• Title/Summary/Keyword: total deposition

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Effect of Heat Treatment on the Corrosion Resistance of the Al-Mg Coated Steel Sheet (열처리가 Al-Mg 코팅 강판의 내식성에 미치는 영향)

  • Jung, Jae-Hun;Yang, Ji-Hoon;Song, Min-A;Kim, Sung-Hwan;Jeong, Jae-In;Lee, Myeong-Hoon
    • Journal of Surface Science and Engineering
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    • v.47 no.4
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    • pp.186-191
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    • 2014
  • Double layer films which consisted of aluminum(Al) and magnesium(Mg) have been prepared by e-beam deposition. The structure, alloy phase, and corrosion resistance of the prepared films were investigated before and after heat treatment. The first (bottom) layer fixed with Al, and the thickness ratio between Al and Mg layers has been changed from 1 : 1 to 5 : 1, respectively. Total thickness of Al-Mg film was fixed at $3{\mu}m$. The cold-rolled steel sheet was used as a substrate. Heat treatment was fulfilled in an nitrogen atmosphere at the temperature of $400^{\circ}C$ for 2, 3 and 10 min. Surface morphology of as-deposited Al-Mg film having Mg top layer showed plate-like structure. The morphology was not changed even after heat treatment. However, cross-sectional morphology of Al-Mg films was drastically changed after heat treatment, especially for the samples heat treated for 10 min. The morphology of as-deposited films showed columnar structure, while featureless structure of the films appeared after heat treatment. The x-ray diffraction data for as-deposited Al-Mg films showed only pure Al and Mg peaks. However, Al-Mg alloy peaks such as $Al_3Mg_2$ and $Al_{12}Mg_{17}$ appeared after heat treatment of the films. It is believed that the formation of Al-Mg alloy phase affected the structure change of Al-Mg film. It was found that the corrosion resistance of Al-Mg film was increased after heat treatment.

The Characteristics of PCBs Deposition on Plants (PCBs의 식물에 대한 침착 특성)

  • Kim, Tae-Wook;Yeo, Hyun-Gu;Choi, Min-Kyu;Chun, Man-Young
    • Korean Journal of Environmental Agriculture
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    • v.20 no.2
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    • pp.99-107
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    • 2001
  • PCBs(Polychlorinated biphenyls) in air and plants were measured every two weeks at Hankyong University located in Ansung, Kyoung ki province from July to November in 1999. The percentage of tri-CBs(PCB 28) and tetra-CBs(PCB 52) is 49% of the total PCBs in air, which shows these two components are the major congeners. A correlation coefficient(r) of PCB congeners detected in two plants is 0.83 (p<0.01), indicating that the plants can be used as a passive sampler to indirectly estimate the pollution levels of residual PCBs in the environmental even if they have different physicochemical properties. The average ratio of PCB 110/PCB 52 is higher in plants as 0.5, 2.9 and 2.5 respectively in the air and mulberry leaves as well as scallions, which comes from the higher lipophilicity of PCB 110 rather than the ratio of PCB 110/PCB 52 in the air.

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Plasma control by tuning network modification in 4MHz ionized-physical vapor deposition (4MHz I-PVD장치에서 정합회로를 이용한 플라즈마 제어)

  • 주정훈
    • Journal of the Korean Vacuum Society
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    • v.8 no.1
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    • pp.75-82
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    • 1999
  • Ion energy is one of the crucial property in thin film deposition by internal ICP assisted I-PVD. As ion energy is determined by the difference between the plasma potential and the substrate bias potential, ICP excitation frequency was tested with medium frequency of 4 MHz and two types of tuning circuits, alternate and floating LC network with a biasing resistor, were tested. The results showed that plasma potential was less than 5 V in a range of Ar pressures, 5mTorr to 30 mTorr, at 4 MHz RF 600 W and 60 V of maximum RF antenna voltage was maintained either at RF input or output terminal. By proper control of RLC circuit installed after after RF antenna, 50V of RF induced voltage on RF antenna was obtained at 500W input power. The total impedance of RF antenna and plasma was around 10$\Omega$, and minimum RF voltage was obtained with a condition of lowest reactance at most 0.05$\Omega$.

