Journal of Advanced Marine Engineering and Technology
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제24권4호
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pp.441-445
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2000
Considering international status of our country as world class ship builder and geographical characteristics encircled by sea in three facets, controlling of air pollutants emission from marine engines becomes more and more important issue in recent days. Implementation of immediate pollutants emission control regulation and standardization of test and certification procedure are required to reduce air pollution from marine engines. But cost increments due to additional equipment of emission control device and development and certification test expenses as well as depreciation of fuel economy should be considered. To satisfy those air pollution reduction and economic requirements, we should make our own interpretation of IMO standard and implementation schedule depending on our country's status. For this purpose we measured NOx emission from small and middle class marine engines to calculate emission factor and total pollutant emission in our country. With the comparison and analysis of other countries emission control regulation we proposed basic data of total emission from marine engine and future emission control standard in our country. According to our estimation, 62% of total NOx emission of marine engines comes from fishing boat and 38% from commercial vessels. The portion of NOx emission from marine engine is 18.6% of whole country NOx emission. Due to the voyage characteristics of middle and large vessel and necessity of international harmonization of marine engine pollutants emission control standard, it is inevitable to adopt IMO standard for middle and large marine engines. But considering technological and cost effect of fishing boat operating in near sea, it is resonable to set a standard within 80% of measured value at the moment and gradually implement the same IMO standard in near future.
The objective of this study was to determine the effect of nitrification inhibitor dicyandiamide (DCD) and urease inhibitor hydroquinone (HQ) on ammonia ($NH_3$) and nitrous oxide ($N_2O$) emission from pig slurry applied to Timothy (Phleum pretense L.) sward. The daily emission of ammonia ($NH_3$) and nitrous oxide ($N_2O$) was monitored for 9 days in three different treatments; 1) control (only pig slurry application), 2) DCD treatment (pig slurry + DCD), and 3) HQ treatment (pig slurry + HQ). Most $NH_3$ emission occurred after 4~5 days in three treatments. Total $NH_3$ emission, expressed as a cumulative amount throughout the measurement time, was $1.33kg\;N\;ha^{-1}$ in the control. The DCD and HQ treatment decreased total $NH_3$ emission by 16.3% and 25.1%, respectively, compared to the control. Total $N_2O$ emission in the control was $47.1g\;N\;ha^{-1}$. The DCD and HQ treatment resulted in a reduction of 67.9% and 41.8% in total $N_2O$ emission, respectively, compared to the control. The present study clearly indicated that nitrification and urease inhibitor exhibited positive roles in reducing N losses through $NH_3$ and $N_2O$ emission.
Stationary combustion sources such as coal-fired power plants, waste incinerators, industrial manufacturing, etc. are recognized as major sources of mercury emissions. Due to rapid economic growth, zinc production in Korea has increased significantly during the last 30 years. Total zinc production in Korea exceeded 739,000 tons in 2008, and Korea is currently the third largest zinc producing country in the world. Previous studies have revealed that zinc smelting has become one of the largest single sectors of total mercury emissions in the World. However, studies on this sector are very limited, and a large gap in the knowledge regarding emissions from this sector needs to be bridged. In this paper, Hg emission measurements were performed to develop emission factors from zinc smelting process. Stack sampling and analysis were carried out utilizing the Ontario Hydro method and US EPA method 101A. Preliminary data showed that $Hg^0$ concentrations in the flue gas ranged from 4.56 to $9.90\;{\mu}g/m^3$ with an average of $6.40\;{\mu}g/m^3$, Hg(p) concentrations ranged from 0.03 to $0.09\;{\mu}g/m^3$ with an average of $0.04\;{\mu}g/m^3$, and RGM concentrations ranged from 0.23 to $1.17\;{\mu}g/m^3$ with an average of $6.40\;{\mu}g/m^3$. To date, emission factors of 7.5~8.0 g/ton for Europe, North America and Australia, and of 20 or 25 g/ton for Africa, Asia and South America are widely accepted by researchers. In this study, Hg emission factors were estimated using the data measured at the commercial facilities as emissions per ton of zinc product. Emission factors for mercury from zinc smelting pross ranged from 4.32 to 12.96 mg/ton with an average of 8.31 mg/ton. The emission factors that we obtained in this study are relatively low, considering Hg contents in the zinc ores and control technology in use. However, as these values are estimated by limited data of single measurement of each, the emission factor and total emission amount must be updated in future.
