• Title/Summary/Keyword: thermal runaway

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Effect of Sintering Temperature on Electrical Stability of $Pr_{6}O_{11}$-Based ZnO Varistors ($Pr_{6}O_{11}$계 ZnO 바리스터의 전기적 안정성에 소결온도의 영향)

  • 남춘우;류정선
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.8
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    • pp.640-646
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    • 2001
  • The electrical stability for DC stress of Pr$_{6}$O$_{11}$-based ZnO varistos consisting of ZnO-Pr$_{6}$O$_{11}$-CoO-Cr$_2$O$_3$-Er$_2$O$_3$-based ceramics were investigated with sintering temperature in the range of 1325~1345$^{\circ}C$. A the sintering temperature is raised, the nonlinear exponent of varistors was decreased, whereas the stability was markedly improved. The density of ceramics was found to greatly affect the electrical stability for DC stress. The varistors sintered at 13$25^{\circ}C$ were completely degraded because of thermal runaway attributing to low density. The varistors sintered at 1335$^{\circ}C$ exhibited the highest nonlinearity, with a nonlinear exponent of 70.53 and a leakage current of 1.92$\mu$A, whereas they did not exhibit relatively high stability. On the contrary, the varistors sintered at >134$0^{\circ}C$ exhibited not only a high nonlinearity marking the nonlinear exponent above 50 and the leakage current below 3$\mu$A, but also a high stability marking the variation rate of the varistor voltage below 2%, even under DC stress such as (0.80V$_{1mA}$/9$0^{\circ}C$/12h)+(0.85V$_{1mA}$/115$^{\circ}C$/12h)+(0.90V$_{1mA}$/12$0^{\circ}C$/12h)+(0.95V$_{1mA}$/1$25^{\circ}C$/12h)+(0.95V$_{1mA}$/15$0^{\circ}C$/12h). In particular, ti was found that the varistors sintered at 134$0^{\circ}C$ were more nonlinear and more stable, compared with that of 1345$^{\circ}C$.EX>.}C$.EX>.

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Changes of Electrical Characteristics of Low-voltage ZnO Varistors by a lightning Impulse Current (뇌충격전류에 의한 저압용 산화아연형 바리스터의 전기적 특성변화)

  • 이종혁;한주섭;길경석;권장우;송동영;최남섭
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.4 no.4
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    • pp.793-801
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    • 2000
  • This paper presents the effect of lightning impulse current on ZnO varistors(390[V], 6.5[kA]) used in low-voltage AC mains as a protective device against transient overvoltages. The electrical characteristics of ZnO varistors are deteriorated by overtime impulse current, and a deteriorated ZnO varistor is brought to a thermal runaway and finally destroyed even in normal operating voltage. Therefore, it is important to estimate the changes of the electrical characteristics of ZnO varistors. A lightning impulse current standardized in IEC 61000-4-5 is applied to the varistors to accelerate deterioration, and the energy applied to the varistor at each time is about 12 [J]. In the experiment, various parameters such as leakage current, reference voltage are measured with the number of applied impulse current. Also, micro-structure changes of the varistors after applying the lightning impulse current of 200 times are compared. The electrical characteristics of the varistors are degraded by overtime impulse current, showing increase in leakage current and decrease in reference voltage.

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A Study on the Improvement of Forward Blocking Characteristics in the Static Induction Transistor (Static Induction Transistor의 순방향 블로킹 특성 개선에 관한 연구)

