• Title/Summary/Keyword: thermal-degradation

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A Study on Mechanical Characteristics and Behaviors of FRP Composite with Three Different types of Matrices under High Temperature (온도 및 매트릭스 특성 변화에 따른 섬유강화 복합재료의 역학적 특성 및 구조적 거동 변화)

  • Jung, Woo-Young;Jang, Jun-Ho;Back, Min-Ho
    • Journal of the Korean Society of Hazard Mitigation
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    • v.8 no.3
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    • pp.1-9
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    • 2008
  • Fiber Reinforced Polymer (FRP) composites are used extensively in aerospace, marine, automotive, infrastructure, chemical processing and sporting good applications. A concern with using FRP composites in some engineering structures is their high flammability and poor fire resistance In this research, material properties of FRP composites at increasingly high temperatures was measured and verified. The obtained mechanical properties of FRP composites were performed according to ASTM D3039/D3039M and tested to a wide range of heat conditions with temperatures from Room-temp. to 300 for times up to 30 min. It is found that the mechanical properties of FRP composites dropped with increasing heat or temperature. The reduction to the properties was due mainly to thermal degradation and combustion of the polymer matrix.

Investigation and Theoretical Analysis of a Fire Accident Caused by Smoldering Combustion (Smoldering 연소로 인한 화재사고 조사보고 소개 및 이론적 해석)

  • 김연승;변영철;황정호
    • Fire Science and Engineering
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    • v.13 no.3
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    • pp.3-17
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    • 1999
  • Smoldering is a non-flaming combustion mode, characterized by thermal degradation and c charring of the virgin material, evolution of smoke and emission of visible glow. A big fire may @ occur even in a confined environment having a limited amount of oxygen, due to smoldering c combustion through a porous solid material. This paper presents a theoretical analysis on the effect of smoldering combustion on fire occurrence based on a report about fire investigation of a real f fire accident. It is assumed that the propagation of the smolder wave is one-dimensional, d downward, opposing an upward forced flow and steady in a frame of reference moving with the s smolder wave. Smoldering combustion is modeled by a one-step reaction mechanism, without c considering pyrolysis. It is found that dominant parameters controlling smoldering combustion i include mass flux of oxidizer entering the reaction zone and void fraction of solid fuel. It is also found that the mechanism of transition to flaming is critically influenced by these two parameters.

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Mechanical Properties and Reliability of Sand Casting 3D Printing Materials (사형 주조 3D 프린팅용 소재의 기계적 특성 및 신뢰성)

  • Son, Hyeon Jin;Jang, Seongwan;Lee, Hwan Jong;Yang, Jeong Jik;Jeong, Yeong Geun;Bae, Chang-Jun
    • Korean Journal of Materials Research
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    • v.30 no.1
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    • pp.38-43
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    • 2020
  • Sand casting 3D printing uses a binder jetting method to produce a mold having complicated shape by spraying a binder on sand coated with activator. Appropriate heat treatment process in sand mold fabrication can increase the degree of polymerization to improve flexural strength. However, long heat treatment of over 24 hours decreases flexural strength and reliability due to chemical bond decomposition through thermal degradation. The main role of the activator is to control the reaction rate between the polymer chains. As a result, when the activator composition is increased from 0.15 wt% to 0.25 wt%, the flexural strength is increased by 218 N/㎠. However, excess activator (0.40 wt%) has been shown to decrease reliability without increasing flexural strength. The main role of the binder is to control the flexural strength of the specimen. As the binder composition is increased from 2.00 wt% to 4.00 wt%, the flexural strength increases to about 255 N/㎠, indicating the maximum flexural strength increase. Finally, the reliability of the flexural strength of the fabricated specimens is evaluated by a Weibull plot. Weibull modulus calculations are used to evaluate the flexural strength reliability of the specimens, and maximum reliability value of 11.7 is obtained at 0.20 wt% activator composition. Therefore, it is confirmed that this composition has maximum flexural strength reliability.