This short report describes the trend of exhaust emission control of the diesel engine vehicles in Korea, which originally was motivated from the newly proposed Emission Control Regulation of Diesel Engine Vehicles possible to be activated in 1991 by Korean Environmental Protection Agency. This short survey report has been prepared by the special working group of The Korea Society of Automotive Engineers (KSAE) on this particular subject. This report includes (1) estimation of portions of contribution of diesel engine vehicle emission to total air pollution, (2) comparison of proposals of new articles/regulations/laws in Korea with those of other selected countries such as USA, European countries, and Japan, (3) comparison of vehical emission control regulations in Korea with those in other selected countries, (4) technical aspects of possibilities of reduction of diesel engine vehicle emissions, (5) additional administrational aspects of technology development program, (6) social impact resulted from the severe emission control regulation on diesel engine vehicles, and (7) proposals, prepared by the special working group of the KSAE, on the emission control regulation of diesel engine vehicles, which can possibly bring better cleaner air released from the air pollution resulted from diesel engine exhaust emissions in real sense with minimal financial contribution, with optimal technological efforts, with less social impacts, within five to ten year period.
Up to the present time, many methods to estimate emissions from a particular diesel engines have wholly depended on the quantity of diesel fuel consumed. Then, the recommended emission factors were normalized by fuel consumption, and further total activity was estimated by the total fuel consumed. One of main purposes in the study is newly to develop emission factors for the railroad diesel rolling stock (RDRS) and to estimate a total amount of major gaseous pollutants from the RDRS in Korea. Prior to develop a Korean mode emission factor. the emission factor from the USEPA was simply applied for comparative studies. When applying the USEPA emission factors, total exhaust emissions from the RDRS in Korea were estimated by 28,117tons of NOx, 2,832.3tons of CO, and 1,237.5tons of HC, etc in 2001. In this study, a emission factor for the RDRS, so called the KoRail mode (the Korean Railroad mode) has been developed on the basis of analyzing the driving pattern of the Gyeongbu-Line especially for the line-haul mode. Explicitly to make the site specific emission factors, many uncertainty problems concerning weighting factors for each power mode, limited emission test, incomplete data for RDRS, and other important input parameters were extensively examined. Total exhaust emissions by KoRail mode in Korea were estimated by 10,960tons of NOx, and 4,622tons of CO, and so on in the year of 2001. The emissions estimated by the USEPA mode were 2.6 times higher for NOx, and 1.6 times lower for CO than those by the KoRail mode. As a conclusion, based on the emission calculated from both the USEPA mode and the KoRail mode, the RDRS is considered as one of the significant mobile sources for major gaseous pollutants and thus management plans an(1 control strategies for the RDRS must be established to improve air quality near future in Korea.
Park, Sang-Hyun;Lee, Bok-Rye;Jeong, Kwang-Hwa;Kim, Tae-Hwan
한국초지조사료학회지
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제38권3호
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pp.145-149
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2018
The objective of this study was to determine the effect of injection application of pig slurry on ammonia ($NH_3$) and nitrous oxide ($N_2O$) emission from timothy (Phleum pretense L.) sward. The three treatments were applied: 1) only water as a control, 2) pig slurry application by broadcasting, 3) pig slurry application by injection. The pig slurry was applied at a rate of $200kg\;N\;ha^{-1}$. Total $NH_3$ and $N_2O$ emission, expressed as a cumulative amount throughout the measurement time (40 days), was $2.68kg\;NH_3-N\;ha^{-1}$ and $6.58g\;N_2O-N\;ha^{-1}$, respectively, in the control. The injection application of pig slurry decreased total $NH_3$ and $N_2O$ emission by 39.8% and 33.3%, respectively, compared to broadcasting application of pig slurry. The present study clearly showed that injection application exhibited positive roles in reducing N losses through $NH_3$ and $N_2O$ emission.
Generally. mobile sources of air pollution were classified in on-road and non-road. Due to increased registration number of construction equipment in Korea. updated emission factors for non-road mobile sources, such as construction machinery. should be developed. NONROAD model of U.S. EPA already has introduced transient adjustment factors and sulfur adjustment factors for emission factors of diesel powered engine. In addition to this. European Environment Agency (EEA) has proposed emission factors for off-road machinery including several types of construction equipment. In this study. six types of construction equipment, such as excavator. forklift, loader, crane, roller and bulldozer, were studied to estimate emission factors based on total registration status in Korea. Total 445 construction equipments between 2004 and 2007 model year were tested with KC1-8 mode and air pollutants (CO, THC, $NO_x$, and PM) were measured. After statistical estimation and calculation, emission factors for CO, THC, $NO_x$, and PM for excavator, forklift, loader, crane, roller and bulldozer were provided and compared with previous emission factors. Moreover, updated emission factors for six types of construction equipment in this study were verified after comparison with emission factors of U.S. EPA. Finally, estimated emission amounts of four air pollutants were suggested according to six types of construction equipment.