  • Kim, Je-Yoon;Jung, Min-Chul;Yoon, Jee-Young;Kim, Sang-Sik;Sung, Man-Young;Kang, Ey-Goo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07a
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    • pp.292-295
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    • 2004
  • The SIT was introduced by Nishizawa. in 1972. When compared with high-voltage, power bipolar junction transistors, SITs have several advantages as power switching devices. They have a higher input impedance than do bipolar transistors and a negative temperature coefficient for the drain current that prevents thermal runaway, thus allowing the coupling of many devices in parallel to increase the current handling capability. Furthermore, the SIT is majority carrier device with a higher inherent switching speed because of the absence of minority carrier recombination, which limits the speed of bipolar transistors. This also eliminates the stringent lifetime control requirements that are essential during the fabrication of high-speed bipolar transistors. This results in a much larger safe operating area(SOA) in comparison to bipolar transistors. In this paper, vertical SIT structures are proposed to improve their electrical characteristics including the blocking voltage. Besides, the two dimensional numerical simulations were carried out using ISE-TCAD to verify the validity of the device and examine the electrical characteristics. A trench gate region oxide power SIT device is proposed to improve forward blocking characteristics. The proposed devices have superior electrical characteristics when compared to conventional device. Consequently, the fabrication of trench oxide power SIT with superior stability and electrical characteristics is simplified.

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Combustion Characteristics and the Modeling of Ionized Methane for Battery Fires (배터리화재를 모사한 이온화 메탄의 연소특성 및 모델링)

  • Ko, Hyuk-Ju;Lee, Eui-Ju
    • Fire Science and Engineering
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    • v.33 no.1
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    • pp.23-29
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    • 2019
  • Rechargeable battery such as lithium-ion battery has been noticed as a kinds of the energy storage system in the recent energy utilization and widely used actually in various small electronic equipment and electric vehicles. However, many thermal runaway caused battery accidents occurred recently, which still is obstacle for advanced application of lithium ion battery. One of the main differences to general fires is the existence of ionized electrolyte with electron during combustion. Therefore, we simply simulated the ion addition effects of battery fires by introducing an ionized fuel in jet diffusion flames. When the ionized methane through a corona discharge was used as fuel, the overall flame stability and shape such as flame length showed no significant difference from normal methane flame, but NOx and CO emissions measured at the post flame region decreased. The ion addition effect of methane oxidation was also numerically simulated with the modeling of hydrogen addition in the mixture. It was confirmed that the hydrogen addition at a fixed temperature had a similar effects on ionization of methane and hence could be modeled successfully.

Evaluation of Internal Blast Overpressures in Test Rooms of Elcetric Vehicles Battery with Pressure Relief Vents (압력배출구를 설치한 전동화 차량 배터리 시험실의 내부 폭압 평가)

  • Pang, Seungki;Shin, Jinwon;Jeong, Hyunjin
    • Journal of the Korean Society for Geothermal and Hydrothermal Energy
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    • v.18 no.3
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    • pp.7-18
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    • 2022
  • Secondary batteries used in electric vehicles have a potential risk of ignition and explosion. Various safety measures are being taken to prevent these risks. A numerical study was performed using a computational fluid dynamics code on the cases where pressure relief vents that can reduce the blast overpressures of batteries were installed in the through-compression test room, short-circuit drop test room, combustion test room, and immersion test room in facilities rleated to battery used in electric vehicles. This study was conducted using the weight of TNT equivalent to the energy release from the battery, where the the thermal runaway energy was set to 324,000 kJ for the capacity of the lithium-ion battery was 90 kWh and the state of charge (SOC) of the battery of 100%. The explosion energy of TNT (△HTNT) generally has a range of 4,437 to 4,765 kJ/kg, and a value of 4,500 kJ/kg was thus used in this study. The dimensionless explosion efficiency coefficient was defined as 15% assuming the most unfavorable condition, and the TNT equivalent mass was calculated to be 11 kg. The internal explosion generated in a test room shows the very complex propagation behavior of blast waves. The shock wave generated after the explosion creates reflected shock waves on all inner surfaces. If the internally reflected shock waves are not effectively released to the outside, the overpressures inside are increased or maintained due to the continuous reflection and superposition from the inside for a long time. Blast simulations for internal explosion targeting four test rooms with pressure relief vents installed were herein conducted. It was found that that the maximum blast overpressure of 34.69 bar occurred on the rear wall of the immersion test room, and the smallest blast overpressure was calculated to be 3.58 bar on the side wall of the short-circuit drop test room.