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인공관절의 수명 향상을 위해 PIII&D (Plasma Immersion Ion Implantation & Deposition) 기술로 제조된 인공관절용 NbN 박막의 마모 특성 평가

  • Park, Won-Ung;Jeon, Jun-Hong;Mun, Seon-U;Choe, Jin-Yeong;Im, Sang-Ho;Han, Seung-Hui
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.189-189
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    • 2011
  • 인공관절은 노인성 질환이나 자가 면역질환, 신체적인 외상 등으로 인하여 발생하는 관절의 손상 부위를 대체하기 위해 고안된 관절의 인공 대용물이다. 인공 관절 중 인공 고관절의 경우 관절 운동을 하는 라이너(Liner)와 헤드(Head) 부분이 인공관절의 수명을 결정하게 되는데, 헤드 부분에 메탈소재와 라이너 부분에 고분자 소재를 사용하는 MOP (metal on polymer) 구조의 인공관절은 충격흡수의 장점이 있는 반면 wear debris에 의한 골용해로 인하여 관절이 느슨해지는 문제점이 발생하여 재 시술의 주요 원인이 되고 있다. 또한 메탈 헤드의 마모로 인한 금속이온의 용출은 세포 독성의 문제를 야기하여 인공관절의 수명을 낮추는 또 하나의 요인이 되고 있다. 따라서 인공관절의 수명을 늘리기 위해 DLC, ZrO, TiN 등의 높은 경도 값을 갖는 박막을 금속 헤드 위에 증착하여 상대재인 인공관절용 고분자 소재의 마모량을 줄이고자 하는 연구가 활발하게 진행 되고 있다. 본 연구에서는 PIII&D (Plasma Immersion Ion Implantation & Deposition)공정을 이용하여 Co-Cr-Mo 합금 소재 niobium nitride (NbN) 박막을 증착하여 상대제인 UHMWPE (ultra high molecular polyethylene)의 마모를 줄이고자 하는 연구를 진행하였다. 마모량을 감소시키기 위하여, 박막 증착전에 질소를 이온주입하는 pre-ion implantation 공정을 도입하였으며, 또한 Co-Cr 합금과 NbN박막 사이의 접착력을 증가시키기 위하여 박막의 증착 초기에 이온주입과 증착을 동시에 수행하는 dynamic ion mixing공정을 수행하였다. NbN 박막의 특성을 평가하기 위해 XRD, XPS, AFM 등의 분석을 수행하였으며, 상대재인 초고분자량 폴리에틸렌의 마모량을 측정하기 위해 Pin-on-disk tester를 이용하여 마모 실험을 진행하였다. 마모 실험 결과, pre-ion implantation 공정을 도입한 경우 현재 상용화 되어있는 Co-Cr 합금에 비하여 마모량을 2배 이상 감소시키는 것을 확인 할 수 있었으며, dynamic ion mixing 공정을 도입한 경우 장시간의 마모 시험에 대한 마모 특성이 향상 되는 것을 확인 할 수 있었다.

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Effect of the Coating Structure on the Corrosion Resistance of Al-Mg Coated Steel (Al-Mg 코팅층의 구조가 강판 내식성에 미치는 영향)

  • Jung, Jae-Hun;Yang, Ji-Hoon;Kim, Sung-Hwan;Byeon, In-Seop;Jeong, Jae-In;Lee, Myeong-Hoon
    • Journal of Surface Science and Engineering
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    • v.49 no.5
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    • pp.454-460
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    • 2016
  • Double-layered Al-Mg films have been deposited by using an e-beam deposition method on a cold-rolled steel sheet(CR), which the structure of the film was Al/Mg/CR. The micro-structure, alloy phase, and corrosion resistance of the Al-Mg coated CR were investigated before and after heat treatment at $400^{\circ}C$ for 2, 3, and 10 min in a nitrogen atmosphere. Total thickness of Al-Mg films was fixed at $3{\mu}m$ and the thickness ratio of Al and Mg layers(Al:Mg) has been changed from 5:1 to 1:5. The cross-sectional morphology of the films, which had the thickness ratio of 2:1(Al:Mg), 1:1, and 1:2, was changed after heat treatment from columnar to featureless structure. The x-ray diffraction data for as-deposited films showed only pure Al and Mg peaks. Al-Mg alloy peaks such as $Al_3Mg_2$ and $Al_{12}Mg_{17}$ phase appeared after the heat treatment. The Al-Mg coating with the thickness ratio of 1:1(Al:Mg) showed the best corrosion resistance of up to 500 hours by salt spray test.

