• Corrosion Science and Technology
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• 제19권3호
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• pp.156-162
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• 2020

The objective of this study was to investigate delayed oxygen evolution and localized corrosion resistance of titanium alloys by performing potentiodynamic polarization, potentiostatic polarization, and Mott-Schottky measurements. Delayed oxygen evolution was compared among titanium alloys, 316 stainless steel, and platinum. Difference in delayed oxygen evolution between titanium alloys and other metals was attributed to specific surface characteristic of each metal. Delayed oxygen evolution of titanium alloys resulted from the predominant process of ionic conduction over electronic conduction. The effect of oxygen evolution on localized corrosion of titanium alloys was investigated using electrochemical critical localized corrosion temperature (E-CLCT) technique. Mott-Schottky measurement was performed to clarify the difference in film properties between titanium alloys and stainless steels. Titanium alloys were found to have much lower donor density than stainless steels by 1/28. These results indicate that delayed oxygen evolution has little influence on the concreteness of passive film and the resistance to localized corrosion of titanium alloys.

• 대한치과기공학회지
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• 제38권2호
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• pp.79-84
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• 2016

Purpose: The aim of this study was to make nanomesh on the surface of titanium by potentiostatic technique which was done at the suitable potential level. Methods: In order to find the suitable potential level, use a $25^{\circ}C$ NaCl, NaOH and NH4F solution of 1 M and 5 M as supporting electrolyte, working electrode(positive potential) was contact to the titanium specimen and counter electrode(negative potential) was contact to the Pt substrate. At the transpassive potential which was observed by potentiostatic technique, potentiostatic technique was done for 2hours. Results: As a result, 1 M NaOH solution was suitable as a supporting electrolyte, potentiostatic technique used a $25^{\circ}C$ NaOH solution of 1 M for 2hours, nanomesh was formed. Conclusion: The potentiostatic technique was used $25^{\circ}C$ NaOH solution of 1 M and 5 M as supporting electrolyte for 2hours. Nanomesh was built more uniform and fine in 1 M NaOH solution than 5 M NaOH solution.