• Journal of the Korean Wood Science and Technology
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• 제51권5호
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• pp.381-391
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• 2023

Densification is a technique used to improve biomass quality in wood pellet manufacturing and torrefaction treatment. In this study, the effects of torrefaction on the quality of Calliandra wood pellets were investigated, and pellets of Calliandra wood (Calliandra calothyrsus) and bark were evaluated. The study was conducted using a completely randomized design with two treatment factors, namely torrefaction temperature (250℃ and 300℃) and torrefaction duration (30, 45, and 60 min). The results showed that the interaction between temperature and torrefaction duration significantly affected the compressive strength, proximate value, and calorific value of the torrefied Calliandra wood pellets. An increase in the temperature and torrefaction duration decreased the compressive strength, moisture content, volatile matter content, and ash content of the torrefied Calliandra wood pellets. Conversely, the calorific value of Calliandra wood pellets increased with increasing temperature and torrefaction duration. The best-quality Calliandra wood pellets were produced at a torrefaction temperature and duration of 300℃ and 60 min, respectively. In terms of important quality parameters, ash content of 0.90% and calorific value of 6,303.80 cal/g were observed, which complied with the quality standards of Indonesian National Standard 8675:2018 and Deutsche Industrie Norm 51731.

• 한국지하수토양환경학회지:지하수토양환경
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• 제19권5호
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• pp.45-52
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• 2014

Torrefaction and hydrothermal carbonization (HTC) are productive methods to reclaim energy from lignocellulosic biomass. The hydrophobic, homogenized, energy dense and carbon rich solid fuel can be obtain from torrefaction and hydrothermal carbonization. Dead leaves were carbonized in a stainless steel reactor of volume 200 ml with torrefaction ($250-270^{\circ}C$) for 120 minutes and hydrothermal carbonization ($200-250^{\circ}C$) for 30 minutes, with mass yield solid fuel ranging from 57-70% and energy content from 16.81MJ/kg to 22.01 MJ/kg compare to the biomass. The char produced from torrefaction process possess high energy content than hydrothermal carbonization. The highest energy yield of 89.96% was obtained by torrefaction at $250^{\circ}C$. The energy densification ratio fluctuated in between 1.15 to 1.30. On the basis of pore size distribution of the chars, the definition of the International Union of Pure and Applied Chemistry (IUPAC) was used as a classification standard. The pore diameter was ranging within 11.09-19 nm which play important role in water holding capacity in soil. Larger pores can hold water and provide passage for small pores. Therefore, it can be concluded that high pore size char can be obtained my HTC process and high energy content char of 22.01 MJ/Kg with 34.04% increase in energy can be obtain by torrefaction process.

• Journal of Biosystems Engineering
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• 제38권3호
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• pp.180-184
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• 2013

Purpose: This study explored the factors influencing heating value in the process of torrefaction of water hyacinth. Methods: Torrefaction was applied with three temperature settings (200, 300, $400^{\circ}C$) and three time settings (1, 2, 3 h) using small electric heaters (11.3L of holding volume). This study investigated the heating values with the washing process and process factors influenced the torrefaction. In addition, this study compared the heating values in washed and unwashed samples and suggested the optimal conditions for increasing heating value. Results: Torrefaction increased the heating value by 8.18 ~ 30.04%. Comparing heating values of each condition, the optimal temperature for torrefaction was $300^{\circ}C$ and holding time was 1 hour. The washing process increased the heating value by 19 ~ 27%. The heating value of the sample treated at $300^{\circ}C$ for three hours was 4310.80 kcal/kg, which was greater than the first class wood pellet of 4300 kcal/kg. Conclusions: This study proved that the torrefaction and washing process increased the heating value of water hyacinth. Therefore, water hyacinth is expected to be an eco-friendly biomass which substitutes for wood pellet.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2012년도 제45회 KOSCO SYMPOSIUM 초록집
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• pp.205-206
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• 2012

A novel torrefaction process is suggested to improve energy efficiency and to produce high quality biomass fuel. Major developments for novel torrefaction process are as follows. To maximize the energy efficiency in heat transfer, flue gas is directly used for heat source in the torrefier. To accomplish the oxygen free environment in the torrefaction reactor, a burner is developed and it can be runned with fuel rich state. To use the calorific gases produced from torrefier, another burner is developed to combust them. In the test, the novel torrefaction process leads low energy consumption and the quality of torrefied fuel becomes better.

