• Macromolecular Research
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• 제12권5호
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• pp.490-492
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• 2004

We report a new method using a heating medium for the thermal decomposition of epoxy resin (EP) at temperatures ranging from 50 to 200$^{\circ}C$. EP decomposition also occurred below 50$^{\circ}C$ during a 6-day period to generate bisphenol A (BPA) at concentrations as high as 5 ppm. When polyethylene glycol was used as a heating medium, we determined the kinetics of the EP decomposition at low temperature. We determined the apparent activation energy of the overall decomposition to be 40.8 kJ/mol and the frequency factor to be 2.3${\times}$10$^3$ by monitoring the rate of BPA formation. Thus, EP is clearly unstable upon the application of heat.

• 공업화학
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• 제28권2호
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• pp.214-220
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• 2017

결정화/응집(drowning-out/agglomeration, D/A) 공정을 이용하여 평균 입도 $550{\mu}m$인 구형 Al/RDX/AP 에너지 복합체를 제조하였다. SEM과 X-선 분광분석을 이용해 복합체의 표면 구조와 Al의 분포를 분석하였다. 열분석 결과 D/A 공정에 의해 제조된 Al/RDX/AP 복합체는 물리적 혼합에 의한 복합체와 비교하여 분해 개시 온도가 약 $50^{\circ}C$ 정도 낮아졌으며, 동시에 활성화 에너지의 증가에 의해 열적 안정성도 상승하는 것으로 확인되었다. AP의 1차 분해 구간에서는 물리적 혼합과 D/A 공정에 의한 복합체 모두 Prout-Tompkins 모델에 의해 잘 모사되었다. 그러나 AP의 2차 분해 구간에서는 물리적 혼합에 의해 제조된 복합체는 zero-order 모델로 해석되는 반면, D/A 공정에 의해 제조된 복합체는 contracting volume 모델로 해석됨을 알 수 있었다.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2017년도 제48회 춘계학술대회논문집
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• pp.521-528
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• 2017

본 논문에서는 고체 로켓 추진기관에서 내열재 및 단열재로 사용되는 실리카/페놀릭 복합재료의 열 반응을 고려한 열전도 수치해석을 수행하였다. 고체 로켓 추진기관의 연소 중 실리카/페놀릭의 삭마와 열분해 과정을 고려한 열전도 해석을 위해 1차원 유한차분법을 이용하여 계산을 수행하였다. 노즐벽에서의 경계조건은 대류열전달계수를 고려하였으며, 이는 적분방정식을 이용하여 계산하였다. 삭마두께 및 숯깊이 해석결과는 목삽입재 평가 모터인 TPEM-10을 이용한 시험결과와 비교분석하였으며, 잘 일치하는 것을 확인할 수 있었다.

• 한국추진공학회지
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• 제22권4호
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• pp.76-84
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• 2018

본 논문에서는 고체 로켓 추진기관에서 내열재 및 단열재로 사용되는 실리카/페놀릭 복합재료의 열반응을 고려한 열전도 수치해석을 수행하였다. 고체 로켓 추진기관의 연소 중 실리카/페놀릭의 삭마와 열분해 과정을 고려한 열전도 해석을 위해 1차원 유한차분법을 이용하여 계산을 수행하였다. 노즐벽에서의 경계조건은 대류열전달계수를 고려하였으며, 이는 적분방정식을 이용하여 계산하였다. 삭마두께 및 숯깊이 해석결과는 목삽입재 평가 모터인 TPEM-10을 이용한 시험결과와 비교분석하였으며, 잘 일치하는 것을 확인할 수 있었다.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2009년도 제33회 추계학술대회논문집
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• pp.177-180
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• 2009

본 연구에서는 HTPE 추진제 원료 및 HTPE 둔감 추진제 조성 2종에 대하여 DSC와 TGA를 사용하여 열분해 특성을 고찰하였다. AN이 포함된 HTPE 002는 약 $125^{\circ}C$에서 AN의 상전이 과정($II{\rightarrow}I$)을 거친 후, 약 $200^{\circ}C$범위까지 BuNENA와 AN이 함께 발열특성을 가지고 분해됨을 알 수 있었다. 추진제 HTPE 001과 HTPE 002의 열폭발에 대한 임계온도, $T_c$,를 Semenov의 열폭발 이론과 몇 가지 가열속도에서 측정된 비등온 곡선으로부터 계산되었고, 임계온도 계산에 사용된 열분해에 대한 활성화 에너지는 Kissinger방법으로 측정하였다.

