• 설비공학논문집
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• 제6권3호
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• pp.282-290
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• 1994

A numerical model for the analysis and design of orifice pulse tube refrigerators has been developed. Heat transfer coefficient and friction factors in the model vary with time, and the real physical properties such as thermal conductivity and viscosity were used to improve the accuracy of the model. Thermodynamic behavior of the working fluid within pulse tube refrigerators was investigated and the effect of design parameters, such as reservoir volume, orifice diameter, and NTU of regenerator, on the cooling load and COP was shown.

• Journal of Photoscience
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• 제12권3호
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• pp.113-117
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• 2005

Spectroscopic investigations on the interaction of gabapentin (GBP) with bovine serum albumin (BSA) were reported. The association constant of GBP-BSA system was determined at different temperatures (298, 302, 306 and 311 K) based on the fluorescence quenching results. The GBP was found to quench the fluorescence of BSA through static mechanism. Thermodynamic parameters, the standard enthalpy change, $({\Delta}H^o)$ and the standard entropy change $({\Delta}S^o)$ were observed to be $-9.61{\pm}0.008\;kJ\;mol^{-1}$ and $3.58{\pm}0.011\;Jmol^{-1}K{-1}$ respectively. These indicated that the hydrophobic and electrostatic forces played a role in the interaction of GBP with BSA. The negative value of ${\Delta}G^o$ revealed that the binding reaction is spontaneous. The circular dichroism studies indicated the conformational changes in BSA upon interaction with GBP. The effect of some metal ions on the binding constant was also investigated.

• BMB Reports
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• 제35권3호
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• pp.302-305
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• 2002

Kinetic and thermodynamic studies have been made on the effect of the inosine product on the activity of adenosine deaminase in a 50 mM sodium phosphate buffer, pH 7.5, at $27^{\circ}C$ using UV spectrophotometry and isothermal titration calorimetry (ITC). A competitive inhibition was observed for inosine as a product of the enzymatic reaction. A graphical-fitting method was used for determination of the binding constant and enthalpy of inhibitor binding by using isothermal titration microcalorimetry data. The dissociation-binding constant is equal to $140\;{\mu}M$ by the microcalorimetry method, which agrees well with the value of $143\;{\mu}M$ for the inhibition constant that was obtained from the spectroscopy method.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2003년도 추계학술대회
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• pp.199-204
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• 2003

In the present study, the compression process in scroll compressor was simulated in consideration of flow leakage and heat transfer. Tangential and radial leakages of the refrigerant between the scrolls were considered as nozzle flow. The experiment was first conducted with a scroll compressor for automobile air conditioning system and R134a as a refrigerant. Temperature and pressure were measured at the suction and discharge ports of the compressor to determine the thermodynamic states of the refrigerant flow. Temperature distribution of the scroll with the involute angle was also measured by thermocouples that were installed inside the scroll. Measured temperature distribution was compared with the numerical results. From this result, the thermal effect of mechanical contact was found to be important in heat transfer of the compression process.

• 한국주조공학회지
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• 제34권4호
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• pp.136-142
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• 2014

Numerical solution of thermal stress by CAE analysis could be an effective method in product development stage of castings to predict and treat the problem of solidification cracking of castings. Quantitative stress-strain data are necessary, in this case. Tension type apparatus of a solidification crack test which can measure stress-strain relationship quantitatively was developed and the test procedure was established by this research. Solidification crack strength obtained from the following test procedure could be utilized to evaluate it in terms of effect factors on thermo-plastic characteristic of solidifying alloy such as grain size of solid, grain morphology, distribution of solid grain, etc. Proposed test procedure is as follow: Prediction of temperature at the failure site of solidification cracked specimen by computer simulation of solidification, Calculation of solid fraction of the failure site from thermodynamic solution of solidification under Scheil condition.