We have studied an organic layer and semitransparent Al electrode thickness dependent optical properties and microcavity effects for top-emission organic light-emitting diodes. Manufactured top-emission device structure is Al(100nm)/TPD(xnm)/Alq(ynm)/LiF(0.5nm)/Al(25nm). While a thickness of total organic layer was varied from 85nm to 165n, a ratio of those two layers was kept to be about 2:3. Semitransparent Al cathode was varied from 20nm to 30nm for the device with an organic layer total thickness of 140nm. As the thickness of total organic layer increases, the emission spectra show a shift of peak wavelength from 490nm to 580nm, and the full width at half maxima from 90nm to 35nm. The emission spectra show a blue shift as the view angle increases. Emission spectra depending on a transmittance of semitransparent cathode show a shift of peak wavelength from 515nm to 593nm. At this time, the full width at half maximum was about to be a constant of 50nm. With this kind of microcavity effect, we were able to control the emission spectra from the top-emission organic light-emitting diodes.
This study was conducted to evaluate effects of plant extracts on methanogenesis and rumen microbial diversity in in vitro. Plant extracts (Artemisia princeps var. Orientalis; Wormwood, Allium sativum for. Pekinense; Garlic, Allium cepa; Onion, Zingiber officinale; Ginger, Citrus unshiu; Mandarin orange, Lonicera japonica; Honeysuckle) were obtained from the Plant Extract Bank at Korea Research Institute of Bioscience and Biotechnology. The rumen fluid was collected before morning feeding from a fistulated Holstein cow fed timothy and commercial concentrate (TDN; 73.5%, crude protein; 19%, crude fat; 3%, crude fiber; 12%, crude ash; 10%, Ca; 0.8%, P; 1.2%) in the ratio of 3 to 2. The 30 ml of mixture, comprising McDougall buffer and rumen liquor in the ratio of 4 to 1, was dispensed anaerobically into serum bottles containing 0.3 g of timothy substrate and plant extracts (1% of total volume, respectively) filled with $O_2$-free $N_2$ gas and capped with a rubber stopper. The serum bottles were held in a shaking incubator at $39^{\circ}C$ for 24 h. Total gas production in all plant extracts was higher (p<0.05) than that of the control, and total gas production of ginger extract was highest (p<0.05). The methane emission was highest (p<0.05) at control, but lowest (p<0.05) at garlic extract which was reduced to about 20% of methane emission (40.2 vs 32.5 ml/g DM). Other plant extracts also resulted in a decrease in methane emissions (wormwood; 8%, onion; 16%, ginger; 16.7%, mandarin orange; 12%, honeysuckle; 12.2%). Total VFAs concentration and pH were not influenced by the addition of plant extracts. Acetate to propionate ratios from garlic and ginger extracts addition samples were lower (p<0.05, 3.36 and 3.38 vs 3.53) than that of the control. Real-time PCR indicted that the ciliate-associated methanogen population in all added plant extracts decreased more than that of the control, while the fibrolytic bacteria population increased. In particular, the F. succinogens community in added wormwood, garlic, mandarin orange and honeysuckle extracts increased more than that of the others. The addition of onion extract increased R. albus diversity, while other extracts did not influence the R. albus community. The R. flavefaciens population in added wormwood and garlic extracts decreased, while other extracts increased its abundance compared to the control. In conclusion, the results indicated that the plant extracts used in the experiment could be promising feed additives to decrease methane gas emission from ruminant animals while improving ruminal fermentation.
In Korea, PM (Particulate Matter) emissions caused by coal-fired power plants are measured by a system, so called Clean Air Policy Support System (CAPSS), which uses foreign emission factors. However, the system fails to reflect the characteristics of domestic power plants. In this regard, this study aims to develop local, accurate domestic emission factors. The study measured the amount of TSP (Total Suspended Particulates), PM10 and PM2.5 by collecting samples from the latter parts of pollution control devices which were installed at 3 bituminous-fired power plants and 3 anthracite-fired power plants. The results showed that the average concentrations of TSP, PM10 and PM2.5 measured at bituminous-fired power plants were 4.63 mg/$Sm^3$, 2.96 mg/$Sm^3$ and 3.07 mg/$Sm^3$ respectively, much higher than those from anthracite-fired power plants (2.96 mg/$Sm^3$, 2.47 mg/$Sm^3$ and 1.37 mg/$Sm^3$, respectively). In addition, bituminous-fired power plants showed higher ratios of PM10/TSP and PM2.5/TSP with 0.66 and 0.92, respectively, compared to 0.82 and 0.46, the ratios of PM10/TSP and PM2.5/TSP measured in anthracite-fired power plants. Emission factors based-on concentration measurements were also higher for bituminous-fired power plants, and PM with smaller particles tended to have bigger difference in emission factors between the two fuels. This study calculated the amount of PM emissions by using the estimated emission factors. When it comes to the PM emissions, it was less than that of CAPSS while similar to that of CleanSYS in its amount. It is expected that the emission factors developed by this study will be used in Korea replacing foreign emission factors currently used in Korea by ensuring the objectivity and reliability as domestic emission factors.
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