• 제목/요약/키워드: thermal ionization

검색결과 104건 처리시간 0.023초

Micro-gap DBD Plasma and Its Applications

  • Zhang, Zhitao;Liu, Cheng;Bai, Mindi;Yang, Bo;Mao, Chengqi
    • 동굴
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    • 제76호
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    • pp.37-42
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    • 2006
  • The Dielectric Barrier Discharge (DBD) is a nonequilibrium gas discharge that is generated in the space between two electrodes, which are separated by an insulating dielectric layer. The dielectric layer can be put on either of the two electrodes or be inserted in the space between two electrodes. If an AC or pulse high voltage is applied to the electrodes that is operated at applied frequency from 50Hz to several MHz and applied voltages from a few to a few tens of kilovolts rms, the breakdown can occur in working gas, resulting in large numbers of micro-discharges across the gap, the gas discharge is the so called DBD. Compared with most other means for nonequilibrium discharges, the main advantage of the DBD is that active species for chemical reaction can be produced at low temperature and atmospheric pressure without the vacuum set up, it also presents many unique physical and chemical process including light, heat, sound and electricity. This has led to a number of important applications such as ozone synthesizing, UV lamp house, CO2 lasers, et al. In recent years, due to its potential applications in plasma chemistry, semiconductor etching, pollution control, nanometer material and large area flat plasma display panels, DBD has received intensive attention from many researchers and is becoming a hot topic in the field of non-thermal plasma.

화재발생시 직류 플래시오버특성에 미치는 연소화염의 영향 (Influence of Combustion Flame on Flashover Characteristics Due to Fire Occurrence)

  • 하장호;김인식;정우영
    • 한국화재소방학회논문지
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    • 제17권2호
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    • pp.25-34
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    • 2003
  • 본 연구에서는 파라핀 연소화염을 사용하여 침대침 및 구대구 전극배치에서 직류전압을 인가하였을 때, 대기압 공기의 플래시오버특성, 인가전압의 크기 및 극성에 따른 화염의 형상변화, 고온 연소화염의 열전리현상 및 플래시오버 특성에 미치는 상대공기밀도의 영향 등에 대해 조사하였다. 실험결과, 연소화염이 존재하면, 대기압 공기의 플래시오버특성은 매우 큰 영향을 받고 있다. 이는 전극의 형태에 따라 코로나풍과 쿨롱력이 작용함으로써 화염의 형상변화와 요동이 일어나기 때문이다. 또한 고온화염으로 인한 주변 공기의 상대공기밀도의 저하로 인해 플래시오버 특성은 더욱 낮아지고 있으며, 연소화염에 대한 열전리의 영향은 크지 않는 것으로 나타났다.

A Correction Method for the Peak Tailing Backgrounds for Accurate Isotope Ratio Measurements of Uranium in Ultra Trace Levels using Thermal Ionization Mass Spectrometry

  • Park, Jong-Ho;Choi, In-Hee;Park, Su-Jin;Lee, Myung-Ho;Song, Kyu-Seok
    • Bulletin of the Korean Chemical Society
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    • 제32권12호
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    • pp.4327-4331
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    • 2011
  • A new method in thermal ionization mass spectrometry (TIMS) was developed to correct peak tailing backgrounds in the isotope ratio measurements of uranium in ultra trace levels for higher accuracy. Two different uranium standard reference materials (U005 and U030) were used to construct databases of signal intensities at mass 234 u and mass 236 u, which correspond to the two uranium minor isotopes, and signal intensity of $^{238}U$. Correlations between peak tailing backgrounds and $^{238}U$ were obtained by least-squares regression on calculated backgrounds at mass 234 u and mass 236 u with respect to the signal intensity of $^{238}U$ followed by separation of the peak tails of the two major isotopes of uranium ($^{235}U$ and $^{238}U$), which enables us to obtain a master equation for peak tailing background correction on all kinds of samples. Verification of the correction method was carried out using U010 and IRMM-040a.

Effect of a Magnetic Field on Thermal Conductivity of Partially Ionized Gases

  • Yun, Hong-Sik
    • 천문학회지
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    • 제9권1호
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    • pp.1-6
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    • 1976
  • The translational and reactive parts of thermal conductivity of a partially ionized solar magneto-plasma gas have been calculated based on Yun and Wyller's formulation (1972) along with Devoto's theory(1968). The computed results are presented as functions of temperature and pressure for given magnetic field strengths. The results of the calculations show that for most photospheric conditions the magnetic field does not play any important role in characterizing thermal properties of the ionized gas. However, when the gas pressure is low(e.g., P<10 dynes/$cm^2)$) the field becomes extremely effective even if its strength is quite small (e.g., B<0.1 gauss). The reactive part of the thermal transport is found to be very important when the gas is undertaking active ionization.

