• 대기
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• 제29권1호
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• pp.13-20
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• 2019

Since 1985, the Dobson Spectrophotometer has been operated at Yonsei University, and this instrument has monitored the daily representative total ozone in Seoul. Climatological value for total ozone in Seoul is updated by using the daily representative observation data from 1985 to 2017. After updating the daily representative total ozone data, seasonal and inter-annual variation of total ozone in Seoul is also estimated after calculating inter-comparison between ground (Dobson Spectrophotometer) and satellite [Total Ozone Mapping Spectrometer (TOMS) and Ozone Monitoring Instrument (OMI)] observations. The global average of total ozone measured by satellite is 297 DU, and its recent amount is about 3.5% lower than the global amount in 1980s. In Seoul, daily representative total ozone is ranged from 225 DU to 518 DU with longterm mean value of 324.3 DU. In addition, monthly mean total ozone is estimated from 290 DU (October) to 362 DU (March), and yearly average of total ozone have been continuously increased since 1985. For the long-term trend of total ozone in Seoul, this study is considered the seasonal variation, Solar Cycle, and Quasi-Biennial Oscillation. In addition to the natural oscillation effect, this study also considered to the long-term variation of sudden increase of total ozone due to the secondary ozone peak. By considering these natural effects, the long-term total ozone trends from 1985 to 2017 are estimated to be 1.11~1.46%/decade.

• 한국지구과학회지
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• 제26권3호
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• pp.199-217
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• 2005

TOMS 월별 오존전량의 전구 자료를 이용하여, 두 기간(전기: 1979-1992년, 후기: 1997-2002년)에 대한 오존전량 추세 및 시공간 변동을 지역과 해륙 분포에 따라 상호 비교하였다. 전기에 비하여 후기의 오존전량이 0-20 N 일부 지역을 제외하고 전지구적으로 10 DU 정도 감소하였다. 오존전량의 추세는 전구적으로 전자기간에 감소(-6.30 DU/decade)를 나타냈다. 후자 기간의 오존 증가 경향은 열대 지역에서 현저하였다. 1997-2002년 기간의 오존전량에 대한 경험직교함수 분석은 준2년 진동(QBO), 준3년 진동(QTO), 엘니뇨(ENSO), 그리고 화산폭발과 관련된 시공간 변동을 반영하였다. 열대 지역에서 대류권 오존의 연직 분포는 동서방향에서 파수 1의 형태를 보였다. 본 연구는 기후 및 환경변화와 관련된 성층권과 대류권 오존 변화의 원인 규명에 도움을 줄 수 있다.

• 대한원격탐사학회지
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• 제11권3호
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• pp.23-31
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• 1995

기상청에서는 1990년부터 Smith등(1984,1986)이 개발한 ITPP-VI(International TOVS Program Package)를 사용하여 직접 물리 해법을 이용한 연직온도분포 및 총오존량을 산출하여 예보현업에 이용하고 있다. 그러나 현재의 초기입력자료로 사용되는 기후값은 너무 오래되었고, 국지효과나 한반도 부근의 특성이 제외되었으므로 도출된 전오존량의 분포를 직접 사용하기에는 그 정확성이나 신빙성이 희박하다. 따라서 ITPP-VI로부터 오존량 산출자료의 질적 개선을 위해 초기 입력자료중 지표값을 기후자료 대신에 GPV(Gridded Point Values) 자료를 입력하여 오존량 도출을 수행하였다. GPV자료의 입력을 통한 TOVS 오존량 자료(TOVS-GPV)가 정량적으로 어느 정도 개선되었는 지 알아보기 위하여 두경우의 총오존분포도를 비교하였다. GPV 지표자료의 입력으로 도출한 총 오존량은 기후값으로 도출한 총오존량(TOVS-CLIMA)에 비해 한반도 부근에서의 오존량 변화를 더 자세하게 표현하였다. 정량적으로 질적 개선을 알아보기 위해 1994년 2월 한달동안 지상 관측 자료로써 연세대학교의 오존분광기(Dobsometer)로 관측한 오존량(Uy), TOVS-GPV(Ug), TOVS- CLIMAT(Uc), 그리고 TOMS(Total Ozone Monitoring System) 관측값(Um)을 이용하여 나타낸 결과, 월변화의 경향은 연세대학교 총오존량값의 변화에 대해 TOVS-GPV(Ug), TOVS-CLIMAT (Uc)와 TOMS(Um) 값들의 변화는 크지만, 새로운 TOVS-GPV 오존량은 TOVS-CLIMAT 오존 량에 비해 TOMS 오존량과 연세대학교 관측치와 유사한 경향을 보였다.

