• Management & Information Systems Review
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• v.36 no.5
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• pp.61-83
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• 2017

The purpose of this study is to investigate the mediating effects of psychological empowerment between participative leadership and creative behavior. Especially, it aims to analyze the unidimension and multidimension of psychological empowerment in an integrated manner, and to suggest effective practice of participative leadership together with theoretical and methodological implications. In this study, the dependent variable was measured separately with time lag as a method to solve the common method bias that can be shown by the self-report type survey method, and positive emotions and negative emotions expressing emotional states in job situations were employed as control variables along with rank. A total of 283 questionnaires were collected from employees who work for companies in various industries with more than 300 domestic employees. SPSS PROCESS macro program('model 4') was used for statistical analysis. Results, First, the full mediation effect of psychological empowerment(unidimension) was confirmed in the relationship between participative leadership and creative behavior. Second, the analysis of the multidimension of psychological empowerment revealed the full mediating effect of meaning, self-determination, and impact, and the mediating effect of competence was not significant. Third, as a result of comparing the mediating effects of unidimension of psychological empowerment and the mediating effects of multidimension, the magnitude of mediating effect of unidimension was found to be much greater than mediating effect of multidimension. And The magnitudes of the three multidimensional mediating effects were similar. This is a case in which the motivational model of participative leadership revealed in the overseas study is proven in the domestic management environment and is significant in that it is the basis of future research. Based on the results of the empirical studies, the implications and limitations of the study and future research directions are presented.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.4 no.3
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• pp.43-52
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• 1984

This paper is concerned with the strain characteristics of the time effect on the remoulded saturated day sampled from the downstream of the Yeongsan river, and the constitutive equation that can generally explain time-dependent behaviors of norma1ly consolidated clay. This paper examines whether or not the afore-said constitutive equation can be applied to the remoulded Mooan-clay. Throughout this study, the conclusions obtained are as follows. 1. Throughout the isotropic consolidation test for 7 days and the isotropic relaxation test, the existence of the static and dynamic yielding surfaces is confirmed respectively. 2. The characteristics of time effect of the deformation, namely, the existence of a unique stress-strain-time relation, is conformed from the experimental result on the Mooan-clay. 3. The prodictions of the stress path and the strain on the Cam-clay theory is not consistent with those observed during the experiments. 4. Constitutive equation(2-3-12) obtained by applying Cam-clay theory to Perzyna's elastic-viscoplasticity theory can explain the behavior of pore water pressure during isotropic stress relaxation, concerned with time dependency under undrained condition. The equation can also explain the results of the undrained triaxial compression test for the clay with different strain rate under the same or different consolidation history. 5. This constitutive equation has eight material parameters which can be determined from triaxial compression tests.

• The Journal of Engineering Geology
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• v.22 no.3
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• pp.343-351
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• 2012

This study proposes a modified equation to calculate the factor of safety for an infinite slope considering the saturation depth ratio as a new variable calculated from rainfall infiltration into unsaturated soil. For the proposed equation, this study introduces the concepts of the saturation depth ratio and subsurface flow depth. Analysis of the factor of safety for an infinite slope is conducted by the sequential calculation of the effective upslope contributing area, subsurface flow depth, and the saturation depth ratio based on quasi-dynamic wetness index theory. The calculation process makes it possible to understand changes in the factor of safety and the infiltration behavior of individual rainfall events. This study analyzes stability changes in an infinite slope, considering the saturation depth ratio of soil, based on the proposed equation and the results of soil column tests performed by Park et al. (2011 a). The analysis results show that changes in the factor of safety are dependent on the saturation depth ratio, which reflects the rainfall infiltration into unsaturated weathered gneiss soil. Under continuous rainfall with intensities of 20 and 50 mm/h, the time taken for the factor of safety to decrease to less than 1.3 was 2.86-5.38 hours and 1.34-2.92 hours, respectively; in the case of repeated rainfall events, the time taken was between 3.27 and 5.61 hours. The results demonstrate that it is possible to understand changes in the factor of safety for an infinite slope dependent on the saturation depth ratio.

• Journal of the Korea Concrete Institute
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• v.24 no.6
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• pp.727-735
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• 2012

Recently, a high-strength strand of 2400 MPa was developed using domestic technologies. In 2011, KS D 7002 was revised to cover the newly developed high-strength strands to support their practical usage. Presently, however, discussions and evaluations are not sufficient on the mechanical properties of the strands and their performance in structural members. Also, there were no detailed reviews on the need to revise the current design code for practical use of the high-strength strands. In this study, flexural behavior of a member with the high-strength strands was estimated through sectional analysis and a review and comparison of the domestic and foreign design codes were conducted considering the analysis results. Also, the need for the revision of the design code was discussed. Such discussion especially focused on the estimation of the stress in strand, which related with various issues such as determination methods for yield point of strands, time-dependent loss of prestressing force, estimation of stress in strand at member failure, and net strain limit for ductile failure of member. The discussion revealed that some parts in the design code need a revision and the further studies are required.

