• Title/Summary/Keyword: total binder content

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Asbestos Content in Friable Sprayed-on Surface Material and Airborne Fiber Concentrations in Commercial Buildings (대형건물내 비고형 석면함유 건축자재에 의한 기중 석면오염 및 관리실태)

  • Kim, Hyunwook
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.5 no.2
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    • pp.137-146
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    • 1995
  • Twenty(20) large commercial buildings located in Seoul with friable sprayed-on surface insulation material on ceilings were investigated for asbestos content in bulk material by polarized light microscopy and for airborne fiber concentrations in buildings by phase contrast microscopy. In addition, such building-related variables as building age, numbers of traffic, airflow, surface conditions of the ceiling, temperature, and humidity were studied for any correlation with airborne fiber concentrations. The results were as follows: 1. Chrysotile asbestos was found in two bulk samples with 3-5% content and with <1%in one sample out of total 20 bulk samples collected. Glass fiber and mineral wool were the two major constituents of the bulk samples. 2. The ceiling surfaces were very friable in 16 buildings and were relatively hard in 4 buildings. The friability of the surface material was dependent upon the type and the amount of binder that had been mixed with the sprayed-on surface material. 3. Airborne fiber concentrations were log-normally distributed and the geometric mean(geometric standard deviation) fiber concentrations in the underground parking lots, inside buildings, and outdoor ambient air were 0.0063(1.97)f/cc, 0.0068(2.29)f/cc, and 0.0033(2.36)f/cc, respectively. 4. No significant relationship of airborne fiber concentrations and all building-related variables studied except humidity was found. The results of this study suggest that the sprayed-on surface insulation material found in some commercial buildings may possibly be contaminated with asbestos. Since most of the ceiling surfaces surveyed were very friable and poorly maintained and the airborne fiber concentrations were relatively high, there is a possibility of asbestos fiber contamination in these buildings, particularly at those buildings with asbestos-contaminated surface material. Since poorly maintained surface conditions were thought to be a source of high airborne fiber concentrations, there is a urgent need of a systematic operation and maintenance program. Further study of non-occupational asbestos exposure in general population utilizing advanced analytical technique such as transmission electron microscopy is highly recommended.

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Performance Evaluation of Bridge Deck Materials based on Ordinary Portland Cement Concrete (보통 포틀랜드 콘크리트 기반 교면포장 재료 성능 평가)

  • Nam, Jeong-Hee;Jeon, Seong Il;Kwon, Soo Ahn
    • International Journal of Highway Engineering
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    • v.19 no.6
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    • pp.129-137
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    • 2017
  • PURPOSES : The purpose of this study is to develop bridge deck concrete materials based on ordinary Portland cement concrete, and to evaluate the applicability of the developed materials through material properties tests. METHODS : For field implementation, raw material (cement, fine aggregate, and coarse aggregate) properties, fresh concrete properties (slump and air content), strength (compressive, flexural and bond strength) gain, and durability (freeze-thaw resistance, scaling resistance, and rapid chloride penetrating resistance) performance were evaluated in the laboratory. RESULTS : For the selected binder content of $410kg/m^3$, W/B = 0.42, and S/a = 0.48, the following material performance results were obtained. Considering the capacity of the deck finisher, a minimum slump of 150 mm was required. At least 6 % of air content was obtained to resist freeze-thaw damage. In terms of strength, 51.28 MPa of compressive strength, 7.41 MPa of flexural strength, and 2.56 MPa of bond strength at 28 days after construction were obtained. A total of 94.9 % of the relative dynamic modulus of elasticity after 300 cycles of freeze-thaw resistance testing and $0.0056kg/m^2$ of weight loss in a scaling resistance test were measured. However, in a chloride ion penetration resistance test, the result of 3,356 Coulomb, which exceeds the threshold value of the standard specification (1000 Coulomb at 56 days) was observed. CONCLUSIONS : Instead of using high-performance modified bridge deck materials such as latex or silica fume, we developed an optimum mix design based on ordinary Portland cement concrete. A test construction was carried out at ramp bridge B (bridge length = 111 m) in Gim Jai City. Immediately after the concrete was poured, the curing compound was applied, and then wet mat curing was applied for 28 days. Considering the fact that cracks did not occur during the monitoring period, the applicability of the developed material is considered to be high.

