of 2.5 ㎛ or less. Contrary to the continuous injection type, the batch injection type had the smallest particle size fraction of particulate matter larger than 10 ㎛. The overall particulate matter decreased as the operating load factor decreased from 100% to 60% at the batch input type D plant. In addition, as incomplete combustion significantly decreased, the particle size fraction also changed significantly. Both TSP and heavy metals (six items) satisfied the emissions standards. The measured value of the emission factor was 38-99% smaller than the existing emissions factor. Conclusions: In the batch injection facility, the particulate matter decreased as the operating load factor decreased, as did the particle size fraction of the particulate matter. These results will help the selection of effective methods such as reducing the operating load factor instead of adjusting the operating time during emergency reduction measures.

• 한국대기환경학회지
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• 제7권1호
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• pp.17-22
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• 1991

Total suspended particulates (TSP) in the atmosphere was collected and size-fractionated by Andersen high volume air sampler for one year (Mar. 1987 $\sim$ Feb. 1988) in Seoul. The concentrations of several polycyclic aromatic hydrocarbons and heavy metals were determined to investigate the atmospheric concentrations, seasonal variations and its relationship with the size distribution of suspended particulate matter. The arithmetic mean concentration of total suspended particulates was 200.44 $\mug/m^3$. The concentrations of heavy metals were 2433.80 for Fe, 629.49 for Zn, 600.71 for Pb, 143.87 for Cu, and 107.21 $ng/m^3$ for Mn, respectively. The concentrations of PAHs were 3.83 for benzo(a) pyrene, 2.95 for benzo(k)fluoranthene, and 4.42 $ng/m^3$ for benzo(ghi)perylene, respectively. PAHs, Pb and Zn abounded in particles below 2.0 $\mu$m, while Fe and Mn aboounded in particles above 2.0 $\mu$m. TSP and its chemical compositions showed the seasonal variations. The concentrations of anthrophogenic pollutants like TSP, PAHs and heavy metals in the fine particles were highest in winter and lowest in summer. PAHs and Pb analyzed showed significant correlations between each other and between TSP concentration in fine particles, indicating that the particles in which they are contained have a similar behavior in the atmosphere.