Fabrication of Indium Tin Oxide (ITO) Transparent Thin Films and Their Microwave Shielding Properties (Indium Tin Oxide (ITO) 투광성 박막의 제조 및 전자파 차폐특성)

  • Kim, Yeong-Sik;Jeon, Yong-Su;Kim, Seong-Su
    • Korean Journal of Materials Research
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    • v.9 no.11
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    • pp.1055-1061
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    • 1999
  • Indium Tin Oxide (ITO) films were fabricated by vacuum deposition technique and their microwave shielding properties were investigated for the application to the transparent shield material. The vacuum coating was conducted in a RF co-sputtering machine. The film composition and structure associated with the sputtering conditions (argon and oxygen pressure. substrate temperature. RF input power) were investigated for the attainment of high electrical conductivity and good transparency. The electrical conductivity of IT0 films fabricated under the optimum deposition conditions (substrate temperature : $300^{\circ}C$. Ar flow rate : 20 sccm, Oxygen flow rate : 10 sccm, In/Sn input power : 50/30 W) showed 5.6$\times10^4$mho/m. The optical transparency is also considerably good. The microwave shielding properties including the dominant shielding mechanism are investigated from the electrical conductivity, thickness and skin depth of the ITO films. The total shielding effectiveness is then estimated to be 26 dB, which provides a suggestion that the IT0 films can be effectively used as the transparent shield material.

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Development of an Accident Consequence Assessment Code for Evaluating Site Suitability of Light- and Heavy-water Reactors Based on the Korean Technical Standards

  • Hwang, Won Tae;Jeong, Hae Sun;Jeong, Hyo Joon;Kil, A Reum;Kim, Eun Han;Han, Moon Hee
    • Journal of Radiation Protection and Research
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    • v.41 no.4
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    • pp.368-372
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    • 2016
  • Background: Methodologies for a series of radiological consequence assessments show a distinctive difference according to the design principles of the original nuclear suppliers and their technical standards to be imposed. This is due to the uncertainties of the accidental source term, radionuclide behavior in the environment, and subsequent radiological dose. Both types of PWR and PHWR are operated in Korea. However, technical standards for evaluating atmospheric dispersion have been enacted based on the U.S. NRC's positions regardless of the reactor types. For this reason, it might cause a controversy between the licensor and licensee of a nuclear power plant. Materials and Methods: It was modelled under the framework of the NRC Regulatory Guide 1.145 for light-water reactors, reflecting the features of heavy-water reactors as specified in the Canadian National Standard and the modelling features in MACCS2, such as atmospheric diffusion coefficient, ground deposition, surface roughness, radioactive plume depletion, and exposure from ground deposition. Results and Discussion: An integrated accident consequence assessment code, ACCESS (Accident Consequence Assessment Code for Evaluating Site Suitability), was developed by taking into account the unique regulatory positions for reactor types under the framework of the current Korean technical standards. Field tracer experiments and hand calculations have been carried out for validation and verification of the models. Conclusion: The modelling approaches of ACCESS and its features are introduced, and its applicative results for a hypothetical accidental scenario are comprehensively discussed. In an applicative study, the predicted results by the light-water reactor assessment model were higher than those by other models in terms of total doses.