Microstructure and Strength Properties of Alkali-activated Binder mixed with Sea Water (해수를 사용한 알칼리 활성화 결합재의 미세구조 및 강도 특성)

  • Jun, Yubin;Oh, Jae-Eun
    • Journal of the Korea Concrete Institute
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    • v.28 no.3
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    • pp.299-308
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    • 2016
  • This paper presents an investigation of the mechanical and microstructural properties on hardened samples that were synthesized using blended binder(fly ash(FA) and blast furnace slag cement(BFSC)), alkali activator and sea water or distilled water. Binders were prepared by mixing the FA and BFSC in different blend weight ratios of 6:4, 7:3 and 8:2. Sodium hydroxide and sodium silicate were used 5 wt% of binder, respectively, as an alkaline activator. The compressive strength and absorption were measured at the age of 3, 7 and 28 days, and the XRD, TGA and MIP tests were performed at the age of 28 days. An increase in the content of BFSC leads to an increase in the quantities of ettringite and C-S-H formed, regardless of the type of mixing water. And it also shows higher strength due to the reduction of pores larger than ~50 nm. All hardened samples in this study have common hydration products of C-S-H, $Ca(OH)_2$ and calcite. Hydrocalumite of all reaction products formed was only present in hardened sample mixed with sea water. For each FA/BFSC mixing ratio, the compressive strength of hardened sample mixed with sea water was similar to that mixed with distilled water. It is proposed that the slight increase of strength of samples mixed with sea water is mainly due to the presence of hydrocalumite phase containing chlorine ion, contributing to the change of total porosity and pore size distribution in samples.

Experimental investigation on durability performance of rubberized concrete

  • Guneyisi, Erhan;Gesoglu, Mehmet;Mermerdas, Kasim;Ipek, Suleyman
    • Advances in concrete construction
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    • v.2 no.3
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    • pp.193-207
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    • 2014
  • The study presented herein aims to investigate the durability related properties of rubberized concrete. Two types of waste scrap tire rubber were used as fine and coarse aggregate, respectively. The rubber was replaced with aggregate by three crumb rubber and tire chips levels of 5, 15, and 25% for the rubberized concrete productions. In order to improve the transport properties and corrosion resistance of rubberized concretes, SF was replaced with cement at 10% replacement level by weight of total binder content. The transport properties of the rubberized concretes were investigated through water absorption, gas permeability, and water permeability tests. The corrosion behavior of reinforcing bars embedded in plain and silica fume based rubberized concretes was investigated by linear polarization resistance (LPR) test. The results indicated that the utilization of SF in the rubberized concrete production enhanced the corrosion behavior and decreased corrosion current density values. Moreover, the reduction in the water and gas permeability coefficients was observed by the incorporation of SF in plain and especially rubberized concretes.

Volumetric Change of Concrete Subjected to Different Curing Condition (양생 조건에 따른 콘크리트의 체적 변화)

  • Lee Kwang Myong;Lee Hoi Keun;Lee Sung Jin;Baek Biehn
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.05a
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    • pp.132-135
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    • 2004
  • High-performance concrete (HPC) may be expected to differ from usual concrete with respect to shrinkage behavior, and it shows high autogenous shrinkage due to the use of very low water-binder ratio (w/b) and various admixtures. Therefore, in order to minimize the shrinkage stress and to ensure the service life of concrete structure, volumetric change of HPC should be understood. In this study, small prisms made of HPC with w/b of 0.32 and blast-furnace slag content of $0\%,\;30\%,\;and\;50\%$ were prepared to measure the volumetric changes such as autogenous shrinkage, drying shrinkage, and swelling under three different curing conditions. It was observed that the concrete cured. sealed condition showed only autogenous shrinkage while the concrete let to dry condition at temperature of $20^{\circ}C$ and relative humidity of $60\%$ during the test period showed both autogenous and drying shrinkage. Moreover, the concrete exposed to dry condition after 2-day water curing swelled and then started to shrink with age. The total shrinkage (autogenous+drying) of this concrete was smaller than that of the concrete cured dry condition, especially at early-age. Therefore, the early-age moisture curing is very effective to control or minimize the volumetric change and its induced stress of HPC.