• Ocean and Polar Research
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• 제26권3호
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• pp.439-451
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• 2004

Total solar irradiance (750), total UV irradiunce (TUV) and erythemal UV irradiance (EUV) measured at King Sejong station $(62.22^{\circ}S,\;58.78^{\circ}W)$ in west Antarctica have been used together with total ozone, cloud amount and snow cover to examine the effects of ozone, cloud and snow surface on these surface solar inadiunce over the period of 1998-2003. The data of three solar components for each scan were grouped by cloud amount, n in oktas $(0{\leq}n<3,\;3{\leq}n<4,\;4{\leq}n<5,\;5{\leq}n<6,\;6{\leq}n<7\;and\;7{\leq}n<8)$ and plotted against solar zenith angle (SZA) over the range of $45^{\circ}\;to\;75^{\circ}$. The radiation amplification factor (RAE) is used to quantify ozone effect on EUV. RAF of EUV decreases from 1.51 to 0.94 under clear skies but increases from 0.94 to 1.85 under cloudy skies as SZA increases, and decreases from 1.51 to 1.01 as cloud amount increases. The effects of cloud amount and snow surface on EUV are estimated as a function of SZA and cloud amount after normalization of the data to the reference total ozone of 300 DU. In order to analyse the transmission of solar radiation by cloud, regression analyses have been performed for the maximum values of solar irradiance on clear sky conditions $(0{\leq}n<3)$ and the mean values on cloudy conditions, respectively. The maximum regression values for the clear sky cases were taken to represent minimum aerosol conditions fur the site and thus appropriate for use as a normalization (reference) factor for the other regressions. The overall features for the transmission of the three solar components show a relatively high values around SZAs of $55^{\circ}\;and\;60^{\circ}$ under all sky conditions and cloud amounts $4{\leq}n<5$ and $5{\leq}n<6$. The transmission is, in general, the largest in TUV and the smallest in EUV among the three components of the solar irradiance. If the ground is covered with snow on partly cloudy days $(6{\leq}n<7)$, EUV increases by 20 to 26% compared to snow-free surface around SZA $60^{\circ}-65^{\circ}$, due to multiple reflections and scattering between the surface and the clouds. The relative difference between snow surface and snow-free surface slowly increases from 9% to 20% as total ozone increases from 100 DU to 400 DU under partly cloud conditions $(3{\leq}n<6)$ at SZA $60^{\circ}$. The snow effects on TUV and TSO are relatively high with 32% and 34%, respectively, under clear sky conditions, while the effects changes to 36% and 20% for TUV and TSO, respectively, as cloud amount increases.

• 한국대기환경학회지
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• 제22권3호
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• pp.271-285
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• 2006

A two-dimensional photochemical transport model (2D PTM) is simulated to describe the transport and chemical reaction of ozone related to aerosols in the troposphere and stratosphere. The vertical profiles and total amounts of ozone, which are advected by both residual Eulerian circulation and the adiabatic circulation under certain circumstance, have been compared with the observation data such as ozonesondes, Brewer spectrometer, the Upper Atmosphere Research Satellite (UARS), and the Total Ozone Mapping Spectrophotometer (TOMS). As a result, we find that the observed distribution of ozone Is adequately reproduced in the model at middle and high latitude in the Northern Hemisphere as well as at Phang ($36^{\circ}\;02'N,\;129^{\circ}\;23'E$) in South Korea. In particular, the 2D PTM is well simulated in the ozone decrease due to the Pinatubo volcanic eruption in 1991. However, ozone mixing ratio are more underestimated than those of UARS and ozonesondes, because are very sensitive to the latitude of transport across the tropopause associated with both Rummukainen errors and off-line model. Relative mean bias errors and relative root mean square errors of ozone calculations using the 2D PTM are shown within${\pm}10%$, respectively.