The Effect of Conjugated Linoleic Acid(CLA) Supplemented to Different Fat Sources on Fat Depositions and Stearoyl-CoA Desaturase l(SCDl) Gene Expression in Mice (지방 급원을 달리한 식이에 첨가된 CLA가 지방조직과 Stearoyl-Co A Desaturase 1(SCD 1) 발현에 미치는 영향)

  • Lee, Se-Na;Kang, Keum-Jee
    • The Korean Journal of Food And Nutrition
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    • v.20 no.3
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    • pp.245-252
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    • 2007
  • This study investigated the effects of conjugated linoleic acid(CLA) on the fat deposition, triglyceride levels and the expression of stearoyl-CoA desaturase 1(SCD1) in the livers of male ICR mice that were fed with either soybean oil or beef tallow supplemented with CLA. Mice weighing $25{\sim}30$ g were divided into four groups; soybean oil(SBO), and SBO supplemented with 1% CLA(SBOC), beef tallow(BT) and BT supplemented with 1% CLA(BTC). Each group consisted of 10 mice that were fed the experimental diets for 4 weeks. The experimental diets consisted of 64% carbohydrate, 20% protein, and 16% fat in terms of their contributions to total calories. All other nutrients were identical in the diets. Triglyceride measurements were completed using a kit. Fatty acid compositions were analyzed in the liver using gas chromatography. The levels of SCD1 expression were analyzed by RT-PCR in the liver. No significant differences were found for food intake level, body weight and food efficiency among the experimental groups. However, the weights of epididymal fat pads and plasma triglyceride levels were significantly lower in SBOC and BTC(p<0.05) compared to the SBO and BT groups. These effects were similar in the CLA supplemented groups. The expression level of SCD1 gene and ${\Delta}9$ desaturase index were not significantly different, regardless of the fat used for CLA supplementation. Based on these results, addition of CLA showed decreasing effects on the fat depots weight and the concentration of triglyceride regardless of the fat sources. The SCD1 gene expression and ${\Delta}9$ desaturase index were not influenced by the types of fats with respect to the CLA effects.

3D printing of multiple container models and their trajectory tests in calm water

  • Li, Yi;Yu, Hanqi;Smith, Damon;Khonsari, M.M.;Thiel, Ryan;Morrissey, George;Yu, Xiaochuan
    • Ocean Systems Engineering
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    • v.12 no.2
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    • pp.225-245
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    • 2022
  • More and more shipping containers are falling into the sea due to bad weather. Containers lost at sea negatively affect the shipping line, the trader and the consumer, and the environment. The question of locating and recovering dropped containers is a challenging engineering problem. Model-testing of small-scaled container models is proposed as an efficient way to investigate their falling trajectories to salvage them. In this study, we first build a standard 20-ft container model in SOLIDWORKS. Then, a three-dimensional (3D) geometric model in the STL (Standard Tessellation Language) format is exported to a Stratasys F170 Fused Deposition Modeling (FDM) printer. In total, six models were made of acrylonitrile styrene acrylate (ASA) and printed for the purpose of testing. They represent three different loading conditions with different densities and center of gravity (COG). Two samples for each condition were tested. The physical models were dropped into the towing tank of University of New Orleans (UNO). From the experimental tests, it is found that the impact of the initial position after sinking can cause a certain initial rolling velocity, which may have a great impact on the lateral displacement, and subsequently affect the final landing position. This series of model tests not only provide experimental data for the study of the trajectory of box-shape objects but also provide a valuable reference for maritime salvage operations and for the pipeline layout design.

Synthetic Strategy and Optical Property Characterization of Complex Nanorods: Plasmon Wave Guide and Solar Cell

  • Park, Sung-Ho
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.111-111
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    • 2012
  • In this talk, we represent a novel approach to investigating intra-nanorod surface plasmon coupling with control over block compositions. The multi-component rod-like nanostructures, which consist of optically active components (Au and Ag) and optically less active component (for example, Ni) in UV-vis-NIR spectral window, showed interesting optical response depending on each block length and the total length of the structure. By controlling the composition and relative lengths of the blocks that comprise these structures, we can tailor the overall optical properties. Depending on the relative fraction of Au and Ag blocks, the intensity of the transverse modes varied without noticeable peak shifts. However, the strong intraparticle surface plasmon coupling resulted in the collective appearance of longitudinal LSP modes, including higher-order modes. The experimental observations were confirmed by theoretical calculation, using a discrete dipole approximation method. In addition, we will briefly discuss how single nanorod solar cells can be synthesized by using by using electrochemical deposition and AAO hard templates.

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