A Study on Developing Safety and Performance Assessment Guideline for Electronic Warm-Acupuncture Apparatus (전기식 온침기에 대한 안전성 및 성능평가 가이드라인 개발 연구)

  • Hansol Jang;U-Ryeong Chung;Jeong-Hyun Moon;Seong-Kyeong Choi;Won-Suk Sung;Min-Seop Hwang;Seung-Deok Lee;Kyung-Ho Kim;Jong-Hwa Yoon;Eun-Jung Kim
    • The Journal of Korean Medicine
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    • v.43 no.3
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    • pp.150-163
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    • 2022
  • Objectives: This research aimed to develop a guideline for evaluating safety and performance of electronic warm-acupuncture apparatus. With the development of medical devices like electronic warm-acupuncture apparatus with improved performance, convenience and safety measures compared to traditional warm-acupuncture needling, safety and performance guideline is a necessity. Methods: By referring to existing standards and guidelines of other electronic devices for Korean medicine with heating function, guideline for safety and performance assessment of electronic warm-acupuncture apparatus was drafted Results: The guideline, presents explanation for adequate temperature and settings of the apparatus, and safety measurements providing against thermal runaway situations along with guidelines for the manual. Guideline for detailed test method for the performance of the apparatus such as accuracy of temperature increase and the timer, and safety unit was also provided. The test items and suggested test methods for the requirements of biological, electrical and electromagnetic safety were referred to Korean approval documents of ministry of Food and Drug Safety. Conclusion: We proposed the relevant items to verify performance and safety of warm-acupuncture apparatus to assure patient safety and improve the quality of currently developing devices for application in clinical field.

Design of Non-Flammable Electrolytes for Highly Safe Lithium-Ion Battery (리튬 이온전지의 안전성을 구현하기 위한 난연성 전해액의 설계)

  • Choi, Nam-Soon;Kim, Sung-Soo;Narukawa, Satoshi;Shin, Soon-Cheol;Cha, Eun-Hee
    • Journal of the Korean Electrochemical Society
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    • v.12 no.3
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    • pp.203-218
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    • 2009
  • The development of lithium-ion battery (LIB) technologies and their application in the field of large-scale power sources, such as electric vehicles (EVs), hybrid EVs, and plug-in EVs require enhanced reliability and superior safety. The main components of LIBs should withstand to the inevitable heating of batteries during high current flow. Carbonate solvents that contribute to the dissociation of lithium salts are volatile and potentially combustible and can lead to the thermal runaway of batteries at any abuse conditions. Recently, an interest in nonflammable materials is greatly growing as a means for improving battery safety. In this review paper, novel approaches are described for designing highly safe electrolytes in detail. Non-flammability of liquid electrolytes and battery safety can be achieved by replacing flammable organic solvents with thermally resistive materials such as flame-retardants, fluorinated organic solvents, and ionic liquids.

Implementation of Battery Management System for Li-ion Battery Considering Self-energy Balancing (셀프에너지 밸런싱을 고려한 리튬이온전지의 Battery Management System 구현)

  • Kim, Ji-Myung;Lee, Hu-Dong;Tae, Dong-Hyun;Ferreira, Marito;Park, Ji-Hyun;Rho, Dae-Seok
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.3
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    • pp.585-593
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    • 2020
  • Until now, 29 fire accidents have occurred; 22 of them were caused by the interconnection of renewable energy sources that occurred during the rest period after the lithium-ion battery had been fully charged regardless of the seasons. The fire accidents of ESS were attributed to thermal runaway due to the overcharging of a few cells with the phenomenon of self-energy balancing, which is unintentional current flow from cells with a high SOC to the low cells if the SOC condition of each cell connected in parallel is different. Therefore, this paper proposes a novel configuration and operation algorithm of the BMS to prevent the self-energy balancing of ESS and presents a hybrid SOC estimation algorithm. From the test results of the self-energy balancing phenomenon between aging and normal cells based on the proposed algorithm and BMS, it was confirmed the possibility of self-energy balancing, which is unintentional current flow from cells with a high SOC to cells with a low SOC. In addition, the proposed configuration of the BMS is useful and practical to improve the safety of lithium-ion batteries because the BMS can reliably disconnect a parallel connection of the cells if the self-energy balancing current becomes excessively high.

