• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2001년도 추계학술대회 논문집 Vol.14 No.1
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• pp.304-307
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• 2001

High quality BSCCO thin films have been fabricated by means of an ion beam sputtering at various substrate temperatures, $T_{sub}$, and ozone gas pressures, $PO_3$. The correlation diagrams of the BSCCO phases appeared against $T_{sub}$ and $PO_3$ are established in the 2212 and 2223 compositional films. In spite of 2212 compositional sputtering, Bi220l and Bi2223 phases as well as Bi2212 one come out as stable phases depending on $T_{sub}$ and $PO_3$. From these results, the thermodynamic evaluations of ${\Delta}H$ and ${\Delta}S$ S, which are related with Gibbs' free energy change for single Bi2212 or Bi2223 phase are performed.

• 에너지공학
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• 제24권2호
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• pp.84-90
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• 2015

Hydrogen has some remarkably high values of the key properties for transport processes, such as kinematic viscosity, thermal conductivity and diffusion coefficient. Hydrogen, as an energy medium, has some distinct benefits for its high efficiency and convenience in storage, transportation and conversion. Hydrogen has much wider limits of flammability in air than methane, propane or gasoline and the minimum ignition energy is about an order of magnitude lower than for other combustibles. Statistical thermodynamics provides the relationships that we need in order to bridge this gap between the macro and the micro. Our most important application will involve the calculation of the thermodynamic properties of the ideal gas.

• 한국결정성장학회:학술대회논문집
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• 한국결정성장학회 1998년도 PROCEEDINGS OF THE 15TH KACG TECHNICAL MEETING-PACIFIC RIM 3 SATELLITE SYMPOSIUM SESSION 4, HOTEL HYUNDAI, KYONGJU, SEPTEMBER 20-23, 1998
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• pp.1-20
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• 1998

Processing of thin films by chemical vapor deposition (CVD) is accompanied by chemical reactions, in which the rigorous kinetic analysis is difficult to achieve. In these conditions, thermodynamic calculation leads to better understanding of the CVD process and helps to optimise the experimental parameters to obtain a desired product. A CVD phase diagram has been used as guide lines for the process. By determining the effect of each process variable on the driving force for deposition, the thermodynamic limit for the substrate temperature that diamond can deposit is calculated in the C-H system by assuming that the limit is defined by the CVD diamond phase diagram. The addition of iso-supersaturation ratio lines to the CVD phase diagram in the Si-Cl-H system provides additional information about the effects of CVD process variables.

• 대한화학회지
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• 제57권1호
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• pp.63-72
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• 2013

Some vanadyl complexes were synthesized by treating a methanolic solution of the appropriate Schiff base ligand and one equivalent of $VO(SO_4)_2$ to yield [($VOL_2^{1-14}$)](L=Salicylaldehyde's derivatives, Schemes 1, 2). These oxovanadium (IV) complexes were characterized based on their FT-IR, UV-Vis spectroscopy and elemental analysis. The IR spectra suggest that coordination takes place through azomethine nitrogen and phenolate oxygen. In addition, the formation constants of the oxovanadium (IV) binary complexes were determined in methanolic medium. The ab initio calculations were also carried out to determine the structural and the geometrical properties of one of the complexes and its calculated vibrational frequencies were investigated.

• 한국전자통신학회논문지
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• 제8권9호
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• pp.1365-1371
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• 2013

표면상에서의 흡착현상 중, 특정한 압력에서 흡착량이 불연속적으로 급격하게 증가하는 2상 공존현상을 이론적으로 설명하기 위하여 2차원 클러스트 응집모형을 도입하였다. 이 2차원 클러스트 응집모형에 기초적인 통계열역학과 미정계수법을 적용하여 흡착등온식을 유도하였으며, 유도된 흡착등온식은 표면흡착에서의 2상 공존현상이 흡착입자들 간의 강한 인력에 의한 것임을 정성적으로 잘 보여주었다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2001년도 추계학술대회 논문집
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• pp.304-307
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• 2001

High quality BSCCO thin films have been fabricated by means of an ion beam sputtering at various substrate temperatures, T$\sub$sub/, and ozone gas pressures, PO$_3$. The correlation diagrams of the BSCCO Phases appeared against T7ub and PO3 are established in the 2212 and 2223 compositional films. In spite of 2212 compositional sputtering, Bi2201 and Bi2223 phases as well as Bi2212 one come out as stable Phases depending on T$\sub$sub/ and PO$_3$. From these results, the thermodynamic evaluations of ΔH and ΔS, which are related with Gibbs' free energy change for single Bi2212 or Bi2223 phase are performed.

