• Title/Summary/Keyword: thermal-degradation

Search Result 1,119, Processing Time 0.035 seconds

Tracking Performance Test of Polymer Insulator with Salt Solution which is added Surface Active Agent (계면활성제가 첨가된 염수용액에 따른 폴리머 애자의 트래킹 성능 평가)

  • Cho, Han-Goo;Lee, Un-Yong;Han, Dong-Hee;Kang, Sung-Hwa;Choi, In-Hyuk;Lim, Kee-Joe
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.18 no.1
    • /
    • pp.62-67
    • /
    • 2005
  • Recently, polymer insulators that are used for high voltage applications have some advantages such as light weight, small size, vandalism resistance, hydrophobicity and easy making process. During outdoor service of polymer insulators, the surface of the insulating material is frequently subjected to moisture and contamination that lead to dry band arcing. Their tracking resistance, erosion resistance, end sealing and shed design are very important because dry band arcing causes degradation of polymer surface. Aging test to estimate life property of polymer insulator is executed through several international standard such as IEC 61109 and CEA tracking wheel test, but is not getting clear conclusion yet. There are two methods in the diagnosis method of polymer insulator such as off-line and on-line. The diagnosis methods in off-line are external condition analysis by the eye, contaminant analysis on surface, surface analysis, pollution withstand voltage test, power frequency flashover voltage test, lightning impulse flashover test, tensile fracture load test and flexural load test. Polymer material is also investigated it's tracking resistance by adding surface active agent in IEC 587. In this paper, the tracking performance of polymer insulator with salt solution which is added surface active agent. The diagnosis of insulator sample has been analyzed by leakage current and visual examination, STRI guide and thermal image camera.

Characteristics of Variant Dielectric Constants With Respect to Internal Combustion Engine Oil States (내연기관의 엔진오일상태에 대한 유전율 변화 특성)

  • Kim, Dong-Min;Kim, Yong-Ju;Lee, Seung-Hee
    • Journal of the Korean Society for Marine Environment & Energy
    • /
    • v.15 no.1
    • /
    • pp.19-21
    • /
    • 2012
  • The engine oil life of internal combustion engine is shorted by the thermal effect and that causes air pollution. In order to measure the status of engine oil accurately, the exchange of new oil extends the life of combustion engine and reduces environmental pollution. Capacitance probes, such as engine oil and fluids can be used to measure the dielectric constant. In this paper, the degradation of engine oil varies depending on the degree of dielectric properties was analyzed. Depending on the state of the oil, the variant capacitance of the probe was measured by LCR Meter, respectively, and then the permittivity of oil was calculated. In addition, according to the size of the probe by measuring the change in capacitance measurement, accuracy of dielectric constant are presented. According to oil contaminated with the more increase in dielectric constant, we can decide that contaminated oil is available.

Effects of Phosphatidylcholine and Phosphatidylethanolamine from Egg Yolk on Thermal Oxidation of Canola Oil (달걀 노른자에서 분리한 포스파티딜콜린과 포스파티딜에탄올아민이 카놀라유의 가열산화에 미치는 영향)

  • Kim, Kang-Hyun;Choe, Eun-Ok
    • Korean Journal of Food Science and Technology
    • /
    • v.40 no.6
    • /
    • pp.611-620
    • /
    • 2008
  • The principal objective of this study was to assess the effects of phosphatidylcholine (PC) and phosphatidylethanolamine (PE) extracted from egg yolk on the oxidation of tocopherol-stripped canola oil and its browning, as well as their content changes during 12 hr of heating at $180^{\circ}C$. PC and/ or PE contents in the oil were measured at 200, 500, 1,000, or 2,000 ppm. PL contents in the oil and oil browning were determined by high performance liquid chromatography (HPLC) and spectrophotometry, respectively. The oil oxidation was evaluated by the combination of fatty acid composition, conjugated dienoic acid content, and p-anisidine value. PC was degraded at a slower rate than PE during heating and the co-presence of PE reduced its rate of degradation. PE increased oil browning more profoundly than PC did. PC significantly reduced oil oxidation during heating; however, we noted a possible antagonism between PE and PC in reducing the oil oxidation. Egg yolk PC was a better antioxidant in oil oxidation during heating.

