• Title/Summary/Keyword: thermal-degradation

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Surface and Tracking Properties of Polymer Suspension Insulator for Power Transmission with secular variation (경년열화에 따른 송전용 폴리머 현수애자의 표면 및 트래킹 성능)

  • Cho, Han-Goo;Lee, Un-Yong;Han, Se-Won;Han, Dong-Hee;Huh, Jong-Chul;Choi, In-Hyuk
    • Proceedings of the KIEE Conference
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    • 2004.11a
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    • pp.233-236
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    • 2004
  • Recently, the polymer insulators that are used for high voltage applications have some advantages such as light weight, small size, vandalism resistance, hydrophobicity and easy making process. During outdoor service of polymer insulators, the surface of the insulating material is frequently subjected to moisture and contamination that lead to dry band arcing. Their tracking resistance, erosion resistance, end sealing and shed design are very important because dry band arcing causes degradation of polymer surface. The shape design of porcelain insulator is formalized but design standard for polymer insulator is no standardized up to now, much research is necessary in real condition. In this paper, the surface and tracking properties of polymer suspension insulator for power transmission is investigated with ICP-AES, SEM, EDX, tracking wheel test and flashover voltage test. The diagnosis of insulator sample in tracking test hass been analyzed by leakage current STRI Guide and thermal image.

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Study on a compatibilization of polypropylene/thermotropic liquid crystalline polymer blends (폴리프로필렌/열방성 액정 고분자 블렌드의 상용화에 관한 연구)

  • Son, Young-Gon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.8 no.5
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    • pp.1215-1219
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    • 2007
  • In this paper, we present a study on the polypropylene/thermotropic liquid crystalline polymer blends. In previous researches, the blends are fabricated at very high temperatures, at least 300oC, since the TLCPs investigated in most studies have melting temperatures higher than 270oC. As a consequence, the thermal degradation of PP can not be avoidable. In order to obtain high physical properties, the excess amount of TLCP must be added. In this study, a new type of TLCP was used in the PP/TLCP blends. Since the new TLCP has a melting point of 220oC, the blending can be performed at much lower temperature than the previous studios. The new PP/TLCP shows similar or somewhat higher physical properties than those of the previous studies. It is proved that the new TLCP can be used as a reinforcement material in PP based blends.

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Study on the rheological properties of PP-SEBS/silicate composites (PP-SEBS/실리케이트 복합체의 유변학적 특성 연구)

  • Kim, Youn-Cheol
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.12 no.4
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    • pp.1988-1992
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    • 2011
  • Polypropylene (PP)-SEBS/silicate composites with PP content of 35, 40, and 45wt% were fabricated by melt compounding at $200^{\circ}C$, using lab scale Brabender mixer. The content of silicate was fixed at 5wt%. The thermal properties of the PP-SEBS/silicate composites were investigated by differential scanning calorimetry (DSC) and thermogravimetric analyzer (TGA). The melting temperature of PP-SEBS compound decreased up to $141^{\circ}C$ with SEBS content. TGA result indicates an increase in degradation temperature when the silicate was added in the PP-SEBS compound. The rheological properties of the compounds were measured by dynamic Rheometer. PP-SEBS/silicate composite indicates higher shear thinning and elastic property than PP-SEBS compound. Van Gurp-Palmen analysis was applied in order to certify an increase in elasticity.

On-Line Condition Monitoring and Diagnostics of Distribution Equipment (배전반 설비의 온라인 모니터링 및 진단)

  • Yun, Ju-Ho;Im, Wan-Su;Hwang, Jong-Sun;Choi, Yong-Sung;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.525-526
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    • 2007
  • Continuous on-line temperature monitoring provides the means to evaluate current condition of equipment and detect abnormality. It allows corrective measures to be taken to prevent upcoming failure. Continuous temperature monitoring and event recording provides information on the energized equipment's response to normal and emergency conditions. On-line temperature monitoring helps to coordinate equipment specifications and ratings, determine the real limits of the monitored equipment and optimize facility operations. Using wireless technique eliminates any need for special cables and wires with lower installation costs if compared to other types of online condition monitoring equipment. In addition, wireless temperature monitoring works well under difficult conditions in strategically important locations. Wireless technology for on-line condition monitoring of energized equipment is applicable both as standalone system and with an interface with power quality monitoring system.

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Fabrication and Electrochemical Characterization of All Solid State Thin Film Micro-Battery by in-situ sputtering (In-situ 스퍼터링을 이용한 마이크로 박막 전지의 제작 및 전지 특성 평가)

  • 전은정;신영화;남상철;조원일;손봉희;윤영수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.159-162
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    • 1999
  • All solid state thin film micro-batteries consisting of lithium metal anode, an amorphous LiPON electrolyte and cathode of vanadium oxide have been fabricated and characterized, which were fabricated with cell structure of Li/LiPON/V$_2$O$\sub$5/Pt. The vanadium oxide thin films were formed by d.c. reactive sputtering on Pt current collector. After deposition of vanadium oxide films, in-situ growths of lithium phosphorus oxynitride film were conducted by r.f. sputtering of Li$_3$PO$_4$ target in mixture gas of N$_2$ and O$_2$. The pure metal lithium film was deposited by thermal evaporation on thin film LiPON electrolyte. The cell capacity was about 45${\mu}$Ah/$\textrm{cm}^2$ $\mu\textrm{m}$ after 200 cycle. No appreciable degradation of the cell capacity could be observed after 50 cycles .