Effect of Phenolic Antioxidants System on Yellowing of Amorphous Poly-α-olefin (페놀계 산화방지제에 의한 비결정성 올레핀 수지의 황변 거동)

  • Kim, Si-Yong;Kim, Ho-Gyum;Park, Sang-Cheol;Min, Kyung-Eun
    • Polymer(Korea)
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    • v.37 no.2
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    • pp.156-161
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    • 2013
  • Phenolic antioxidants are effective stabilizers that provide excellent long-term heat stability by preventing thermo-oxidative degradation during processing and service life. However, under a selected set of circumstances, certain types of phenolics have been susceptible to discoloration due to prolonged storage in an environment containing oxides of nitrogen. It is investigated that the effect of addition of secondary antioxidant and chemical structure of primary antioxidant on discoloration of amorphous poly-${\alpha}$-olefin (APAO), which is especially prone to be decomposed in high processing temperature. From the result, it is concluded that a higher level of steric hindrance of phenolic antioxidant provided by long alkyl chain allows a more enhanced synergic effect with secondary antioxidant.

ROLE OF PASSIVE SAFETY FEATURES IN PREVENTION AND MITIGATION OF SEVERE PLANT CONDITIONS IN INDIAN ADVANCED HEAVY WATER REACTOR

  • Jain, Vikas;Nayak, A.K.;Dhiman, M.;Kulkarni, P.P.;Vijayan, P.K.;Vaze, K.K.
    • Nuclear Engineering and Technology
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    • v.45 no.5
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    • pp.625-636
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    • 2013
  • Pressing demands of economic competitiveness, the need for large-scale deployment, minimizing the need of human intervention, and experience from the past events and incidents at operating reactors have guided the evolution and innovations in reactor technologies. Indian innovative reactor 'AHWR' is a pressure-tube type natural circulation based boiling water reactor that is designed to meet such requirements, which essentially reflect the needs of next generation reactors. The reactor employs various passive features to prevent and mitigate accidental conditions, like a slightly negative void reactivity coefficient, passive poison injection to scram the reactor in event of failure of the wired shutdown systems, a large elevated pool of water as a heat sink inside the containment, passive decay heat removal based on natural circulation and passive valves, passive ECC injection, etc. It is designed to meet the fundamental safety requirements of safe shutdown, safe decay heat removal and confinement of activity with no impact in public domain, and hence, no need for emergency planning under all conceivable scenarios. This paper examines the role of the various passive safety systems in prevention and mitigation of severe plant conditions that may arise in event of multiple failures. For the purpose of demonstration of the effectiveness of its passive features, postulated scenarios on the lines of three major severe accidents in the history of nuclear power reactors are considered, namely; the Three Mile Island (TMI), Chernobyl and Fukushima accidents. Severe plant conditions along the lines of these scenarios are postulated to the extent conceivable in the reactor under consideration and analyzed using best estimate system thermal-hydraulics code RELAP5/Mod3.2. It is found that the various passive systems incorporated enable the reactor to tolerate the postulated accident conditions without causing severe plant conditions and core degradation.

Morphology and Mechanical Properties of Polyurethane/Organoclay Nanocomposites (폴리우레탄/유기화 점토 나노복합체의 모폴로지와 기계적 물성)

  • Park, Kyu-Nam;Yoon, Kwan-Han;Bang, Dae-Suk
    • Elastomers and Composites
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    • v.42 no.4
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    • pp.224-231
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    • 2007
  • Polyurethane (PU) was prepared with the compositions of polytetramethylene glycol (PTMG) having two different molecular weight (250, 1000 g/mol). The optimum composition of PTMG 250/1000 was 60/40 based on the mechanical properties. PU/organoclay nanocomposites were prepared with several kinds of organoclay. The mechanical properties of nanocomposite prepared with 93A were considerable. The improvement in tensile strength and modulus for PU/organoclay nanocomposite with the application of ultrasound compared to the PU/organoclay nanocomposite without the application of ultrasound was factors of 1.2, and hardness (shore A type) increased from 90 to 95. The difference in thermal degradation was not observed. The results of transmission electron micrographs and X-ray measurements suggest that the intercalated organoclay in PU matrix was observed.

Risk Mitigation for Independent Power Producer Projects in Developing Countries Based on Case Studies (사례연구를 통한 개발도상국 민자발전사업 리스크 경감방안)

  • Yoon, Young-Il;Yoo, Ho-seon;Yeo, Yeong-Koo
    • Plant Journal
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    • v.9 no.1
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    • pp.50-57
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    • 2013
  • This study investigates the risks that can occur during the development stage of IPP project in developing countries. In case that ECA and MLA cannot participate due to poor credit rating of the country, the diversification of power purchaser in marginal states can be a great help to reduce both market risk and country risk at the same time. In case of thermal power plants and combined cycle power plants, the effect of performance degradation as time passed will be considered and expected profit of sponsors should be maintained. Recently, developing countries are expanding IPP projects to reduce the financing cost and Korean power companies are positively participating in IPP projects. Accordingly, the loss of Korean companies should be minimized by risk management through the risk mitigation methods of this study.