Development of Micro Tensile Test of CVD-SiC coating Layer for TRISO Nuclear Fuel Particles at elevated temperature

  • Lee, Hyun-Min;Park, Kwi-Il;Kim, Do-Kyung
    • Proceedings of the Materials Research Society of Korea Conference
    • /
    • 2012.05a
    • /
    • pp.95.1-95.1
    • /
    • 2012
  • Very High Temperature gas cooler Reactor (VHTR) has been considered as one of the most promising nuclear reactor because of many advantages including high inherent safety to avoid environmental pollution, high thermal efficiency and the role of secondary energy source. The TRISO coated fuel particles used in VHTR are composed of 4 layers as OPyC, SiC, IPyC and buffer PyC. The significance of CVD-SiC coatings used in tri-isotropic(TRISO) nuclear coated fuel particles is to maintain the strength of the whole particle. Various methods have been proposed to evaluate the mechanical properties of CVD-SiC film at room temperature. However, few works have been attempted to characterize properties of CVD-SiC film at high temperature. In this study, micro tensile system was newly developed for mechanical characterization of SiC thin film at elevated temperature. Two kinds of CVD-SiC films were prepared for micro tensile test. SiC-A had [111]-preferred orientation, while SiC-B had [220]-preferred orientation. The free silicon was co-deposited in SiC-B coating layer. The fracture strength of two different CVD-SiC films was characterized up to $1000^{\circ}C$.The strength of SiC-B film decreased with temperature. This result can be explained by free silicon, observed in SiC-B along the columnar boundaries by TEM. The presence of free silicon causes strength degradation. Also, larger Weibull-modulus was measured. The new method can be used for thin film material at high temperature.

  • PDF

A Study on Mechanical Characteristics and Behaviors of FRP Composite with Three Different types of Matrices under High Temperature (온도 및 매트릭스 특성 변화에 따른 섬유강화 복합재료의 역학적 특성 및 구조적 거동 변화)

  • Jung, Woo-Young;Jang, Jun-Ho;Back, Min-Ho
    • Journal of the Korean Society of Hazard Mitigation
    • /
    • v.8 no.3
    • /
    • pp.1-9
    • /
    • 2008
  • Fiber Reinforced Polymer (FRP) composites are used extensively in aerospace, marine, automotive, infrastructure, chemical processing and sporting good applications. A concern with using FRP composites in some engineering structures is their high flammability and poor fire resistance In this research, material properties of FRP composites at increasingly high temperatures was measured and verified. The obtained mechanical properties of FRP composites were performed according to ASTM D3039/D3039M and tested to a wide range of heat conditions with temperatures from Room-temp. to 300 for times up to 30 min. It is found that the mechanical properties of FRP composites dropped with increasing heat or temperature. The reduction to the properties was due mainly to thermal degradation and combustion of the polymer matrix.

Investigation and Theoretical Analysis of a Fire Accident Caused by Smoldering Combustion (Smoldering 연소로 인한 화재사고 조사보고 소개 및 이론적 해석)

  • 김연승;변영철;황정호
    • Fire Science and Engineering
    • /
    • v.13 no.3
    • /
    • pp.3-17
    • /
    • 1999
  • Smoldering is a non-flaming combustion mode, characterized by thermal degradation and c charring of the virgin material, evolution of smoke and emission of visible glow. A big fire may @ occur even in a confined environment having a limited amount of oxygen, due to smoldering c combustion through a porous solid material. This paper presents a theoretical analysis on the effect of smoldering combustion on fire occurrence based on a report about fire investigation of a real f fire accident. It is assumed that the propagation of the smolder wave is one-dimensional, d downward, opposing an upward forced flow and steady in a frame of reference moving with the s smolder wave. Smoldering combustion is modeled by a one-step reaction mechanism, without c considering pyrolysis. It is found that dominant parameters controlling smoldering combustion i include mass flux of oxidizer entering the reaction zone and void fraction of solid fuel. It is also found that the mechanism of transition to flaming is critically influenced by these two parameters.

  • PDF

Mechanical Properties and Reliability of Sand Casting 3D Printing Materials (사형 주조 3D 프린팅용 소재의 기계적 특성 및 신뢰성)

  • Son, Hyeon Jin;Jang, Seongwan;Lee, Hwan Jong;Yang, Jeong Jik;Jeong, Yeong Geun;Bae, Chang-Jun
    • Korean Journal of Materials Research
    • /
    • v.30 no.1
    • /
    • pp.38-43
    • /
    • 2020
  • Sand casting 3D printing uses a binder jetting method to produce a mold having complicated shape by spraying a binder on sand coated with activator. Appropriate heat treatment process in sand mold fabrication can increase the degree of polymerization to improve flexural strength. However, long heat treatment of over 24 hours decreases flexural strength and reliability due to chemical bond decomposition through thermal degradation. The main role of the activator is to control the reaction rate between the polymer chains. As a result, when the activator composition is increased from 0.15 wt% to 0.25 wt%, the flexural strength is increased by 218 N/㎠. However, excess activator (0.40 wt%) has been shown to decrease reliability without increasing flexural strength. The main role of the binder is to control the flexural strength of the specimen. As the binder composition is increased from 2.00 wt% to 4.00 wt%, the flexural strength increases to about 255 N/㎠, indicating the maximum flexural strength increase. Finally, the reliability of the flexural strength of the fabricated specimens is evaluated by a Weibull plot. Weibull modulus calculations are used to evaluate the flexural strength reliability of the specimens, and maximum reliability value of 11.7 is obtained at 0.20 wt% activator composition. Therefore, it is confirmed that this composition has maximum flexural strength reliability.