• 한국수소및신에너지학회논문집
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• 제29권2호
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• pp.148-154
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• 2018

This paper presents a comparative analysis of thermodynamic performance of ammonia-water Rankine cycles with and without regeneration and Kalina cycle for recovery of low-temperature heat source. Special attention is paid to the effect of system parameters such as ammonia mass fraction and turbine inlet pressure on the characteristics of the system. Results show that maximum net power can be obtained in the regenerative Rankine cycle for high turbine inlet pressures. However, Kalina cycle shows better net power and thermal efficiency for low turbine inlet pressures, and the optimum ammonia mass fractions of Kalina cycle are lower than Rankine cycles.

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2002년도 춘계학술대회논문집
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• pp.796-801
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• 2002

The goal of this research is the shape design of the valve using a computer simulation. For an analysis a basic mathematical model describing compression cycle is considered as consisting of five sets of coupled equations. These are the volume equation (kinematics), valve dynamic equation (dynamics), ideal gas equation (thermodynamics), Bernoulli equation (fluid dynamics), and dynamic equation of fluid particle based on Helmholtz equation (acoustics). Valve motion is made by the superposition of free vibration modes obtained by the finite element method. That is, the eigenvalues and eigenvectors are the sufficient modeling factors fur the valve in the simulation program. Thus, to design a shape of the valve, shape design sensitivity through chain-ruled derivatives is considered from two sensitivity coefficients, one is the design sensitivity of the capability of compressor with respect to the eigenvalues of the valve, and the other is the design sensitivity of the eigenvalue with respect to the shape change of the valve. In this research, the continuum design sensitivity analysis concepts are used for the latter.

• 한국추진공학회지
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• 제13권4호
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• pp.45-54
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• 2009

열효율과 비동력을 대폭 향상시킬 수 있는 잠재성을 가진 증기분사 재생 가스터빈 시스템에 대해 엑서지 해석을 수행하였다. 열역학 제2법칙을 근거로 한 해석 모델을 이용하여 압력비, 증기분사율, 주위 온도, 터빈입구온도 등 주요 설계변수들의 변화에 따라 엑서지 효율, 열교환기의 엑서지 회수율, 엑서지 파괴율 및 손실률 등 시스템의 성능과 최대 엑서지 효율에 미치는 영향을 조사하였다. 계산 결과 재생 증기분사 가스터빈 시스템은 시스템의 엑서지 효율을 대폭 증대시키고 비가역성을 감소시킨다는 사실을 확인하였다.

• International Journal of Automotive Technology
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• 제8권2호
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• pp.127-135
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• 2007

The objective of this study is to analyze the effect of velocity and vorticity on stratified mixture formation in the visualization engine. In order to investigate spray behavior, the pray velocity is obtained through the cross-correlation PIV method, a useful optical diagnostics technology and the vorticity calculated from the spray velocity component. These results elucidated the relationship between vorticity and entropy, which play an important role in the diffusion process for the early injection case and the stratification process for the late injection case. In addition, we quantified the homogeneous diffusion ate of spray using entropy analysis based on Boltzmann's statistical thermodynamics. Using these methods, we discovered that the homogeneous mixture distribution is more effective as a momentum dissipation of surrounding air than that of the spray concentration with a change in the injection timing. We found that the homogenous diffusion rate increased as the injection timing moved to the early intake stroke process, and BTDC $60^{\circ}$ was the most efficient injection timing for the stratified mixture formation during the compression stroke.