• Title/Summary/Keyword: thiourea

Search Result 243, Processing Time 0.025 seconds

Effect of Ureaform, SCU and Melamine on Barley Growth and their Nitrogen Supplying Ability (Ureaform, SCU, Melamine의 질소공급력(窒素供給力)과 보리 생육(生育)에 대(對)한 효과(效果))

  • Lim, Sun-Uk;Oh, Nam-Soon
    • Korean Journal of Soil Science and Fertilizer
    • /
    • v.17 no.3
    • /
    • pp.265-273
    • /
    • 1984
  • To investigate nitrogen supplying effect of some slowrelease N-fertilizers on barley in upland soil sulfurcoated urea(SCU), ureaform and melamine (1,3,5-Triazine-2,4,6-triamine) were treated and compared to urea. In addition, thiourea as a nitrification inhibitor was also tested. Effects of variable soil condition such as moisture content, pH and temperature on nitrogen supplying ability of the fertilizers and on growth of barley were studied through incubation test and pot culture and the obtained results were summarized as follows: The releasing rate of ammonia from urea, SCU, ureaform and melamine were resulted as 27-59%, 25-39%, 9-34% and 0.7-4.3% at maximum conversion rate, respectively. Nitrification rate of the tested fertilizers was higher at pH 6.54 markedly than at pH 4.73. Addition of thourea depressed the formation of $NO_3$ during four weeks of incubation period. Mixed application of ureaform with small amount of urea contributed to nitrogen supply till latter growth stage of barely Basal application of melamine showed lowest nitrogen supplying ability and injurious response on barley growth.

  • PDF

Use of Phosphate Coated Urea to Decrease Ammonia Volatilization Loss from Direct Seeded Rice Field at Early Stage (건답(乾畓) 직파(直播) 논에서 초기(初期)의 암모니아 휘산(揮散) 경감(輕減)을 위한 인산(燐酸) 입힌 요소(尿素)의 효과(效果))

  • Jung, Yeong-Sang;Ha, Sang-Keun;Cho, Byung-Ok;Lee, Ho-Jin
    • Korean Journal of Soil Science and Fertilizer
    • /
    • v.29 no.1
    • /
    • pp.8-14
    • /
    • 1996
  • Use of phosphate coated urea to decrease ammonia volatilization from directly seeded paddy under dryland condition at early stage was tested. Effect on urea hydrolysis was investigated through laboratory study comparing with use of thiourea, a urease inhibitor, under different water content. A field measurement of volitilized ammonia with phosphate-glycerol ammonia absorber was conducted for surface treated urea, phosphate coated urea, phosphate coated slow-release fertilizer and organic fertilizer. Through laboratory study, hydrolysis rate of phosphate coated urea at three days after treatment was lower than that of urea, however, the rate after one week was same. Thiourea addition retarted urea hydrolysis. By field measurement, ammonia volatilization was effectively reduced by use of phosphate coated urea.

  • PDF

Synthesis of Alkylphosphate-Thiourea Condensation Product and Its Application as Flame Retardant (알키포스페이트-티오우레아 축합물의 합성과 난연제로서의 응용)

  • Park, Hong-Soo;Kim, Young-Geun;Bae, Jang-Soon
    • Journal of the Korean Applied Science and Technology
    • /
    • v.7 no.1
    • /
    • pp.31-36
    • /
    • 1990
  • Synthesizing octylphosphate(OTP) from phosphorus pentoxide with n-octyl alcohol, octylphosphatethiourea(OTPU) was prepared from OTP with thiourea. After flame retardant finishing OTPU to acrylic fabrics, nylon taffeta and tetron taffeta, the physical properties, such as tear strength and flame retardancy were measured. As the results of the measurement, OTPU was found to be a good flame retardant having softness using to synthetic fibers.

