• Environmental Analysis Health and Toxicology
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• 제17권2호
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• pp.95-107
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• 2002

This study was designed to investigate the characteristics of atmospheric concentrations of toxic volatile organic compounds (VOCs) in Korea. Target compounds included 1,3-butadiene, aromatics such as BTEX, and a number of carbonyl compounds. In this paper, as the first part of the study, the performance of sampling and analytical methods was evaluated for the measurement of selected VOCs and carbonyl compounds in the ambient air. VOCs were determined by the adsorbent tube sampling and automatic thermal desorption coupled with GC/MSD analysis, while carbonyls by the DNPH-silica cartridge sampling with HPLC analysis. The methodology was investigated with a wide range of performance criteria such as repeatability, linearity. lower detection limits, collection efficiency, thermal conditioning, breakthrough volume and calibration methods using internal standards. In addition, the sampling and analytical methods established in this study were applied to real field samples duplicately collected in various ambient environments. Precisions for the duplicate samples appeared to be comparable with the performance criteria recommended by USEPA TO-17. The overall precision of the sampling and analytical methods was estimated to be within 20 ∼ 30% for major aromatic VOCs such as BTEX, whereas the precision for major carbonyl compounds such as formaldehyde and acetaldehyde was within 10 ∼ 20% for field samples. This study demonstrated that the adsorbent sampling and thermal desorption method can be reliably applied for the measurement of BTEX in ppb levels frequently occurred in common indoor and ambient environments.

• Nuclear Engineering and Technology
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• 제49권4호
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• pp.873-880
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• 2017

To identify the feasibility of disposing of spent activated carbon as a clearance level waste, we performed characterization of radioactive pollution for spent activated carbon through radioisotope analysis; results showed that the C-14 concentrations of about half of the spent activated carbon samples taken from Korean NPPs exceeded the clearance level limit. In this situation, we selected thermal treatment technology to remove C-14 and analyzed the moisture content and thermal characteristics. The results of the moisture content analysis showed that the moisture content of the spent activated carbon is in the range of 1.2-23.9 wt% depending on the operation and storage conditions. The results of TGA indicated that most of the spent activated carbon lost weight in 3 temperature ranges. Through py-GC/MS analysis based on the result of TGA, we found that activated carbon loses weight rapidly with moisture desorption reaching to $100^{\circ}C$ and desorbs various organic and inorganic carbon compounds reaching to $200^{\circ}C$. The result of pyrolysis analysis showed that the experiment of C-14 desorption using thermal treatment technology requires at least 3 steps of heat treatment, including a heat treatment at high temperature over $850^{\circ}C$, in order to reduce the C-14 concentration below the clearance level.

• 한국환경과학회지
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• 제19권5호
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• pp.577-584
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• 2010

The generation of $TiO_2$ nanoparticles by a thermal decomposition of titanium tetraisopropoxide (TTIP) was carried out experimentally using a tubular electric furnace at various synthesis temperatures (700, 900, 1100 and $1300^{\circ}C$) and precursor heating temperatures (80, 95 and $110^{\circ}C$). Effects of degree of crystallinity, surface area and anatase mass fraction of those $TiO_2$ nanoparticles on photocatalytic properties such as decomposition of methylene blue was investigated. Results show that the primary particle diameter obtained from thermal decomposition of TTIP was considerably smaller than the commercial photocatalyst (Degussa, P25). Also, those specific surface areas were more than 134.4 $m^2$/g. Resultant $TiO_2$ nanoparticles showed improved photocatalytic activity compared with Deggusa P25. This is contributed to the higher degree of crystallinity, surface area and anatase mass fraction of $TiO_2$ nanoparticles compared with P25.

• 에너지공학
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• 제23권2호
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• pp.57-61
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• 2014

자동차산업이 해결해야 할 과제로서 석유에너지의 소비증가와, $CO_2$ 배출에의한 지구온난화, 배기가스 배출에 의한 도시부 대기오염 등에 대한 대처가 필요한 시점이다. 이들의 해법으로 시장에서 높은 평가를 받고 있는 전기자동차의 필요성이 대두되고 있다. 본 연구에서는 전기자동차 모터, 배터 리 및 구동모터를 포함한 고전압 핵심부품들의 효율적인 열관리 기술, 배터리 및 구동모터의 열관리 기술 및 개발동향을 알아보고자 한다.