Effect of Phenolic Antioxidants System on Yellowing of Amorphous Poly-α-olefin (페놀계 산화방지제에 의한 비결정성 올레핀 수지의 황변 거동)

  • Kim, Si-Yong;Kim, Ho-Gyum;Park, Sang-Cheol;Min, Kyung-Eun
    • Polymer(Korea)
    • /
    • v.37 no.2
    • /
    • pp.156-161
    • /
    • 2013
  • Phenolic antioxidants are effective stabilizers that provide excellent long-term heat stability by preventing thermo-oxidative degradation during processing and service life. However, under a selected set of circumstances, certain types of phenolics have been susceptible to discoloration due to prolonged storage in an environment containing oxides of nitrogen. It is investigated that the effect of addition of secondary antioxidant and chemical structure of primary antioxidant on discoloration of amorphous poly-${\alpha}$-olefin (APAO), which is especially prone to be decomposed in high processing temperature. From the result, it is concluded that a higher level of steric hindrance of phenolic antioxidant provided by long alkyl chain allows a more enhanced synergic effect with secondary antioxidant.

ROLE OF PASSIVE SAFETY FEATURES IN PREVENTION AND MITIGATION OF SEVERE PLANT CONDITIONS IN INDIAN ADVANCED HEAVY WATER REACTOR

  • Jain, Vikas;Nayak, A.K.;Dhiman, M.;Kulkarni, P.P.;Vijayan, P.K.;Vaze, K.K.
    • Nuclear Engineering and Technology
    • /
    • v.45 no.5
    • /
    • pp.625-636
    • /
    • 2013
  • Pressing demands of economic competitiveness, the need for large-scale deployment, minimizing the need of human intervention, and experience from the past events and incidents at operating reactors have guided the evolution and innovations in reactor technologies. Indian innovative reactor 'AHWR' is a pressure-tube type natural circulation based boiling water reactor that is designed to meet such requirements, which essentially reflect the needs of next generation reactors. The reactor employs various passive features to prevent and mitigate accidental conditions, like a slightly negative void reactivity coefficient, passive poison injection to scram the reactor in event of failure of the wired shutdown systems, a large elevated pool of water as a heat sink inside the containment, passive decay heat removal based on natural circulation and passive valves, passive ECC injection, etc. It is designed to meet the fundamental safety requirements of safe shutdown, safe decay heat removal and confinement of activity with no impact in public domain, and hence, no need for emergency planning under all conceivable scenarios. This paper examines the role of the various passive safety systems in prevention and mitigation of severe plant conditions that may arise in event of multiple failures. For the purpose of demonstration of the effectiveness of its passive features, postulated scenarios on the lines of three major severe accidents in the history of nuclear power reactors are considered, namely; the Three Mile Island (TMI), Chernobyl and Fukushima accidents. Severe plant conditions along the lines of these scenarios are postulated to the extent conceivable in the reactor under consideration and analyzed using best estimate system thermal-hydraulics code RELAP5/Mod3.2. It is found that the various passive systems incorporated enable the reactor to tolerate the postulated accident conditions without causing severe plant conditions and core degradation.

Morphology and Mechanical Properties of Polyurethane/Organoclay Nanocomposites (폴리우레탄/유기화 점토 나노복합체의 모폴로지와 기계적 물성)

  • Park, Kyu-Nam;Yoon, Kwan-Han;Bang, Dae-Suk
    • Elastomers and Composites
    • /
    • v.42 no.4
    • /
    • pp.224-231
    • /
    • 2007
  • Polyurethane (PU) was prepared with the compositions of polytetramethylene glycol (PTMG) having two different molecular weight (250, 1000 g/mol). The optimum composition of PTMG 250/1000 was 60/40 based on the mechanical properties. PU/organoclay nanocomposites were prepared with several kinds of organoclay. The mechanical properties of nanocomposite prepared with 93A were considerable. The improvement in tensile strength and modulus for PU/organoclay nanocomposite with the application of ultrasound compared to the PU/organoclay nanocomposite without the application of ultrasound was factors of 1.2, and hardness (shore A type) increased from 90 to 95. The difference in thermal degradation was not observed. The results of transmission electron micrographs and X-ray measurements suggest that the intercalated organoclay in PU matrix was observed.