• 대기
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• 제17권4호
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• pp.339-348
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• 2007

Global Environment Laboratory at Yonsei University in Seoul ($37.57^{\circ}N$, $126.95^{\circ}E$) has carried out the ozone layer monitoring program in the framework of the Global Ozone Observing System of the World Meteorlogical Organization (WMO/GAW/GO3OS Station No. 252) since May of 1984. The daily measurements of total ozone and the vertical distribution of ozone amount have been made with the Dobson Spectrophotometer (No.124) on the roof of the Science Building on Yonsei campus. From 2004 through 2006, major parts of the manual operations are automated in measuring total ozone amount and vertical ozone profile through Umkehr method, and calibrating instrument by standard lamp tests with new hardware and software including step motor, rotary encoder, controller, and visual display. This system takes full advantage of Windows interface and information technology to realize adaptability to the latest Windows PC and flexible data processing system. This automatic system also utilizes card slot of desktop personal computer to control various types of boards in the driving unit for operating Dobson spectrophotometer and testing devices. Thus, by automating most of the manual work both in instrument operation and in data processing, subjective human errors and individual differences are eliminated. It is therefore found that the ozone data quality has been distinctly upgraded after automation of the Dobson instrument.

• 한국환경과학회지
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• 제24권8호
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• pp.993-1001
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• 2015

Comparing to the other air pollutants like $SO_2$, CO, the number of exceedance of the ozone national ambient air quality standard(NAAQS) and the ozone warning increased recently in Busan. The purpose of this study is to find out the preliminary symptoms for high ozone days in Busan area. In order to find out the preliminary symptoms, the hourly ozone data at air quality monitoring stations and the hourly meterological parameters at Busan regional meteorological 2007 to 2013 were used for the analysis. Averaged daily max ozone concentration was the highest(0.055 ppm) at Noksan and Youngsuri in the ozone season from 2007 to 2013. The horizontal distributions of daily max. ozone including all stations in Busan at high ozone days(the day exceeding 0.1 ppm of ozone concentration at least one station) were classified from two to five clusters by hierarchial cluster analysis. The meteorological variables showing strong correlation with daily max. ozone were the daily mean dew point temperature, averaged total insolation, the daily mean relative humidity and the daily mean cloud amount. And the most frequent levels were $19-23^{\circ}C$ in dew point temperature, $21-24 MJ/m^2$ in total insolation on the day before, $2.6-3.0 MJ/m^2$ on the very day, 67-80% in relative humidity and 0-3 in cloud amount.

• 한국환경과학회지
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• 제15권8호
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• pp.701-718
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• 2006

The average ratio of the daily UV-B to total solar (75) irradiance at Busan (35.23$^{\circ}$N, 129.07$^{\circ}$E) in Korea is found as 0.11%. There is also a high exponential relationship between hourly UV-B and total solar irradiance: UV-B=exp (a$\times$(75-b))(R$^2$=0.93). The daily variation of total ozone is compared with the UV-B irradiance at Pohang (36.03$^{\circ}$N, 129.40$^{\circ}$E) in Korea using the Total Ozone Mapping Spectrometer (TOMS) data during the period of May to July in 2005. The total ozone (TO) has been maintained to a decreasing trend since 1979, which leading to a negative correlation with the ground-level UV-B irradiance doting the given period of cloudless day: UV-B=239.23-0.056 TO (R$^2$=0.52). The statistical predictions of daily total ozone are analyzed by using the data of the Brewer spectrophotometer and TOMS in East Asia including the Korean peninsula. The long-term monthly averages of total ozone using the multiplicative seasonal AutoRegressive Integrated Moving Average (ARIMA) model are used to predict the hourly mean UV-B irradiance by interpolating the daily mean total ozone far the predicting period. We also can predict the next day's total ozone by using regression models based on the present day's total ozone by TOMS and the next day's predicted maximum air temperature by the Meteorological Mesoscale Model 5 (MM5). These predicted and observed total ozone amounts are used to input data of the parameterization model (PM) of hourly UV-B irradiance. The PM of UV-B irradiance is based on the main parameters such as cloudiness, solar zenith angle, total ozone, opacity of aerosols, altitude, and surface albedo. The input data for the model requires daily total ozone, hourly amount and type of cloud, visibility and air pressure. To simplify cloud effects in the model, the constant cloud transmittance are used. For example, the correlation coefficient of the PM using these cloud transmissivities is shown high in more than 0.91 for cloudy days in Busan, and the relative mean bias error (RMBE) and the relative root mean square error (RRMSE) are less than 21% and 27%, respectively. In this study, the daily variations of calculated and predicted UV-B irradiance are presented in high correlation coefficients of more than 0.86 at each monitoring site of the Korean peninsula as well as East Asia. The RMBE is within 10% of the mean measured hourly irradiance, and the RRMSE is within 15% for hourly irradiance, respectively. Although errors are present in cloud amounts and total ozone, the results are still acceptable.