백상폐지의 과산화수소 표백에 미치는 활성제의 영향

  • 안병준;백기현
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
    • /
    • 2001.04a
    • /
    • pp.63-70
    • /
    • 2001
  • Sodium persulfate, prestogen W, prestogen EB, citric acid 및 thiourea의 첨가에 따른 $H_2O_2$ 표백 효과가 연구되었다. Sodium persulfate(1%), Prestogen EB(15.0%)를 $H_2O_2$ 활성제로 첨가하여 표백할 경우 기존 $H_2O_2$ 표백(86.0% ISO)보다 표백 펄프의 백색도가 2-3% ISO 더 증가하였다. $H_2O_2$ 표백 후 thiourea를 첨가하여 표백하는 산화-환원 연속표백(87.9% ISO)에서도 $H_2O_2$ 표백 후 FAS로 2단 표백(88.3% ISO)을 한 경우와 비슷한 백색도를 나타내었다. 한편 표백 펄프의 인장지수, 파열지수 그리고 인열지수는 기존 표백 또는 Prestogen EB를 첨가할 경우 높고 sodium persulfate 첨가에서 가장 낮았다. 산화-환원 연속 표백된 펄프의 강도도 기존 $H_2O_2$ 표백보다 미세하게 낮았다.

  • PDF

A Study on the Sericin Fixation of Raw Silk Fibers by Fixing with the Mixtures of Various Amines and Formalin (아민류와 포르말린 혼합액에 의한 실크 생사의 세리신 정착에 관한 연구)

  • Park, Geon-Yong
    • Textile Coloration and Finishing
    • /
    • v.21 no.1
    • /
    • pp.67-72
    • /
    • 2009
  • To investigate the strong and effective sericin fixing agents and conditions, raw silk fibers were treated with the mixtures of urea-formalin, thiourea-formalin and melamine-formalin as sericin fixing agents, respectively. And the treated raw silk fibers were degummed by the degumming liquors of alkaline detergent and sodium carbonate to confirm the hardness of sericin fixation. The weight of raw silk fibers was decreased in the process of sericin fixation treating at 80$^{\circ}C$ for 60min. The effective sericin fixation was obtained by treating at $60{\sim}80^{\circ}C$ for 15min with the mixture of melamine and formalin. The mixture of melamine and formalin showed an outstanding ability of sericin fixation because the three amino groups of melamine were able to cross-link the hydroxy amino acids of sericin such as serine with the assistance of formalin.

Acid and Base Catalyzed Intramolecular Cyclizations of N-Benzoylthiocarbamoyl-acetals

  • Lee, Bong-Yong;Kim, Choong-Sup;Lee, Jong-Wook
    • Archives of Pharmacal Research
    • /
    • v.23 no.2
    • /
    • pp.99-103
    • /
    • 2000
  • Acid and base catalyzed intramolecular cyclizations of N-benzoylthioureidoacetal, contain-ing four functional groups adjacent to thiourea such as benzocarbamoyl, acetal, thioure and amide, were investigated. The condensation reaction of N-benzoyl thiocarbamoylgly-cine amide in the presence of 10% aqueous NaOH provided 1-(2,2-dimethoxy)ethyl-imi- dazolidine-2-thione exclusively. In the presence of pyridine, it was transformed to 2- thiohydantoin. N-Benzoyl thiocarbamoyl glycine amide was completely transformed to an iminothiazolidine exclusively in the presence of Lewis acid such as borontrifluoride ether-ate or trimethylsilyl iodide. 1-(2,2-Dimethoxy)ethyl-imidazolidine-2-thione was transformed to imidazole[2,1-b]thiazole and pyrazino[5,1-a]imidazole in the presence of $BF_3$.$ET_2$O and formic acid, respectively.

  • PDF

Simple Method of Preparation and Characterization of New Antifungal Active Biginelli Type Heterocyclic Compounds

  • Pothiraj, C.;Velan, A. Senthilkumara;Joseph, J.;Raman, N.
    • Mycobiology
    • /
    • v.36 no.1
    • /
    • pp.66-69
    • /
    • 2008
  • A simple, efficient and cost effective method is described for the synthesis of Biginelli type heterocyclic compounds of dihydropyrimidinones analogous. They were prepared from a reaction mixture consisting of substituted benzaldehydes, thiourea and ethylacetoacetate using ammonium dihydrogenphosphate as catalyst. The procedure for the preparation of the compounds is environmentally benign and safe which is advantageous in terms of experimentation, catalyst reusability, yields of the products, shorter reaction times and preclusion of toxic solvents. The four new synthesised compounds were tested for their antifungal activity. They have good antifungal activity comparing to the standard (Fluconazole).