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수분 함유량에 따른 모래의 지중방전 특성 분석 (Analysis of soil discharge characteristics in sand with water content)

  • 이복희;김회구;박건훈;이규선;안창환
    • 한국조명전기설비학회:학술대회논문집
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    • 한국조명전기설비학회 2008년도 춘계학술대회 논문집
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    • pp.436-439
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    • 2008
  • It has been known that the value of soil resistance drops when a high impulse curennt is injected into a grounding electrode. In this paper, impulse generator is used to investigate the dry soil and wet soil characteristics in cylinderical test cell. The impulse resistances and breakdown characteristics were discussed based on its voltage and current traces. As a result, sand resistances are decreased with increasing the applied currents. It was thought that a decrease in resistance of dry sand with increasing current is due to both thermal and ionization processes. On the other hand, in case there is no water presence in the soil, the reduction in resistance as the currents are of dry sand increased is mainly due to the ionization process.

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배터리 시스템 안전을 위한 이온화 연료의 연소 특성 (Combustion Characteristics of Ionized Fuels for Battery System Safety)

  • 고혁주;이의주
    • 한국안전학회지
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    • 제33권1호
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    • pp.22-27
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    • 2018
  • Many electronic devices are powered by various rechargeable batteries such as lithium-ion recently, and occasionally the batteries undergo thermal runaway and cause fire, explosion, and other hazards. If a battery fire should occur in an electronic device of vehicle and aircraft cabin, it is important to quickly extinguish the fire and cool the batteries to minimize safety risks. Attempts to minimize these risks have been carried out by many researchers but the results have been still unsatisfied. Because most rechargeable batteries are operated on the ion state during charge and discharge of electricity and the combustion of ion state has big difference with normal combustion. Here we focused on the effect of ions including an electron during combustion process. The effects of an ionized fuel on the flame stability and the combustion products were experimentally investigated in the propane jet diffusion flames. The burner used in this experiment consisted of 7.5 mm diameter tube for fuel and the propane was ionized with th ionizer (SUNJE, SPN-11). The results show that toe overall flame stability and shape such as flame length has no significant difference even in the higher ion concentration. However the fuel ionization affects to the pollutant emissions such as NOx and soot. NOx and CO emissions measured in post flame region decreased by fuel ionization, especially high fuel velocity, i.e. high ion density. TGA analysis and morphology of soot by TEM indicates that the fuel ionization makes soot to be matured.

Characterization of Thermal Degradation of Polytrimethylene Terephthalate by MALDI-TOF Mass Spectrometry

  • Jang, Sung-Woo;Yang, Eun-Kyung;Jin, Sung-Il;Cho, Young-Dal;Choe, Eun-Kyung;Park, Chan-Ryang
    • Bulletin of the Korean Chemical Society
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    • 제33권3호
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    • pp.833-838
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    • 2012
  • The thermal degradation products of polytrimethylene terephthalate (PTT) obtained by heating the sample in the temperature range of $250-360^{\circ}C$ under non-oxidative conditions was characterized using MALDI-TOF (matrix assisted laser desorption/ionization) mass spectrometry. The structures of the degradation products were determined and the relative compositions were estimated. The MALDI-TOF mass spectra of the thermally degraded PTT sample showed three main series of oligomer products with different end groups, which were carboxyl/carboxyl, carboxyl/allyl, and allyl/allyl. In contrast to the thermal degradation of polyethylene terephthalate (PET), the oligomers containing terephthalic anhydrides were not detected, whereas the formation of oligomers containing the unsaturated allyl ester group was confirmed by mass assignment. From these results, it was concluded that the thermal degradation of PTT proceeds exclusively through the ${\beta}$-CH hydrogen transfer mechanism, which is in accordance with the proposed reaction mechanism for the thermal degradation of polybutylene terephthalate (PBT).

Formation of star clusters by cloud-cloud collision

  • Han, Daniel;Kimm, Taysun
    • 천문학회보
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    • 제44권2호
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    • pp.68.3-68.3
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    • 2019
  • We present the preliminary results on the formation of star clusters by cloud-cloud collision. For this purpose, we perform sub-parsec scale, radiation-hydrodynamic simulations of giant molecular clouds using a sink particle algorithm. The simulations include photo-ionization, direct radiation pressure, and non-thermal radiation pressure from infrared and Lyman alpha photons. We confirm that radiation feedback from massive stars suppresses accretion onto sink particles. We examine the collision-induced star formation and discuss the possibility on the formation of a globular cluster.

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Sn-complexes를 이용한 OLED의 발광 특성 향상에 관한 연구 (Improvement of Luminance Properties of Blue OLEO using $SnDP(HPB)_2$)

  • 김동은;최규채;권영수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 춘계학술대회 논문집 센서 박막재료연구회 및 광주 전남지부
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    • pp.121-122
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    • 2008
  • Blue emitting materials have been explored by various researchers. However, blue-emitting materials with high luminous efficiency, good color purity, and thermal stability are still much desired. In this study, we synthesized a new blue luminescent material, $SnDP(HPB)_2$ which is low molecular compound and thermal stability. The PL spectrum of $SnDP(HPB)_2$ was observed blue at the wavelength of 447nm. The ionization potential(IP) and the electron affinity(EA) of $SnDP(HPB)_2$ was measured to be 6.7 eV and 3.0 eV, respectively. The fundamental structure of the OLED was ITO/NPB/$SnDP(HPB)_2/Alq_3$/LiF/Al. As a Result, we obtained to enhance the performance of blue OLED.

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