• Title/Summary/Keyword: thermodynamic modeling

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Adsorption Characteristics of Sr Ions by Coal Fly Ash-Based-Zeolite X using Response Surface Modeling Approach (반응표면분석법을 이용한 석탄회로 합성한 제올라이트 X에서의 Sr 이온 제거특성)

  • Lee, Chang-Han;Kam, Sang-Kyu;Lee, Min-Gyu
    • Journal of Environmental Science International
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    • v.26 no.6
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    • pp.719-728
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    • 2017
  • In order to investigate the adsorption characteristics for Sr ion using the Na-X zeolite synthesized from coal fly ash, batch tests and response surface analyses were carried out. The adsorption kinetic data for Sr ions, using Na-X zeolite, fitted well with the pseudo-second-order model. The uptake of Sr ions followed the Langmuir isotherm model, with a maximum adsorption capacity of 196.46 mg/g. Thermodynamic studies were conducted at different reaction temperatures, with the results indicating that Sr ion adsorption by Na-X zeolite was an endothermic (${\Delta}H^o$>0) and spontaneous (${\Delta}G^o$<0) process. Using the response surface methodology of the Box-Behnken method, initial Sr ion concentration ($X_1$), initial temperature ($X_2$), and initial pH ($X_3$) were selected as the independent variables, while the adsorption of Sr ions by Na-X zeolite was selected as the dependent variable. The experimental data fitted well with a second-order polynomial equation by multiple regression analysis. The value of the determination coefficient ($R^2=0.9937$) and the adjusted determination coefficient (adjusted $R^2=0.9823$) was close to 1, indicating high significance of the model. Statistical results showed the order of Sr removal based on experimental factors to be initial pH > initial concentration > temperature.

Effects of Underexpanded Plume in Transonic Region on Longitudinal Stability (천음속 영역에서 과소 팽창 화염이 종안정성에 미치는 영향에 관한 연구)

  • Jung, Suk-Young;Yoon, Sung-Joon
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.32 no.8
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    • pp.118-128
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    • 2004
  • Exhaust plume effects on longitudinal aerodynamics of missile were investigated by wind tunnel tests using a solid plume simulator and CFD analyses with both the solid plume and air jet plumes. Approximate plume boundary prediction technique was used to produce the outer shape of the solid plumer and chamber conditions and nozzle shapes of the air jet plumes were determined through plume modeling technique to compensate the difference in thermodynamic properties between air and real plume. From comparisons among turbulence models in case of external flow interaction with the air jet plume, Spalart-Allmaras model turned out to give accurate result and to be less grid-dependent. Effects induced by the plume were evaluated through the computations with Spalart-Allmaras turbulence model and the air jet plume to account for various ratios of chamber and ambient pressure and Reynolds number under the flight test condition.

Finite Element Analysis of Strain Localization in Concrete Considering Damage and Plasticity (손상과 소성을 고려한 콘크리트 변형률 국소화의 유한요소해석)

  • 송하원;나웅진
    • Computational Structural Engineering
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    • v.10 no.3
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    • pp.241-250
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    • 1997
  • The strain localization of concrete is a phenomenon such that the deformation of concrete is localized in finite region along with softening behavior. The objective of this paper is to develop a plasticity and damage algorithm for the finite element analysis of the strain-localization in concrete. In this paper, concrete member under strain localization is modeled with localized zone and non-localized zone. For modeling of the localized zone in concrete under strain localization, a general Drucker-Prager failure criterion by which the nonlinear strain softening behavior of concrete after peak-stress can be considered is introduced in a thermodynamic formulation of the classical plasticity model. The return-mapping algorithm is used for the integration of the elasto-plastic rate equation and the consistent tangent modulus is also derived. For the modeling of non-localized zone in concrete under strain localization, a consistent nonlinear elastic-damage algorithm is developed by modifying the free energy in thermodynamics. Using finite element program implemented with the developed algorithm, strain localization behaviors for concrete specimens under compression are simulated.

