• Composites Research
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• v.33 no.6
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• pp.329-335
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• 2020

In this study, the thermo-rheological behaivors of petroleum pitches with different softening points were studied, and a B-stage phenolic resins/petroleum pitches blends were prepared by adding petroleum pitches to the phenolic resins. As a result, the petroleum pitch with different softening points decreased the fluidity of the petroleum pitch as the Quinoline insoluble (QI) content increased and showed the viscous properties of the solid. In addition, the effect of adding petroleum pitches having different softening points on the thermo-rheological properties of phenolic resins was investigated. When petroleum pitch with a high softening point was added, the fluidity of the phenolic resin was reduced, and the hardening behavior was fast. It was possible to control the curing rate and curing behavior of the phenolic resin by adding petroleum pitches of different softening points. Among them, the phenolic resin mixture to which P-Pitch 2 was added has a higher fluidity than other blends under the same curing temperature condition.

• Korea-Australia Rheology Journal
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• v.21 no.4
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• pp.235-244
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• 2009

Miscible polymer blends still have heterogeneity in their component chain concentration in the segmental length scale because of the chain connectivity (that results in the self-concentration of the segments of respective chains) as well as the dynamic fluctuation over various length scales. As a result, the blend components feel different dynamic environments to exhibit different temperature dependence in their segmental relaxation rates. This type of dynamic heterogeneity often results in a broad glass transition (sometimes seen as two separate transitions), a broad distribution of the local (segmental) relaxation modes, and the thermo-rheological complexity of this distribution. Furthermore, the dynamic heterogeneity also affects the global dynamics in the miscible blends if the component chains therein have a large dynamic asymmetry. Thus, the superficially simple miscible blends exhibit interesting dynamic behavior. This article gives a brief summary of the features of the segmental and global dynamics in those blends.

• Journal of the Microelectronics and Packaging Society
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• v.10 no.3
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• pp.9-17
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• 2003

In this paper, thermo-mechanical and rheological properties of NCPs (Non-Conductive Pastes) depending on silica filler contents and diluent contents were investigated. And then, thermal cycling (T/C) reliability of flip chip assembly using selected NCPs was verified. As the silica filler content increased, thermo-mechanical properties of NCPs were changed. The higher the silica filler content was added, glass transition temperature ($T_g$) and storage modulus at room temperature became higher. While, coefficient of thermal expansion (CTE) decreased. On the other hand, rheological properties of NCPs were significantly affected by diluent content. As the diluent content increased, viscosity of NCP decreased and thixotropic index increased. However, the addition of diluent deteriorated thermo-mechanical properties such as modulus, CTE, and $T_g$. Based on these results, three candidates of NCPs with various silica filler and diluent contents were selected as adhesives for reliability test of flip chip assemblies. T/C reliability test was performed by measuring changes of NCP bump connection resistance. Results showed that flip chip assembly using NCP with lower CTE and higher modulus exhibited better T/C reliability behavior because of reduced shear strain in NCP adhesive layer.

• Structural Engineering and Mechanics
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• v.47 no.1
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• pp.27-44
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• 2013

A finite element computational procedure for the accurate analysis of quasistatic thermorheological complex structures response is developed. The geometrical nonlinearity, arising from large displacements and rotations (but small strains), is accounted for by the total Lagrangian description of motion. The Schapery's nonlinear single-integral viscoelastic constitutive model is modified for a time-stress-temperature-dependent behavior. The nonlinear thermo-viscoelastic constitutive equations are incrementalized leading to a recursive relationship and thereby the resulting finite element equations necessitate data storage from the previous time step only, and not the entire deformation history. The Newton-Raphson iterative scheme is employed to obtain a converged solution for the non-linear finite element equations. The developed numerical model is verified with the previously published works and a good agreement with them is found. The applicability of the developed model is demonstrated by analyzing two examples with different thermal/mechanical loading histories.