• Korean Chemical Engineering Research
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• 제52권5호
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• pp.672-677
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• 2014

반탄화는 $200{\sim}300^{\circ}C$의 불활성분위기에서 바이오매스를 전처리하는 열처리공정이며 이러한 반탄화 공정은 바이오 매스에 함유된 섬유질성분의 분해온도에 크게 영향을 받은 것으로 알려져 있다. 본 연구에서는 사탕수수 부산물의 반탄화 특성에 관한 연구를 수행하였으며 반탄화 온도 및 반탄화 시간에 따른 에너지 수율, 발열량 및 발생가스 그리고 가연분과 회분의 관계에 중점을 두었다. 또한 본 연구에서는 TGA(Thermogravimetric Analyzer)를 이용한 사탕수수 부산물의 반탄화 반응에 대한 활성화 에너지의 변화도 함께 고찰하였다. 본 연구로부터 반탄화 온도에 따라 회분 및 발열량은 증가하였으나 가연분 및 에너지 수율은 감소하였으며 또한 산소성분을 함유한 일산화탄소가 탄화수소 화합물, $C_xH_y$ 보다 더 낮은 온도에서 분해되기 시작하는 것을 확인할 수 있었다.

• Korean Chemical Engineering Research
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• 제56권4호
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• pp.547-554
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• 2018

Torrefaction is the promising process of pretreating biomass materials to increase the quality of their energy, especially to upgrade the materials' grindability so that it is suitable for a commercial pulverizer machine. In this study, torrefaction of oak, bamboo, oil palm trunk, and rice husk was carried out under different torrefaction temperatures ($300^{\circ}C$, $330^{\circ}C$, and $350^{\circ}C$) and different torrefaction residence times (30, 45, and 60 minutes). Complete characterization of the torrefied biomass, including proximate analysis, calorific value, thermogravimetric analysis, mass yield, energy yield, and grindability properties (Hardgrove Grindability Index) was carried out. Increasing the torrefaction temperature and residence time significantly improved the calorific value, energy density (by reducing the product mass), and grindability of the product. Furthermore, for commercial purposes, the torrefaction conditions that produced the desired grindability properties of the torrefied product were $330^{\circ}C-30minutes$ and $300^{\circ}-45minutes$, and the latter condition produced a higher energy yield for bamboo, oil palm trunk, and rice husk; however, torrefaction of oak did not achieve the targeted grindability property values.

• Korean Chemical Engineering Research
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• 제51권4호
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• pp.465-469
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• 2013

본 연구는 반탄화된 OPF(oil palm fronds)의 연료로써 이용가능성을 알아보았다. OPF는 200, 250, 300, $350^{\circ}C$에서 각각 1시간과 2시간 동안 반탄화를 진행하였다. 반탄화된 OPF는 온도가 높아짐에 따라 그리고 반탄화 시간이 증가됨에 따라 발열량이 증가하였다. 또한, 반탄화 시간보다는 반탄화 온도가 더 중요한 요소였다. 하지만 반탄화 온도가 높아질수록 반탄의 수득률이 감소함으로 적절한 반탄화 온도가 요구되었다. $250^{\circ}C$에서의 반탄화로는 헤미셀룰로오스의 분해가 상당히 진행되고 $300^{\circ}C$에서는 셀룰로오스의 분해까지도 거의 진행됨을 OPF의 열분해 거동으로부터 알 수 있었다. 또한, 반탄화된 OPF는 바이오매스의 grindability를 향상시킴으로 분쇄에 소모되는 에너지를 감소시킴을 예측할 수 있었다.