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Modeling and Theoretical Analysis of Thermodynamic Characteristic of Nano Vibration Absorber (나노 진동 흡수기의 모델링 및 열역학적 특성 해석에 대한 이론적 연구)

  • 문병영;정성원
    • Journal of the Earthquake Engineering Society of Korea
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    • v.7 no.6
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    • pp.93-99
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    • 2003
  • In this study, new shock absorbing system is proposed by using nano-technology based on the theoretical analysis. The new shock absorbing system is complementary to the hydraulic damper, having a cylinder-piston-orifice construction. Particularly for new shock absorbing system, the hydraulic oil is replaced by a colloidal suspension, which is composed of a porous matrix and a lyophobic fluid. The matrix of the suspension is consisted of porous micro-grains with a special architecture: they present nano-pores serially connected to micro-cavities. Until now, only experimentally qualitative studies of new shock absorbing system have been performed, but the mechanism of energy dissipation has not been clarified. This paper presents a modeling and theoretical analysis of the new shock absorbing system thermodynamics, nono-flows and energy dissipation. Compared with hydraulic system, the new shock absorbing system behaves more efficiently, which absorb a large amount of mechanical energy, without heating. The theoretical computations agree reasonably well with the experimental results. As a result. the proposed new shock absorbing system was proved to be an effective one, which can replace with the conventional one.

An Analysis of Thermal Conductivity of Ceramic Fibrous Insulator by Modeling & Simulation Method I (모델링/시뮬레이션 기법을 이용한 세라믹 섬유 단열재의 열전도도 해석 I)

  • Kang, Hyung;Baek, Yong-Kee
    • Journal of the Korea Institute of Military Science and Technology
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    • v.5 no.1
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    • pp.83-95
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    • 2002
  • Thermal conductivity of ceramic fibrous insulator was analysed and predicted by using the modeling/simulation technique. Ceramic fibrous insulators are widely used as high temperature insulator on account of their lightweight mass and heat resisting properties. Especially it is suitable to protect the high speed aircraft and missiles from severe aero-thermodynamic heating. Thermal conductivity of ceramic fibrous insulator could be determined from the conductive heat transfer and the radiative heat transfer through the insulator. In order to estimate conductive thermal conductivity, homogenization technique was applied, while radiative thermal conductivity was computed by means of random number and radiation probability. Particularly radiation probability can make it possible to estimate the conductivity of fibrous insulator without any experimental constant. The calculated conductivity predicted in the present study have a reasonable accuracy with an average error of 7 percent to experimental data.

Nonlinear modeling of a RC beam-column connection subjected to cyclic loading

  • Dominguez, Norberto;Perez-Mota, Jesus
    • Computers and Concrete
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    • v.21 no.3
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    • pp.299-310
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    • 2018
  • When reinforced concrete structures are subjected to strong seismic forces, their beam-column connections are very susceptible to be damaged during the earthquake event. Consequently, structural designers try to fit an important quantity of steel reinforcement inside the connection, complicating its construction without a clear justification for this. The aim of this work is to evaluate -and demonstrate- numerically how the quantity and the array of the internal steel reinforcement influences on the nonlinear response of the RC beam-column connection. For this, two specimens (extracted from an experimental test of 12 RC beam-column connections reported in literature) were modeled in the Finite Element code FEAP considering different stirrup's arrays. The nonlinear response of the RC beam-column connection is evaluated taking into account the nonlinear thermodynamic behavior of each component: a damage model is used for concrete; a classical plasticity model is adopted for steel reinforcement; the steel-concrete bonding is considered perfect without degradation. At the end, the experimental responses obtained in the tests are compared to the numerical results, as well as the distribution of shear stresses and damage inside the concrete core of the beam-column connection, which are analyzed for a low and high state of confinement.