• Journal of the Korean Chemical Society
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• v.55 no.3
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• pp.385-391
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• 2011

The time-dependent density functional theory (TDDFT) method has been carried out to investigate the excitedstate hydrogen-bonding dynamics of phenol-$(H_2O)_2$ complex. The geometric structures and infrared (IR) spectra in ground state and different electronically excited states ($S_1$ and $T_1$) of the hydrogen-bonded complex have been calculated using the density functional theory (DFT) and TDDFT method. A ring of three hydrogen bonds is formed between phenol and two water molecules. We have demonstrated that the intermolecular hydrogen bond $O_1-H_2{\cdots}O_3-H$ of the three hydrogen bonds is strengthened in $S_1$ and $T_1$ states. In contrast, the hydrogen bond $O_5-H_6{\cdots}O_1-H$ is weakened in $S_1$ and $T_1$ states. These results are obtained by theoretically monitoring the changes of the bond lengths of the hydrogen bonds and hydrogen-bonding groups in different electronic states. The hydrogen bond $O_1-H_2{\cdots}O_3-H$ strengthening in both the $S_1$ and $T_1$ states is confirmed by the calculated stretching vibrational mode of O-H (phenol) being red-shifted upon photoexcitation. The hydrogen bond strengthening and weakening behavior in electronically excited states may exist in other ring structures of phenol-$(H_2O)_n$.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.9 no.2
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• pp.231-239
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• 1999

The microstructure of ceramic composite has been found to be governed by the type and amount of the secondary phase, the sintering aid, and the sintering conditions such as sintering temperature, pressure and holing time. Moreover, tribological properties are strongly dependent on microsturcture of composite and operating conditions. In this study, silicon nitride with various amount of magnesia as a sintering aid were prepared and sintered by a hot pressing (HP) technique. Microstructure, mechanical properties (hardness, strength, and fracture toughness), and tribological properties in different environments of $Si_{3}N_{4}$ (in air, water, and paraffine oil) were investigated as a function of MgO content in $Si_{3}N_{4}$. As increasing the amount of MgO in $Si_{3}N_{4}$, the glassy phase in the grain boundaries enlarged the $\beta$-phase elongated grains, and also degraded the Hertzian contact damage resistance. Tribological behaviors in air was seemed to be determined by fracture toughness of $Si_{3}N_{4}$, and those in water and paraffin oil was seemed to be determined by hardness as well as strength. Since glassy grain-boundary phase (MgO) in $Si_{3}N_{4}$ expected to be reacted with water during sliding, such tribochemical reaction reduced wear. In paraffin oil under a higher applied load, the initial sliding dominated wear rate because of Hertzian contact damage.

• Journal of the Korea Concrete Institute
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• v.23 no.5
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• pp.581-590
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• 2011

Since ultra-high performance cementitious composites (UHPCC) not only represents high early age shrinkage strain due to its low water-to-binder ratio (W/B) and high fineness admixture usage but also reduces the cross section of structure from the higher mechanical properties, it generally has more shrinkage cracks from the restraints of formwork and reinforcing bars. In this study, free and restrained shrinkage experiments were conducted to evaluate the suitability of incorporating both expansive admixture (EA) and shrinkage reducing agent (SRA). The test results indi-cated that approximately 40~44% of free shrinkage strain was decreased. Also, the results showed that 35% and 47% of residual tensile stresses were relieved by synergetic effect of SRA and EA, respectively. Residual tensile stresses from ringtest were relaxed by approximately 61% and 64% of elastic shrinkage stresses due to SRA and EA, respectively, because of the tensile creep effect. Therefore, the creep effect should be considered to precisely estimate the restrained shrinkage behavior of concrete structures. The degree of restraint of UHPCC was approximately in the range of 0.78~0.85. The addition of combined EA and SRA showed minute influence on the degree of restraint. However, the effect decreased when thicker concrete ring was used. Tensile creep strains were measured and compared to the predicted values from 4-parametric prediction model considering time dependent restrained forces.