• 한국분무공학회지
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• 제25권3호
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• pp.132-138
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• 2020

N₂O is hazardous atmosphere pollution matter which can damage the ozone layer and cause green house effect. There are many other nitrogen oxide emission control but N₂O has no its particular method. Preventing further environmental pollution and global warming, it is essential to control N₂O emission from industrial machines. In this study, the thermal decomposition experiment of N₂O gas mixture is conducted by using cylindrical reactor to figure out N₂O reduction and NO formation. And CHEMKIN calculation is conducted to figure out reaction rate and mechanism. Residence time of the N₂O gas in the reactor is set as experimental variable to imitate real SNCR system. As a result, most of the nitrogen components are converted into N2. Reaction rate of the N₂O gas decreases with N₂O emitted concentration. At 800℃ and 900℃, N₂O reduction variance and NO concentration are increased with residence time and temperature. However, at 1000℃, N₂O reduction variance and NO concentration are deceased in 40s due to forward reaction rate diminished and reverse reaction rate appeared.

• 한국수소및신에너지학회논문집
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• 제28권1호
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• pp.70-76
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• 2017

To synthesize copper nanoparticle a thermal decomposition was adopted. And to solve the problem of surface oxidation of the synthesized copper powder an electroless Ag plating method was used. The size and shape of synthesized Cu nanoparticle were affected by the size of copper oxalate used as a precursor, reaction solvent, reaction temperature and amount of reducing agent. Especially reaction solvent is dominant factor to control shape of Cu nano-particle which can have the shapes of sphere, polygon and rod. In case of glycerol, it produced spherical shape of about 500 nm in size. Poly ethylene produced uniform polygonal shape in about 700 nm and ethylene glycol produced both of polygon and rod having size range between 500 and 1500 nm. The silver coated copper powder showed a high electrical conductivity.

• 공업화학
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• 제32권6호
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• pp.706-710
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• 2021

In the current research, thermal and catalytic thermogravimetric (TG) analysis of polyethylene terephthalate (PET) over natural zeolite (NZ), olivine, bentonite, HZSM-5, and HAl-MCM-41 were investigated using a TG analyzer and model-free kinetic analysis. Catalytic TG analysis of PET was carried out at multi-heating rates, 10, 20, 30, and 40 ℃/min, under nitrogen atmosphere. Apparent activation energy (Ea) values for the thermal and catalytic pyrolysis of PET were calculated using Flynn-Wall-Ozawa method. Although natural catalysts, NZ, olivine, and bentonite, could not lead the higher PET decomposition efficiency than synthetic zeolites, HZSM-5 and HAl-MCM-41, maximum decomposition temperatures on the differential TG (DTG) curves for the catalytic pyrolysis of PET, 436 ℃ over olivine, 435 ℃ over bentonite, and 434 ℃ over NZ, at 10 ℃/min, were definitely lower than non-catalytic pyrolysis. Calculated Ea values for the catalytic pyrolysis of PET over natural catalysts, 177 kJ/mol over olivine, 168 kJ/mol over bentonite, and 171 kJ/mol over NZ, were also not lower than those over synthetic zeolites, however, those were also much lower than the thermal decomposition, suggesting their feasibility as the proper and cost-effective catalysts on the pyrolysis of PET.

• 한국응용과학기술학회지
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• 제26권2호
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• pp.205-212
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• 2009

Solution copolymerization of Styrene(St.) with 2-Hydroxypropylacrylate(2-HPA) was carried out with Benzoylperoxide(BPO) as an initiator in toluene at $80^{\circ}C$ in a batch reactor. Reaction volume and reaction time were 0.3 liters, 8 hours respectively. The time to reach steady state was about the six time. The monomer reactivity ratios, $r_1$(St.) and $r_2$(2-HPA) were determined by both the Kelen-Tudos method and the Fineman-Ross method ; $r_1$(St.)=0.376(0.330), $r_2$(2-HPA)=0.408(0.778). The activation energy of thermal decomposition was in the range of $33{\sim}55kcal/mol$.

• 대한화학회지
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• 제12권4호
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• pp.146-149
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• 1968

A new chelate compound, tris(8-bydroxyquinolino)molybdenum(III), [$Mo(C_9H_6ON)_3$], has been prepared by the method of electrolytic reduction of the acidic molybdate solution. Thermal decomposition products of the chelate has been studied by DTA and TGA method. It is concluded that the decomposition product is a yellowish green colored bis(8-hydroxyquinolino)dioxo molybdenum(VI), [$MoO_2(C_9H_6ON)_2$].