• 한국수소및신에너지학회논문집
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• 제19권4호
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• pp.299-304
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• 2008

Thermal decomposition of Ammonia Borane have been investigated with various analytical methods including TGA, TP-MS, DSC. By-products such as aminoborane and borazine were identified during hydrogen release by TGA, TP-MS analysis. $H_2$ release amount was measured at each temperature isothermally, which resulted in 7 wt% $H_2$ release at 130$^{\circ}C$. Moreover, higher temperature enhanced hydrogen release kinetics leading to shortened induction period from 20 min at 95$^{\circ}C$ to 0 min at 130$^{\circ}C$. Melting and decomposition at close temperature (4$^{\circ}C$ difference) caused the formation of thin foam during hydrogen release. Suppression of by-products and thin foam formation during hydrogen release is suggested as critical issues to realize chemical hydrogen storage system with ammonia borane.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2001년도 제16회 학술발표회 논문초록집
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• pp.1-6
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• 2001

In this paper, edge delaminations in cracked composite plates are analytically investigated. A theoretical model based upon a sub-laminate approach is used to determine the strain energy release rate, $G^{ed}$, in [$\pm$$\theta_m$/$90_n$]$_s$ carbon/epoxy laminates loaded in tension. The analysis provides closed-form expressions for the reduced stiffness due to edge delamination and matrix cracking and the total energy release rate. The parameters controlling the laminate behaviour are identified. It is shown that the available energy for edge delamination is increased notably due to transverse ply cracking. Also thermal stresses increase substantially the strain energy release rate and this effect is magnified by the presence of matrix cracking. Prediction for the edge delamination onset strain is presented and compared with experimental data. The analysis could be applied to ceramic matrix composite laminates where similar mechanisms develop, but further experimental evidence is required.

• 한국의류학회지
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• 제19권1호
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• pp.36-50
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• 1995

The purpose of this study was 1) to estimate the improvement of thermal storage/release and moisture transport properties of PEG-treated acrylic athletic socks and suggest the optimum add-on for PEG treatment, 2) to investigate wear performance of untreated cocks and two kinds of socks treated with PEG of minimum and optimum add-on respectively, and 3) to consider the effect of thermal storage/release and moisture transport properties of PEG- treated socks on the wear performance and the subjective comfort zone. Thermal activities of specimens treated by PDC were evaluated on a DSC by measuring the heat of fusion on heating and the heat of crystallization on cooling. Moisture regain, absorption speed, wickability, water retenti on value, and water-vapor permeability were measured. In the wear trials that the subjects performed a subsequent exercise protocol wearing three differently treated socks in a conditioned environment ($14\pm2^{\circ}C$, 65$\pm$2% R.H.), microclimate temperature and humidity, and subjective wear sensations including thermal sensation, wettedness, softness, fit, and overall comfort were obtained. PEC-treated specimens with more than 20% add-on showed thermal storage on heating and thermal release on cooling by a DSC and the heat contents of treated ones were generally proportional to the add-ons. Moisture transport properties were highly improved after PEG treatment and increased rapidly with increasing add-on. The tendencies were, however, relaxed above 50% add-on and the treated knits were much stiffer above that add-on. In the wear trials of untreated, PEG add-on 20%, and 50% acrylic socks, the changes of microclimate temperature of 50% socks were significantly less than that of 20% socks. PEG add-on 50% socks showed significantly less changes of microclimate humidity than other two kinds of socks. Three kinds of socks showed significant differences in overall comfort and add-on 50% socks were accepted more comfortable than other two kinds of socks. Comfort zone of foot was extended after PEG treatment on socks and it implied that the subjects wearing PEG- treated socks felt comfortable in wider ranges of microclimate temperature and humidity.