• 한국산업융합학회 논문집
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• 제25권2_2호
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• pp.271-278
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• 2022

The solar energy has been widely used to reduce the fossil fuel and prevent the environmental pollution. The renewable energy including solar heat tends to spread due to carbon neutrality for main country of the world. Targets of solar collector are usually acquisitions of hot water or hot air. Especially, air-heating collector using solar heat is known as the technology for obtaining hot air. This study aims to investigate of characteristics of thermal flow when the hot air by air-heating collector using solar heat flows inside of indoor space. The thermal flow of heating indoor space was simulated using ANSYS-CFX program and thus the behaviors of hot air in indoor space were evaluated with standard k-𝜀 turbulence model. As the results, as the inlet velocity was increased, the behaviors of hot air became simple, and temperature range of 25~75℃ had almost no effect on behavior of flow. As the inlet temperature was increased, the temperature curve of indoor space from bottom to top was changed from linear to quadratic. Furthermore, it was confirmed that inlet velocity as well as inlet temperature also should be considered to heat indoor space equally by air-heating collector using solar heat.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2001년도 춘계학술대회논문집D
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• pp.665-670
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• 2001

The purpose of this study is to develop a new type dryer, which is to proceed mixing and drying of wet-materials at the same time and drying process is carried out in a closed system. In this drying system, thermal contact occurs, when a fluidized zone is created by paddle mechanism. Accordingly, wet-materials is dried in a short time without any damage. Also wet-materials could be dried uniformly to low moisture contents. It is suitable to dry a small quantity of multi-kind materials. And drying process is carried out in a closed system, so as for environmental pollution dust not to be emitted into the atmosphere. Accordingly, it could be used to dry not only food and chemical materials, but also environmental pollution materials.

• 한국수소및신에너지학회논문집
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• 제5권1호
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• pp.25-31
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• 1994

It is very important factor to reduce air pollution from any engines. Some exhaust gases, as $CO_2$, $NO_X$ and $SO_X$, are the products by combustion of hydrocarbon fuel and air. Hydrogen is clean energy to keep our environment out of air pollution. In this study a turbine engine system is theoretically developed which produces pure water only with no exhaust gas by combustion of hydrogen and stoichiometric oxygen. The thermal efficiency of the whole system can be calculated by calculation of each part.

• 한국주거학회:학술대회논문집
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• 한국주거학회 2004년도 추계학술대회 논문집
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• pp.315-318
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• 2004

In recent days, IAQ(Indoor Air Quality) is regarded as one of the most important environmental factors as well as thermal and acoustic comfort. The purpose of this study was to estimate on effect of indoor air pollution from VOCs and formaldehyde emitted by building materials. As the results, we knew that concentration of Toluene, Xylene, Styrene and HCHO emitted from the furnitures and frame material of windows and doors are high emission factors on indoor air pollution.

• 한국수소및신에너지학회논문집
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• 제9권1호
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• pp.1-7
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• 1998

Most of today's energy supply is obtained from fossil fuels. Despite of high energy density, higher store efficiency and long mileage, fossil fuels cause environmental pollution and their reserves are limited. In this study pure hydrogen gas and oxygen gas are burned without the emission of pollution. A gas turbine is used to obtain power. Water is injected into a combustor, which prevents overheating and recovers cooling heat. Excessively supplied water is recirculated. With variation of mass flow rate and equivalence ratio, the affection of water injection rate and the temperature of injected water on efficiency and power are experimented. Injected water gets cooling heat, is expanded from liquid to vapor and raises the thermal efficiency. It is enable to determine the rate of water injection, which makes the maximum power. The increase of temperature of water injection raises the efficiency of the system.

• 동력기계공학회지
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• 제8권1호
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• pp.18-23
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• 2004

The direct injection diesel engine is one of the most efficient thermal engines. For this reason DI diesel engines are widely used for heavy-duty applications. But the world is faced with very serious problems related to the air pollution due to the exhaust emissions of diesel engine. So, that is air pollution related to exhaust gas resulted from explosive combustion should be improved. Exhaust Gas Recirculation(EGR) is a proven method to reduce NOx emissions. In this study, the experiments-were performed at various engine loads while the EGR rates were set from 0% to 20%. The emissions trade-off and combustion of diesel engine are investigated. Hot and cooled EGR are achieved without cooling and with cooling respectively. It was found that the exhaust emissions with the EGR system resulted in a very large reduction in oxides of nitrogen at the expense of higher smoke emissions. Also, the reduction rates of NOx emissions for hot and cooled EGR are similar at load 20%.