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The Measurement and Analysis for Ultraviolet Radiation (자외선복사의 측정과 분석)

  • Han, Jong-Sung;Kim, Hong-Bum;Kim, Hoon
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.19 no.2
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    • pp.7-12
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    • 2005
  • When a light is projected upon a material, part of its radiant energy is absorbed and the rest is reflected or transmitted according to the nature of the material. The molecules of the substance absorbing a light obtains the radiant energy to make thermal reactions or photochemical reactions. Specially, photochemical reactions by ultraviolet(UV) radiation brings about photochemical degradation such as color change. Because the photochemical damage brings about a devaluation of material and once damaged, it is irretrievable, it is necessary to minimize the damage and conserve the native quality of a material by a protective lighting system. This paper presents the measurement and photochemical damage for UV radiation from light sources. We measured the optical radiations from artificial light sources and daylight, and we analyzed a functional relation between irradiance and UV radiation form the results.

DIAMETRAL CREEP PREDICTION OF THE PRESSURE TUBES IN CANDU REACTORS USING A BUNDLE POSITION-WISE LINEAR MODEL

  • Lee, Sung-Han;Kim, Dong-Su;Lee, Sim-Won;No, Young-Gyu;Na, Man-Gyun;Lee, Jae-Yong;Kim, Dong-Hoon;Jang, Chang-Heui
    • Nuclear Engineering and Technology
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    • v.43 no.3
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    • pp.301-308
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    • 2011
  • The diametral creep of pressure tubes (PTs) in CANDU (CANada Deuterium Uranium) reactors is one of the principal aging mechanisms governing the heat transfer and hydraulic degradation of the heat transport system (HTS). PT diametral creep leads to diametral expansion, which affects the thermal hydraulic characteristics of the coolant channels and the critical heat flux (CHF). The CHF is a major parameter determining the critical channel power (CCP), which is used in the trip setpoint calculations of regional overpower protection (ROP) systems. Therefore, it is essential to predict PT diametral creep in CANDU reactors. PT diametral creep is caused mainly by fast neutron irradiation, temperature and applied stress. The objective of this study was to develop a bundle position-wise linear model (BPLM) to predict PT diametral creep employing previously measured PT diameters and HTS operating conditions. The linear model was optimized using a genetic algorithm and was devised based on a bundle position because it is expected that each bundle position in a PT channel has inherent characteristics. The proposed BPLM for predicting PT diametral creep was confirmed using the operating data of the Wolsung nuclear power plant in Korea. The linear model was able to predict PT diametral creep accurately.

Current Status and Research Trend of Rare-earth Permanent Magnet (희토류 영구자석의 현황 및 개발 동향)

  • NamKung, Seok;Cho, Sang-Geun;Kim, JinBae
    • Journal of the Korean Magnetics Society
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    • v.22 no.6
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    • pp.221-227
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    • 2012
  • High performance permanent magnets have become the subject of considerable attention because of the potential applications in the traction motors of hybrid and electric vehicles and wind generators. Nd-Fe-B magnets have attracted considerable interest due to a large maximum energy product. However, Nd-Fe-B magnet cannot be used in high temperature (${\sim}200^{\circ}C$) applications due to the thermal degradation of coercivity. Therefore, the development of high coercivity Nd-Fe-B permanent magnet is a challenging issue. In case of high coercivity Nd-Fe-B permanent magnet, an increment in the intrinsic coercivity can be easily achieved by substituting Nd atoms with Dy or Tb atoms. However, these heavy rare-earth elements are known to cause a decrease in remanence due to the antiferromagnetic coupling between Dy and Fe atoms. In addition, Dy is relatively expensive and being limited in quantity. Hence, a new technology that can increase the coercivity of Nd-Fe-B sintered magnet using only a small amount, or even, no amount of heavy rare-earth elements is being investigated. This article describes the research trend in reducing the heavy rare-earth elements in Nd-Fe-B magnets.