• Geomechanics and Engineering
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• v.13 no.2
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• pp.333-352
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• 2017

A comparison study is made between the dynamic properties of an argillaceous siltstone and its grouting-reinforced body. The purpose is to investigate how grout injection can help repair broken soft rocks. A slightly weathered argillaceous siltstone is selected, and part of the siltstone is mechanically crushed and cemented with Portland cement to simulate the grouting-reinforced body. Core specimens with the size of $50mm{\times}38mm$ are prepared from the original rock and the grouting-reinforced body. Impact tests on these samples are then carried out using a Split Hopkinson Pressure Bar (SHPB) apparatus. Failure patterns are analyzed and geotechnical parameters of the specimens are estimated. Based on the experimental results, for the grouting-reinforced body, its shock resistance is poorer than that of the original rock, and most cracks happen in the cementation boundaries between the cement mortar and the original rock particles. It was observed that the grouting-reinforced body ends up with more fragmented residues, most of them have larger fractal dimensions, and its dynamic strength is generally lower. The mass ratio of broken rocks to cement has a significant effect on its dynamic properties and there is an optimal ratio that the maximum dynamic peak strength can be achieved. The dynamic strain-softening behavior of the grouting-reinforced body is more significant compared with that of the original rock. Both the time dependent damage model and the modified overstress damage model are equally applicable to the original rock, but the former performs much better compared with the latter for the grouting-reinforced body. In addition, it was also shown that water content and impact velocity both have significant effect on dynamic properties of the original rock and its grouting-reinforced body. Higher water content leads to more small broken rock pieces, larger fractal dimensions, lower dynamic peak strength and smaller elastic modulus. However, the water content plays a minor role in fractal dimensions when the impact velocity is beyond a certain value. Higher impact loading rate leads to higher degree of fragmentation and larger fractal dimensions both in argillaceous siltstone and its grouting-reinforced body. These results provide a sound basis for the quantitative evaluation on how cement grouting can contribute to the repair of broken soft rocks.

• Polymer(Korea)
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• v.30 no.3
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• pp.271-278
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• 2006

In order to investigate the structure and dynamics of atatic poly (vinyl alcohol) (PVA)/water system, laser light scattering experiment has been done in the semi-dilute concentration regime at $25^{\circ}C$. The scattering intensity I(q) can be analyzed with the fractal equation of $I(q){\sim}q^{-m}$ instead of Onstein-Zernike type equation. The fractal dimensionality m was found to be constant after reaching the plateau value of $m=2.6{\pm}0.3$ above C=3wt%. The time correlation function of dynamic light scattering has always two different modes such as fast mode and slow one. The cooperative diffusion of fast mode showed concentration independence contrary 4o the reptation theory's concentration dependent exponent of 3/4. The slow mode can be interpreted as the motion of large scale heterogeneities and its strong concentration dependence is apparent with a large negative exponent of -3.0. It is considered that the stereo-regular arrangement with four successive meso units of -OH plays as a key role in forming such heterogeneity.

• Journal of Korean Society on Water Environment
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• v.32 no.3
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• pp.271-280
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• 2016

The aim of this study was to analyze spatial and temporal patterns of bacterial pollution levels and the relationship between bacterial pollutants and environmental parameters at the main stream and tributaries of Nakdong River. Water quality data including total coliform and fecal coliform were compiled from a total of 50 monitoring sites (30 at the main stream and 20 at the tributaries) along with rainfall and discharge data for three consecutive years from 2012 to 2014. During the study periods, the geometric mean values of total coliforms and fecal coliforms in the main stream were 74 (22~465) CFU/100 mL and 8 (3~42) CFU/100 mL, respectively. The geometric mean values of total coliforms and fecal coliforms in the tributaries were 275 (36~5,145) CFU/100 mL and 6 (1~1,352) CFU/100 mL, respectively. High concentrations of fecal coliforms were observed at Gumi (M 10), Hyeonpung (M 19), Hapcheon (M 23), and Namji (M 25) in the main stream, whereas Gamcheon (T 6), Bakcheon (T 7), Geumho-gang (T 8), and Gyeseongcheon (T 16) were identified as pollution hot spots in the tributaries. Although bacterial pollution levels showed complex behavior across monitoring sites and time, the highest coliform concentrations were routinely observed in the monsoon season between July and September of each year, indicating that the pollution levels were strongly dependent on precipitation in addition to other physiochemical parameters. Statistically significant correlations were found between fecal coliform concentrations and precipitation (r=0.403, p<0.01), followed by SS (r=0.425, p<0.01), nutrient TP (r=0.388, p<0.01), organic matter COD (r=0.322, p<0.01), and PO₄-P (r=0.317, p<0.01) in the main stream in the order of correlation coefficient from high to low.