• Korean Chemical Engineering Research
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• 제57권3호
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• pp.372-377
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• 2019

Leaching ($60^{\circ}C$, 5 min) and wet torrefaction ($200^{\circ}C$, 5 min) of empty fruit bunch (EFB) were carried out to improve the fuel properties; each liquid fraction was reused for leaching and wet torrefaction, respectively. In the leaching process, potassium was effectively removed because the leaching solution contained 707.5 ppm potassium. Inorganic compounds were accumulated in the leaching solution by increasing the reuse cycle of leaching solution. The major component of the leached biomass did not differ significantly from the raw material (p-value < 0.05). Inorganic compounds in the biomass were more effectively removed by sequential leaching and wet torrefaction (61.1%) than by only the leaching process (50.1%) at the beginning of the liquid fraction reuse. In the sequential leaching and wet torrefaction, the main hydrolysate component was xylose (2.36~4.17 g/L). This implied that hemicellulose was degraded during wet torrefaction. As in the leaching process, potassium was effectively removed and the concentration was accumulated by increasing the reuse cycle of wet torrefaction hydrolysates. There was no significant change in the chemical composition of wet torrefied biomass, which implied that fuel properties of biomass were constantly maintained by the reuse (four times) of the liquid fraction generated from leaching and wet torrefaction.

• Advances in Energy Research
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• 제1권2호
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• pp.127-146
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• 2013

Torrefaction technologies convert assorted biomass feedstocks into energy-concentrated, carbon neutral fuel that is economically transported and easily ground for blending with fossil coals at numerous power plants around the world without needs to retrofit. Utilization of torrefied biomass in conventional electric generating units may be an increasingly attractive alternative for electricity generation as aging power plants in the world need to be upgraded or improved. This paper examines the economic feasibility of torrefaction in different scenarios by modeling torrefaction plants producing 136,078 t/year (150,000 ton/year) biocoal from wood and corn stover. The utilization of biocoal blends in existing coal-fired power plants is modeled to determine the demand for this fuel in the context of emerging policies regulating emissions from coal in the U.S. setting. Opportunities to co-locate torrefaction facilities adjacent to corn ethanol plants and coal-fired power plants are explored as means to improve economics for collaborating businesses. Life cycle analysis was conducted in parallel to this economic study and was used to determine environmental impacts of converting biomass to biocoal for blending in coal-fired power plants as well as the use of substantial flows of off-gasses produced in the torrefaction process. Sensitivity analysis of the financial rates of return of the different businesses has been performed to measure impacts of different factors, whether input prices, output prices, or policy measures that render costs or rewards for the businesses.

• 농업생명과학연구
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• 제52권6호
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• pp.73-79
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• 2018

본 연구에서는 고수분 음식물 및 농업 폐기물을 재활용한 고형연료 제조에 필요한 열분해장치를 개발하고 실험을 통해 그 성능을 확인하고자 하였다. 연구를 위해 건조용량 50kg/hr인 실험실용 열분해장치를 제작하였다. 건조 처리된 농업폐기물과 음식물 폐기물을 열분해처리용 실험 원료로 사용하였다. 원료종류, 열분해 온도, 열분해 시간에 따른 농업폐기물과 음식물 폐기물의 열분해 특성을 파악하였다. 농업폐기물 건조물의 열분해 처리 결과, 열분해 처리능력은 평균 55.35kg/hr, 저위발열량은 평균 3,333kcal/kg으로 측정되었다. 열분해처리 하지 않은 농업폐기물의 고위발열량은 3,400kcal/kg, 저위발열량은 3,090kcal/kg으로 측정되어 열분해처리로 발열량이 향상됨을 알 수 있었다. 음식물 폐기물 건조물의 열분해 처리 결과, 열분해 처리능력은 평균 88.27kg/hr, 저위발열량은 평균 4,016kcal/kg으로 측정되었다. 열분해처리 하지 않은 음식물 폐기물의 고위발열량은 4,040kcal/kg, 저위발열량은 3,686kcal/kg으로 측정되어 열분해처리로 발열량이 역시 향상됨을 알 수 있다. 열분해 처리능력은 연구목표치인 50kg/hr보다 높게 나타났으며, 저위발열량은 연구목표치인 4,000kcal/kg 보다 다소 높게 나타났다. 다만 저위발열량 측정 기준 함수율이 습량기준으로 약 10%로 추정되는 바 5%로 조절하고, 열분해 열풍온도를 상승시키면 발열량이 더욱 향상될 것으로 판단되었다.