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2014년도 추계학술대회 논문집
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• pp.330-331
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• 2014

A mathematical model is suggested for diagnosis on a reciprocating pump. To the end, kinematic, thermodynamic and fluidic analyses are carried out for a simplified reciprocating pump model. The pressure inside the cylinder is expressed as a function of the rotation angle of a crank axle. The mathematical model consists of one cylinder with suction and discharge valves and an accumulator. The effect of valve leakage on the discharge angle is investigated. The discharge angle difference between normal state and leakage state increases with the leakage extent.

• 신재생에너지
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• 제3권2호
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• pp.47-52
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• 2007

Hydrate phase equilibrium for the binary $CO_{2}$+water and $CH_{4}$+water mixtures in silica gel pore of nominal 6, 30, and 100 nm were measured and compared with the cacluated results based on van der Waals and Platteeuw model. At a specific temperature three-phase hydrate-water-vapor (HLV) equilibrium curves for pore hydrates were shifted to the higher-pressure condition depending on pore sizes when compared with those of bulk hydrates. Notably, hydrate phase equilibria for the case of 100 nominal nm pore size were nearly identical with those of bulk hydrates. The activities of water in porous silica gels were modified to account for capillary effect, and the calculation results were generally in good agreement with the experimental data.

• 한국염색가공학회지
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• 제11권4호
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• pp.39-49
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• 1999

In order to study the properties of cochineal colors, uv-visible spectra of cochineal colors solution, dyeing properties on the wool in several dyeing conditions and thermodynamic parameters were investigated. UV-visible spectra of cochineal colors solution showed hypochromic effect with the lapse of irradiation time but bathochromic shift with decreasing acidity of solution and addition of metallic ions. The concentration of cochineal colors in wool fiber increased with the increase of dyeing temperature, time, and acidity of initial dyebath. The value of apparent diffusion coefficients and standard affinities of dyeing decreased with the increase of dyeing temperature. The standard heats of dyeing$(\Delta{H}^\circ)$ and variation of entropy$(\Delta{S}^\circ)$ increased with the increase of concentration of initial dyebath. The activation energy$(E_a)$ were calculated to be 1.399~2.595kcal/mol in condition of 6~1%(o.w.f) dyebath. Wool fabrics were dyed reddish blue by iron sulfate, copper sulfate, aluminum acetate and tannic acid, and red by tin chloride, respectively. Lightfastness of wool fabrics dyed by cochineal colors were increased by mordant treatment, especially copper sulfate and iron sulfate treatment.

• 설비공학논문집
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• 제13권8호
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• pp.771-779
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• 2001

In this study, a simulation program has been developed to predict the performance of a parallel flow condenser of an air conditioning system for an automobile. The well-known correlations for he heat transfer rates and the pressure drops are included in this model. It is fond that the numerical model can predict the heat transfer rate and the pressure drop accurately. As the condensing pressure increases of fixed air inlet temperature, the heat transfer rate increases and the pressure drop decreases. The effect of he degree of subcooling on the performance of the condenser is greater than that of the degree of super-heating because the ratio of the area occupied by he tow-phase refrigerant the total area is significantly affected by he degree of subcooling rather than the degree of superheating.

• 대한화학회지
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• 제16권2호
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• pp.84-92
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• 1972

A mechanism for the ring formation of nickel phthalocyanine (Ni-Pc) has been proposed based on chemical kinetics. The effect of the catalyst on the rate was examined, and ammonium molybdate has been found to be the most effective. The reaction order of the ring formation was determined to be of the 1st order over all, with only the concentration of urea affecting the rate of the ring formation. All the results including thermodynamic parameters support a conclusion that the rate-determining step seems to be the enolization of the urea-catalyst transition complex, followed by fast decomposition of the tautomeric enolized urea into ammonia and isocyanic acid. These intermediates then reacted with the phthalic anhydride to form imino and diimino-phthalimide, which condense to form nickel phthalocyanine in the presence of the nickel cation.