A Study on the Stability of ZnO-${Pr_6}{O_{11}}$-CoO-${Er_2}{O_3}$Based Varistors (ZnO-${Pr_6}{O_{11}}$-CoO-${Er_2}{O_3}$계 바리스터의 안정성에 관한 연구)

  • 남춘우
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.8
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    • pp.667-674
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    • 2000
  • The stability of ZnO-Pr$_{6}$/O$_{11}$-CoO-Er$_{2}$/O$_3$based varistors was investigated with Er$_{2}$/O$_3$additive content of the range 0.0 to 2.0 mol%. All varistors sintered at 130$0^{\circ}C$ exhibited the thermal runaway within short times even under weak d.c. stress. As a result these varistors were completely degraded. On the contrary the stability of varistors sintered at 135$0^{\circ}C$ was far better than that of 130$0^{\circ}C$. In particular the varistors added with 0.5mol% Er$_{2}$/O$_3$ which the nonlinear exponent is 34.83 and the leakage current is 7.38 $mutextrm{A}$ showed a excellent stability which the variation rate of the varistors voltage the nonlinear coefficient and the leakage current is below 1%, 2%, and 3.5% respectively even under more severe d.c. stress such as (0.80 V$_{1mA}$9$0^{\circ}C$/12h)+(0.85 V$_{1mA}$115$^{\circ}C$/12h)+(0.90 V$_{1mA}$12$0^{\circ}C$12h) Consequently it is estimated that the ZnO-0.5 mol% Pr$_{6}$/O sub 11/-1.0 mol% CoO-0.5 mol% Er$_{2}$/O sub 3/ based varistors will be used to develop the advanced Pr$_{6}$/O$_{11}$-1.0 mol% CoO-0.5 mol% Er$_{2}$/O$_{3}$ based varistors will be used to develop the advanced Pr$_{6}$/O$_{11}$-based ZnO varistors having the high performance and stability in future. future.ure. future.

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Electrical Stability of Zn-Pr-Co-Cr-Dy Oxides-based Varistor Ceramics (Zn-Pr-Co-Cr-Dy 산화물계 바리스터 세라믹스의 전기적 안정성)

  • 남춘우;박종아;김명준;류정선
    • Journal of the Korean Ceramic Society
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    • v.40 no.11
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    • pp.1067-1072
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    • 2003
  • The electrical stability of the varistor ceramics composed of Zn-Pr-Co-Cr-Dy oxides-based varistors was investigated at 0.0∼2.0 mol% Dy$_2$O$_3$ content under DC accelerated aging stress. The ceramic density was increased up to 0.5 mol% Dy$_2$O$_3$ whereas further addition of Dy$_2$O$_3$ decreased sintered ceramic density. The density sailently affected the stability due to the variation of conduction path. The nonlinearity of varistor ceramics was greatly improved above 45 in the nonlinear exponent and below nearly 1.0 ${\mu}$A by incorporating Dy$_2$O$_3$. Under 0.95 V$\_$1mA/150$^{\circ}C$/24 h stress state, the varistor ceramics doped with 0.5 mol% Dy$_2$O$_3$ exhibited the highest electrical stability, in which the variation rates of varistor voltage, nonlinear exponent, and leakage current were -0.9%, -14.4%, and +483.3%, respectively. The variation rates of relative permittivity and dissipation factor were +7.1% and +315.4%, respectively. The varistors with further addition of Dy$_2$O$_3$ exhibited very unstable state resulting in the thermal runaway due to low density.