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Synthesis and Properties of Blue Emitting Polymers Containing Carbazole Groups

  • Kwon, Young-Hwan;Wang, Hui;Kim, Yeon-Bo;Ryu, Jeong-Tak;Chang, Seung-Hyun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.473-474
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    • 2005
  • Blue-emitting polymers containing carbazole units In main chains were synthesized by palladium catalyzed polycondensation of aniline with dibromo-substituted monomers such as 3,6-dibromocarbazole, N-(2-ethylhexyl)-3,6-dibromocarbazole, and bis[6-bromo-N-(2-ethylhexyl)-carbazole-3-yl], respectively. All synthesized polymers exhibited relatively good solubility in common organic solvents, considerable molecular weights and high resistance to thermal degradation. From UV-Vis absorption and photoluminescence (PL) spectra of these solution-processable polymers, $\lambda_{max,UV}$ were in the range of 290 ~ 340 nm and $\lambda_{max,PL}$ were in the blue emission range of 440 ~ 478 nm, The polymers had HOMO energy (-5.19 ~ -5.64 eV) and wide band gap energy (2,91 - 3.42 eV).

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Photosensitive Polyimides Having Aromatic Sulfonyloxyimide Groups in the Main Chain (주쇄에 광분해성 방향족 술포닐옥시이미드기를 함유한 감광성 폴리이미드)

  • 오세용;이지영;조성열;정찬문
    • Polymer(Korea)
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    • v.24 no.3
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    • pp.407-417
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    • 2000
  • Photosensitive polyimides having cyclobutane or phenyl and aromatic sulfonyloxyimide units in the main chain have been synthesized and the photodegradation behavior was investigated in relation with the polymer structure. The polyimides were prepared by condensation polymerization of N-hydroxyl and sulfonyl chloride. The prepared polyimides were stable up to 25$0^{\circ}C$ without thermal degradation. It has been found that the photodegradation of polyimides upon irradiation of 254 nm UV light results from scission of N-O bonds or ring opening of imides moiety by spectroscopic measurements. The polyimides were useful as positive working photodegradable polymers. Especially, the positive tone image of polyimide containing a pyromellitic diimide moiety exhibited high sensitivity and resolution.

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Analysis of Charred-Woods Excavated from the Daewoongjeon Hall of Youngguksa Temple (영국사 대웅전 출토 탄화목의 재질 분석)

  • Son, Byung Hwa;Park, Won-Kyu
    • Journal of the Korean Wood Science and Technology
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    • v.35 no.1
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    • pp.36-43
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    • 2007
  • Elemental analysis, SEM-EDX, X-ray diffraction (XRD) and IR analysis were adopted to examine the quality of charred woods excavated from the underground of the Daewoongjeon Hall of Youngguksa Temple, Youngdong-gun, Chungbuk, Korea. A large amount of calcium was detected in SEM-EDX analysis. The analyses of chemical elements suggested that completely charred wood was carbonized at about $500^{\circ}C$. The XRD results indicated the destruction of cellulose crystalline region. The IR analysis exhibited that thermal degradation of wood component was different depending upon the carbonization temperature. It can be suggested from the results that PEG with different molecular weights should be used for the conservation of excavated charred woods.

Erosion properties of plasma sprayed zirconia Based coatings (지르코니아계 용사 코팅층의 Erosion 특성)

  • 신종한;임상규;임대순
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2001.06a
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    • pp.346-353
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    • 2001
  • Zirconia powder containing 3 mol% yttria(3Y-PSZ) with and with out Fe$_2$O$_3$ addition was coated on tile cast iron substrate by plasma spraying method. The erosion experiments were performed at temperatures from $25^{\circ}C$ to $600^{\circ}C$. A gas blast type erosion tester was used to examine erosion behavior of the specimens. The results of 3Y-PSZ coatings showed that tile erosion rate had maximum value at 40$0^{\circ}C$. It coincided with tile results of phase transformation tetragonal phase to monoclinic phase caused by low temperature thermal degradation. The tensile stress relaxation and the micro-hardness improvement significantly influenced on the erosion rate at $600^{\circ}C$. In the case of Fe$_2$O$_3$ added 3Y-PSZ coatings, the erosion rate of tested at $25^{\circ}C$ showed maximum value at 5.0 mol% Fe$_2$O$_3$ added coating. This tendency is caused by the improvement of mechanical properties and the tensile residual stress. The erosion rate at 200'c and 400'L showed significantly decrease by Fe203 addition. This decrease is believed to be the stabilization of the tetragonal phase and the increase of micro-hardness.

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Evaluation on the Cooling Performance to Design Heat sinks for LED lightings (LED 조명용 히트싱크 방열기 설계를 위한 냉각성능 평가)

  • Jung, Tae-Sung;Kang, Hwan-Kook
    • Journal of the Korean Society for Precision Engineering
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    • v.29 no.7
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    • pp.778-784
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    • 2012
  • In comparison with some other light sources, LED has merits such as increased life expectancy, fast response, pollution free, and high energy efficiency. Lately, due to development of LED with high brightness and capacity, LED has widely used in many industrial fields such as automotive, aviation, display, transportation and special lighting applications. Since the high heat generation of LED chips can cause a reduction in lifetime, degradation of luminous efficiency, and variation of color temperature, studies have been carried out on the optimization of LED packaging and heat sinks. In this study, experiments on measuring the heat generation rate of LED and the cooling performance of a heat sink were carried for analyzing the thermal characteristics of LED lighting system in free convection. From the results, dimensionless correlation on the cooling performance of heat sink in natural convection was proposed with Nusselt number and Rayleigh number as a guideline for designing cooling device of LED lightings.