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Effects of Reducing Agents on Textural Changes and Protein Modification in Extruded Wheat Gluten (압출성형시 환원제 첨가에 의한 밀가루 글루텐의 조직 변화와 단백질의 변성)

  • 고봉경
    • Journal of the East Asian Society of Dietary Life
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    • v.6 no.2
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    • pp.213-219
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    • 1996
  • Addition of reducing agents during extrusion markedly affected physical and chemical properties of wheat flour and gluten extrudates. Expansion at the die was increased for wheat flour and gluten extrudates. Organic materials containing sulfur were evaporated as a flavor from gluten at the die and total sulfur contents were decreased. Physical shape was different for gluten extrudates without reducing agents. It was difficult to form the long strand of gluten extrudate without cooling die. Hydroquinone accelerated cell breakdown and produced more irregular shape of extrudate. However, addition of cysteine decreased the cell breakdown and produced the long strand of gluten extrudates. Chemical reactions of reducing agents such as cysteine and hydroquinone were different for high content (<80%) of wheat gluten. It was assumed that reducing agents donated hydrogen to inhibit the formation of disulfide crosslinking, decreased the dough strength and produced the broken cell and irregular shape of extrudates. Whereas, cysteine reacted as a binder as well as reducing agent and formed long strands. The evidence of reaction of reducing agents was shown from the fact that non-protein disulfide was increased and protein disulfide was slightly decreased from cysteine added gluten extrudate.

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Binder-free Sn/Graphene Nanocomposites Prepared by Electrophoretic Deposition for Anode Materials in Lithium Ion Batteries

  • Bae, Eun Gyoung;Hwang, Yun-Hwa;Pyo, Myoungho
    • Bulletin of the Korean Chemical Society
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    • v.34 no.4
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    • pp.1199-1204
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    • 2013
  • Nanocomposites consisting of Sn nanoparticles and graphene oxide (GO) were electrophoretically deposited onto Cu current collectors that was used for anodes in Li ion batteries (LIBs). In order to optimize the electrochemical performance of nanocomposites as an anode material by controlling the oxygen functionality, the GO was subjected to $O_3$ treatment prior to electrophoretic deposition (EPD). During thermal reduction of the GO in the nanocomposites, the Sn nanoparticles were reduced in size, along with the formation of SnO and/or $SnO_2$ at a small fraction, relying on the oxygen functionalities of the GO. The variation in the duration of time for the $O_3$ irradiation resulted in a small change in total oxygen content, but in a significantly different fraction of each functional group in the GO, which influenced the Sn nanoparticle size and the amount of SnO (and/or $SnO_2$). As a result, the EPD films prepared with the GO that possessed the least amount of carboxylic groups (made by treating GO in an $O_3$ environment for 3 h) showed the best performance, when compared with the nanocomposites composed of untreated GO or GO that was $O_3$-treated for a duration of less than 3 h.

Performance Evaluation of RAP and WMA Mixtures Located in MN/Road Test Cells through Air Voids Analyses (MN/Road 시험포장 구간내의 공기량 측정 및 결과값 분석을 통한 RAP 및 저온 아스팔트(WMA) 혼합물의 특성 평가)

  • Moon, Ki Hoon;Falchetto, Augusto Cannone;Jeong, Jin Hoon
    • International Journal of Highway Engineering
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    • v.16 no.4
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    • pp.63-74
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    • 2014
  • PURPOSES: This research is to evaluate the mechanical performance of different types of Hot Mix Asphalt (HMA) pavement cells prepared for MN/Road field testing section through an extensive experimental analysis of air voids and simple statistical evaluation tools (i.e. hypothesis test). METHODS: An extensive experimental work was performed to measure air voids in 82 asphalt mixture cores (238 samples in total) obtained from nine different types of road cell located in MN/Road testing field. In order to numerically and quantitatively address the differences in air voids among the different test Cells built in MN/Road, a simple statistical test method (i.e. t-test) with 5% significance was used. RESULTS: Similar trends in air voids content were found among the mixtures including conventional HMA, Reclaimed Asphalt Pavement (RAP) and Warm Mix Asphalt (WMA) combined with taconite aggregate this provides support to the use of RAP and WMA technology in the constructions of asphalt pavement. However, in case of acid modified HMA mixtures, significant differences in air void content were observed between on the wheel path and between wheel path location, which implies negative performances in rutting and thermal cracking resistances. Conclusions : It can be concluded that use of RAP and WMA technology in the construction of conventional asphalt pavement and the use of PPA (Poly Phosphoric Acid) in combinations with SBS (Styrene Butadiene Styrene) in asphalt binder production provide satisfactory performance and, therefore, are highly recommended.