• 한국화재소방학회논문지
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• 제34권3호
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• pp.28-34
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• 2020

고체 가연물 주위의 유동과 열적 두께의 변화가 열방출률 특성에 미치는 영향을 고찰해보기 위해 ISO 5660-1 콘 칼로리미터 실험을 수행하였다. 고체 가연물로는 연소반응 중 Char를 발생시키지 않는 Polymethyl methacrylate (PMMA)를 선정하였고 열침투깊이를 계산하여 PMMA의 열적 두께를 구분하였다. 콘 칼로리미터의 덕트 유동을 12, 24, 40 L/s로 설정하여 가연물 주위에 강제 유동을 발생시킨 뒤 PMMA의 연소 시 측정된 열방출률을 측정함으로써 열분해 특성을 분석하였다. 열적으로 얇은 가연물의 열방출률은 주위의 유동 변화에 크게 영향을 받지 않았지만, 열적으로 두꺼운 가연물은 유량의 변화에 따라 열방출률이 크게 영향 받는 것을 확인하였다.

• Archives of Pharmacal Research
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• 제16권2호
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• pp.129-133
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• 1993

Temperature sensitive liposomes(TSL) containing adriamycin (ADM) and cytarabine (Ara-C) were prepared. ADM and Ara-C were selected as model compounds of amphiphilic and hydrophilic drug, respectively. Encapsulation efficiency of ADM entrapped into TSL was about twice greater than that of Ara-C. It might be due to different polarity of the drug, Lipid compositions of TSL had no effect on the encapsulation efficiency of drugs. Thermal behavior of TSL using a differential scanning calorimetry (DSC) was also investigated. Phase transition of TSL using a differential scanning calorimetry (DSC) was also investigated. Phase transition temperature $(T_c)$ of TSL was dependent on the lipid compositions of TSL ADM broadened thermogram of TSL but Ara-C did not. However, $T_c$ of TSL was not changed by any drug. Release rate of drugs was highly dependent on temperature. The release profile of ADM was similar to that of Ara-C. The maximum release rate of drugs from TSL was occurred at the near $T_c$ and observed at $39-41^\circ{C}$ for DPPC (Dipalmitoylphosphatidylcholine) only, $52-54^\circ{C}$ for DPPC and DSPC (1:1), respectively. Effect of human serum alburmin (HAA) on the release rate of ADM was investigated. HSA had no significant effect on the release of ADM below $T_c$. However, ADM release from TSL was increased at the near and above $T_c$. The HSA-induced leakage of drug may result from the interaction of liposomal constituents with HSA structure at the near TEX>$4^\circ{C}$. From the fact that the release profiles of ADM from freshly prepared TSL and stored TSL for 1 week at TEX>$4^\circ{C}$ was not changed, the TSL was considered to be stable for at least 1 week at TEX>$4^\circ{C}$. Based on these findings, TSL may be useful to deliver drugs to preheated target sites due to its thermal behaviors.

• 환경영향평가
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• 제9권2호
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• pp.99-107
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• 2000

In order to solve water quality problem of domestic dam reservoir, many projects have been performed in a point of view to restoration of water quality. This study was carried out to evaluate the effect of release from sediment on water quality and release characteristics. Daecheong dam reservoir was investigated for two years, from 1998 to 1999. The nutrient release rates of Daecheong reservoir is less than foreign eutrophic reservoir at anoxic condition. For the evaluation of the effect of nutrient release on water quality, internal and external loading was calculated at Daecheong reservoir. As total phosphorus loading from sediment is calculated 9.3 ton/yr and inflow loading from Daecheong reservoir watershed 118 ton/yr, internal loading shows the portion of 7.88% to external loading. At this study, because sampling point was choosed at the point where much sediment is accumulated, experimental result is more than average release rates. Because Daecheong reservoir shows complete thermal stratification and anoxic condition below 30m from water surface in summer seasons, released phosphorus from sediment can not transfer to epilimnion and eventually resettles. Therefore sediment has insignificant impacts on water quality on Daecheong dam reservoir.