• 폴리머
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• 제27권2호
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• pp.98-105
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• 2003

오존 처리된 저밀도 폴리에틸렌 (LDPE) 필름의 표면 작용기와 표면 자유에너지에 대하여 고찰하였다. 오존 표면처리 조건을 각각 처리시간, 오존 생산량, 그리고 오존의 농도로 변화시켰으며, 오존 처리된 LDPE 필름 표면에 도입된 작용기는 FTIR-ATR과 XPS 분석을 통하여 알아보았다 LDPE 필름의 표면 자유에너지는 접촉각 측정을 통하여 고찰하였다. 실험결과, 오존으로 표면처리된 LDPE 픽름은 표면에 형성된 산소 함유 작용기로 인하여 물 접촉각이 15$^{\circ}$ 정도 감소하였고, 그 결과 표면 자유에너지의 증가및 $O_{IS}$ / $C_{IS}$ 의 증가를 확인할 수 있었다. 또한, 표면 자유에너지와 산소 함유 작용기는 오존 표면처리 시간과 오존의 농도에 비례하는 관계를 보인 반면, 오존의 총 발생량의 변화는 표면 자유에너지 및 $O_{IS}$ / $C_{IS}$ 의 증가와는 무관하였다. Kubelka-Munk 식을 이용한 염색성 측정 결과로부터, 오존 표면처리는 LDPE 필름 표면에 산소 작용기를 형성시키는데 중요한 역할을 하는 것을 확인할 수 있었으며, 최종 염기성 염료에의 염색성을 향상시켰다.

• 한국대기환경학회지
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• 제26권5호
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• pp.475-489
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• 2010

In order to verify the enhancement of ozone and carbon monoxide (CO) during springtime in East Asia, we investigated weather conditions and data from remote sensors, air quality models, and air quality monitors. These include the geopotential height archived from the final (FNL) meteorological field, the potential vorticity and the wind velocity simulated by the Meteorological Mesoscale Model 5 (MM5), the back trajectory estimated by the Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model, the total column amount of ozone and the aerosol index retrieved from the Total Ozone Mapping Spectrometer (TOMS), the total column density of CO retrieved from the Measurement of Pollution in the Troposphere (MOPITT), and the concentration of ozone and CO simulated by the Model for Ozone and Related Chemical Tracers (MOZART). In particular, the total column density of CO, which mightoriginate from the combustion of fossil fuels and the burning of biomass in China, increased in East Asia during spring 2000. In addition, the enhancement of total column amounts of ozone and CO appeared to be associated with both the upper cut-off low near 500 hPa and the frontogenesis of a surface cyclone during a weak Asian dust event. At the same time, high concentrations of ozone and CO on the Earth's surface were shown at the Seoul air quality monitoring site, located at the surface frontogenesis in Korea. It was clear that the ozone was invaded by the downward stretched vortex anomalies, which included the ozone-rich airflow, during movement and development of the cut-off low, and then there was the catalytic photochemical reaction of ozone precursors on the Earth's surface during the day. In addition, air pollutants such as CO and aerosol were tracked along both the cyclone vortex and the strong westerly as shown at the back trajectory in Seoul and Busan, respectively. Consequently, the maxima of ozone and CO between the two areas showed up differently because of the time lag between those gases, including their catalytic photochemical reactions together with the invasion from the upper troposphere, as well as the path of their transport from China during the weak Asian dust event.