The Effect of EGR Pipe Configuration on EGR Characteristics of Diesel Engine with Variable Geometry Turbocharger (EGR관 형상이 가변형상 과급기를 장착한 디젤엔진의 EGR 특성에 미치는 영향)

  • Jeong, Soo-Jin;Chung, Jae-Woo;Kang, Jeong-Ho;Kang, Woo
    • Transactions of the Korean Society of Automotive Engineers
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    • v.15 no.2
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    • pp.65-73
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    • 2007
  • The use of an Exhaust Gas Recirculation(EGR) for a diesel engine with variable geometry turbocharger(VGT) has confronted how to obtain the amount of EGR for NOx reduction requirement at wide operating range and less side effect. Through a combined effort of modeling(wave action simulation) and experiment, an investigation into the effect of EGR area ratio and pipe length on EGR characteristics of common rail diesel engine with VGT has been performed. For accurate computation, calibration of constants involved in empirical and semi-empirical correlations has been performed at a specific operating point, before of its use for engine simulation. From the results of this study, it was found that EGR rate is sharply increased with increasing EGR area ratio until area ratio of 0.3. However, the effect of EGR area ratio on EGR rate is negligible beyond this criteria. This study also investigates the effect of EGR pipe length on a EGR amount and pulsating flow characteristics at EGR junction. The results showed that the longer EGR pipe length, the lower EGR amount was achieved due to the flow loss resulting in lower amplitude of pressure wave.

Analysis of Solar Radiation Components in Korea (국내 일사량의 성분 분석)

  • Jo, Dok-Ki;Yun, Chang-Yeol;Kim, Kwang-Deuk;Kang, Young-Heack
    • 한국태양에너지학회:학술대회논문집
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    • 2009.04a
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    • pp.8-12
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    • 2009
  • The Knowledge of the solar radiation components are essential for modeling many solar energy systems. This is particularly the case for applications that concentrate the incident energy to attain high thermodynamic efficiency achievable only at the higher temperatures. In order to estimate the performance of concentrating thermal systems, it is necessary to know the intensity of the beam radiation, as only this component can be concentrated. The Korea Institute of Energy Research(KIER) has began collecting solar radiation component data since August, 2002. KIER's component data will be extensively used by concentrating system users or designers as well as by research institutes. The Result of analysis shows that the annual-average daily diffuse radiation on the horizontal surface is $1,458cal/m^2$ and daily direct radiation on the horizontal surface is $1,632cal/m^2$ for all over the 16 areas in Korea.

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Dynamic Numerical Modeling for LOx Swirl Injector at Supercritical Conditions (초임계 상태에서의 LOx 스월 인젝터에 대한 동적 수치 모델링)

  • Kim, Kuk-Jin;Heo, Jun-Young;Kim, Jong-Chan;Sung, Hong-Gye
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.11a
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    • pp.42-46
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    • 2009
  • For understanding of high performance liquid rocket engine operating at high pressure, dynamic characteristics of liquid oxygen in a swirl injector operating at supercritical conditions has been numerically investigated. Turbulent numerical model is based on large eddy simulation and contains full conservation laws including Soave modification of Redlich-Kwong equation of state and Chung's model. Preconditioning method is applied to get an effective convergence rate. Numerical analysis results are compared with the one that ideal equation of state applied to. Differences of thermodynamic properties and mixing dynamics are investigated at liquid phase area inside injector and combustion chamber.

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Numerical Analysis of Cryogenic Liquid Nitrogen Jets at Supercritical Pressures using Multi-Environment Probability Density Function approach (다점 확률분포 모델을 이용한 초임계 압력 액체질소 제트 해석)

  • Jung, Kiyoung;Kim, Namsu;Kim, Yongmo
    • Journal of ILASS-Korea
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    • v.22 no.3
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    • pp.137-145
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    • 2017
  • This paper describes numerical modeling of transcritical and supercritical fluid flows within a liquid propellant rocket engine. In the present paper, turbulence is modeled by standard $k-{\varepsilon}$ model. A conserved scalar approach in conjunction with multi-environment probability density function model is used to account for the turbulent mixing of real-fluids in the transcritical and supercritical region. The two real-fluid equations of state and dense-fluid correction schemes for mixtures are used to construct thermodynamic data library based on the conserved scalar. In this study, calculations are made on two cryogenic nitrogen jets under different chamber pressures. Sensitivity analysis for two different real-fluid equations of sate is particularly emphasized. Based on numerical results, precise structures of cryogenic nitrogen jets are discussed in detail. Numerical results show that the current real-fluid model can predict the essential features of the cryogenic liquid nitrogen jets.