• Nuclear Engineering and Technology
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• 제43권6호
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• pp.499-508
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• 2011

The paper briefs a fuel performance code, COSMOS, which can be utilized for an analysis of the thermal behavior and fission gas release of fuel, up to a high burnup. Of particular concern are the models for the fuel thermal conductivity, the fission gas release, and the cladding corrosion and creep in $UO_2$ fuel. In addition, the code was developed so as to consider the inhomogeneity of MOX fuel, which requires restructuring the thermal conductivity and fission gas release models. These improvements enhanced COSMOS's precision for predicting the in-pile behavior of MOX fuel. The COSMOS code also extends its applicability to the instrumented fuel test in a research reactor. The various in-pile test results were analyzed and compared with the code's prediction. The database consists of the $UO_2$ irradiation test up to an ultra-high burnup, power ramp test of MOX fuel, and instrumented MOX fuel test in a research reactor after base irradiation in a commercial reactor. The comparisons demonstrated that the COSMOS code predicted the in-pile behaviors well, such as the fuel temperature, rod internal pressure, fission gas release, and cladding properties of MOX and $UO_2$ fuel. This sufficient accuracy reveals that the COSMOS can be utilized by both fuel vendors for fuel design, and license organizations for an understanding of fuel in-pile behaviors.

• 한국화재소방학회:학술대회논문집
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• 한국화재소방학회 1996년도 학술발표회
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• pp.53-56
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• 1996

In order to propose the method of the consequence analysis for fire accidents by the heavy gas release and to obtain optimum conditions of parameter selections, the consequence analysis for jet fire by the accident of xylene vapor release were performed. And the effect and the sensitivity analysis of parameters affecting the consequence were investigated. Simulation results showed that important parameters affecting results of the xylene vapor release accident were mainly hole diameter, interested distance, wind speed, and so on. For the jet fire, the accident result and the sensitivity of thermal radiation were increased with the decrease of interested distance and the increase of hole diameters, and the accidental result was increased as the increase wind speed, but the sensitivity of thermal radiation was decreased.

• 한국화재소방학회논문지
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• 제17권2호
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• pp.17-24
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• 2003

본 논문은 파스콘 또는 콘크리트 재질의 트로프에 설치되는 전선에 대한 열의 영향과 이들 트로프에 대한 열 방출 정도에 대한 차이점을 이론상으로 접근하고 평가하고자 하였으며, 실제 상황과 근접한 조건으로 컴퓨터 시뮬레이션을 실시함으로서 두 트로프 내의 전선에 대한 열의 영향과 두 트로프의 열 발산정도를 추정하고 그에 대한 타당성을 입증하고자 하였다. 이에 대한 연구 결과 파스콘의 고유 열전도 값과 콘크리트의 고유 열전도 값을 단순 비교하면 콘크리트 제품의 열 방출량이 우수한 것으로 판단할 수 있으나, 실제 설치되는 두 트로프의 실제 두께와 면적 및 세부 구조를 고려하여 연산 및 시뮬레이션을 실시해 본 결과 파스콘 트로프가 콘크리트 트로프 보다 다소 우위에 있는 것으로 평가되었다.

• 한국의류학회지
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• 제21권6호
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• pp.1041-1050
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• 1997

This study was carried out to improve the thermal insulation properties of wool and wool- like fabrics by treating the fabrics with polyethylene glycol, to evaluate the fabric hand of PEG treated wool and wool-like fabrics and to grade up the fabric hand of the treated fabrics by treating with softening agents. Wool and wool-like fabrics were treated with high molecular PEG-8,000 by PDC. The thermal release/storage properties were measured on a DSC. Hand of specimens were evaluated by KES-FB system. The results were as follows; 1. PEG-treated fabrics showed thermal storage and thermal release properties by DSC and the heat contents were generally proportional to the add-ons. 2. PEG-treated fabrics showed higher Koshi and lower Numeri and Sofutosa values due to lower tensile energy and recovery and higher bending rigidity and shear stiffness as the add- ons increased. 3. PEG-treated fabrics showed much lower bending rigidity after softening agents treatment.