Study on the Optimum Harvest Timing for Different Operational Systems of Rice (벼의 수확작업 체계별 수확정기 결정에 관한 연구)

  • 이종호;강화석;정창주
    • Journal of Biosystems Engineering
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    • v.3 no.2
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    • pp.88-99
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    • 1978
  • In this study, rice harvesting systems suitable to Korean situations and the optimum timing of these systems were determined, respectively, based on experimentally determined factors such as filed yield and the milling quantity and quality measured at various levels of the grain moisture content at harvest. Rice varieties used for the experiment were the AKIBARE (Japonica-type) and the SUWEON 251 (high yielding TONGIL sister-line variety), The harvesting systems studied by the experimental work of this study were traditional system with both the wet material and dry-material threshing system by use of binder with both the dry-material and wet-material threshings, and system by use of combine. Grain samples were taken from final products of the paddy rice harvested from the experiment a fields for each system to measure the recovery rates of the milled rice. The results may be summarized as follows; 1. The milling recovery rate of the AKIBARE variety had highest value within the range of the grain moisture at harvest, showing from 21 to 26 percent. The head-rice recovery for the same variety was a little greater in the wet-material threshing than in the dry-material threshing , higher values of which , were 20 to 25 percent , seen within the range of grain moisture at harvest regardless of the harvesting systems tested. 2. The milling recovery of the SUWEON 251 , when tested for different harvesting systems and harvesting grain moisture, did not show a statistically significant different. In contrast , head-rice recovery for the systems operated by the wet-material threshing was much greater than that by the -material threshing. The difference of the recoveries between these systems range from 2.6 to 4.7 percent. 3. An assessment of the optimum period of -harvest timing for each of the harve\ulcornersting systems tested were made bJ.sed on (a) the maximum total milled-rise yield and (b) the percentage reduction in the total milled-rice yield due to untimely harvest operations. The optimum period determined are: 23-19% for the ATD, AC, STD, SBW, STW systems, 25-21% for the ATW ani ABW systems, and 27-18% for the ABD, SBD, and SC systems, respectively.

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STUDY ON THE PROPERTIES OF GYPSUM-BONDED DENTAL INVESTMENTS (치과용 석고계 매몰재의 특성에 관한 연구)

  • Kim, Kyoung-Sun;Woo, Yi-Hyung;Choi, Boo-Byung
    • The Journal of Korean Academy of Prosthodontics
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    • v.28 no.1
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    • pp.137-163
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    • 1990
  • The properties of a investment material can be described by the consistency at the slurry state, the setting time, the compressive strength and the thermal expansion during the casting. In this study the effect of the production parameters which are included the ratio of quartz and cristobalite, the content of binder, the water powder ratio and the content and concentration of additives on the Properties of the gypsum-bonded investments has been investigated with help of the consistency test, the vicat needle test, the compressive strength test, the thermal expansion test, x-ray diffraction and DTA thermal differential test. The experimental results showed that the constitution of a investment with W/P ratio of 0.34, 30% of gypsum, 0.8% aluminium sulfate, 2% magnesium sulfate, 0.6% sodium phosphate was adapted for the properties of the KDA Spec. No. 13 type I investment. The important experimental results are summarized as follows. 1. The consistency of the investment decreased with increasing amount of aluminium sulfate and decreasing amount of sodium phosphate. An addition of magnesium sulfate up to 2% an increase of the consistency was shown. But 3% magnesium sulfate in investment showed a decrease of the consistency. The consistency did not vary significantly with a variation of the content of gypsum and cristobalite and the W/P ratio. 2. Aluminium sulfate and the magnesium sulfate promoted the hardening and the aluminium phosphate delayed the hardening. The setting time increased with amount of gypsum. The effect of the matrix on the setting time was insignificant. With the W/P ratio of 0.34 the setting time was 14 min. 3. The compressive strength decreased with the amount of aluminium sulfate up to 0.25% and increased with the amount of aluminium sulfate greater than 3%. The compressive strength decreased as decreasing the amount of magnesium sulfate and gypsum and as increasing the W/P ratio. The effect of the refractory on the compressive strength was also not significant. With the W/P ratio of 0.34 the compressive strength was $34Kg/mm^2$. 4. The 1st thermal expansion was found at the temperature near and the steady state or the contraction stage was found at the temperature between $250^{\circ}C$ and $500^{\circ}C$. After this stage the 2nd thermal expansion took place at the temperature near $500^{\circ}C$. The amount of thermal expansion increased with decreasing the content of magnesium sulfate, aluminium sulfate and gypsum and the W/P ratio. And the amount of thermal expansion increased as the content of sodium phosphate and cristobalite. With the W/P ratio of 0.34 the amount of total expansion was 1.2%.

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