• 콘크리트학회논문집
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• 제23권3호
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• pp.377-384
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• 2011

화재에 취약한 고강도 콘크리트 구조물의 화재 피해를 보다 정확하게 예측하기 위해서는 다양한 구조물의 설계 조건과 가열 조건 하에서 열적 특성을 고려하는 연구가 필요하다. 따라서 이 연구에서는 단면 크기, 피복 두께, 철근 배근을 다르게 한 고강도 콘크리트 기둥을 제작하여 다른 가열 조건하에서 가열하였을 때 발생하는 내부 온도 분포와 폭렬을 관찰하였다. 내부 온도 분포는 콘크리트 타설 전 설치한 열전대를 통해서 측정하였으며 가열 전후에 측정한 콘크리트 기둥 실험체의 무게 손실률과 단면 손실률을 통해서 폭렬을 수치화 하였다. 가열 실험은 비재하 상태에서 ISO 834 화재 곡선을 따라 가열하는 실험과 화재 시뮬레이션을 통해 측정한 온도-시간 곡선을 따라 가열하는 실험의 두 가지로 나누어 수행하였다. 고강도 콘크리트 기둥은 일반적으로 고온에서 폭렬이 발생하여 내부 온도의 급격한 증가와 단면 손실을 나타내었으며, 설계 변수에 따라서는 단면이 클수록, 피복 두께가 작을수록 내부 온도 분포와 단면 손실률이 높게 나타났다. 또한 철근비가 동일한 상태에서 철근 배근을 다르게 하였을 때, 단면이 작은 철근을 여러 개 배치하는 것이 단면이 큰 철근을 적게 배치하는 것 보다 높은 온도 분포와 단면 손실을 보였다. 이 연구를 통하여 화재로 인한 고강도 콘크리트 구조물의 열적 변화를 정확하게 파악함으로써, 내화 안전성을 평가하고 현재 적용되고 있는 내화 성능 관리 기준을 보다 효율적이고 안전하게 정립할 수 있도록 하는데 유용하게 활용될 수 있을 것이라고 판단된다.

• Journal of Magnetics
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• 제3권1호
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• pp.4-8
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• 1998

Two different compositions of melt spun magnetic alloys, $ Nd_4Fe_{80}B_{16} and Nd_4Fe_{76}Co}\_3Hf_{0.5}Ga_{0.5}B_{16},$ were characterized in terms of magnetic properties and thermal behaviors. It was found that the addition of Hf and Ga effectively slow down the crystallization rate of the nanocomposite $ Nd_2Fe_{14}B/Fe_3B$ magnet. Coercivity(iHc) changes only slightly with varying the post annealing conditions confirming that iHc is not a sensitive magnetic quantity as a function of grain size and exchange coupled interaction. The experimentally observed behaviors of Mr and Hc do not vary monotonously with in-creasing grain size which is not in agreement with the numerically calculated result near the critical grain size (dc). The plot of the grain size dependence for the remanence and coercivity in isotrop!c nanocomposite magnets has been revised in this study. The maxium energy product, $(B, H)_{max}$ =15.34 MGOe, and a reduced remanence, Mr/Ms=0.84 were obtained, respectively.

• Bulletin of the Korean Chemical Society
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• 제32권4호
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• pp.1253-1257
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• 2011

The surface structures, adsorption conditions, and thermal desorption behaviors of cyclopentanethiol (CPT) self-assembled monolayers (SAMs) on Au(111) were investigated by scanning tunneling microscopy (STM), X-ray photoelectron spectroscopy (XPS), and thermal desorption spectroscopy (TDS). STM imaging revealed that although the adsorption of CPT on Au(111) at room temperature generates disordered SAMs, CPT molecules at $50^{\circ}C$ formed well-ordered SAMs with a $(2{\surd}3{\times}{\surd}5)R41^{\circ}$ packing structure. XPS measurements showed that CPT SAMs at room temperature were formed via chemical reactions between the sulfur atoms and gold surfaces. TDS measurements showed two dominant TD peaks for the decomposed fragments ($C_5H_9^+$, m/e = 69) generated via C-S bond cleavage and the parent molecular species ($C_5H_9SH^+$, m/e = 102) derived from a recombination of the chemisorbed thiolates and hydrogen atoms near 440 K. Interestingly, dimerization of sulfur atoms in n-alkanethiol SAMs usually occurs during thermal desorption and the same reaction did not happen for CPT SAMs, which may be due to the steric hindrance of cyclic rings of the CPT molecules. In this study, we demonstrated that the alicyclic ring of organic thiols strongly affected the surface structure and thermal desorption behavior of SAMs, thus providing a good method for controlling chemical and physical properties of organic thiol SAMs.

• Bulletin of the Korean Chemical Society
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• 제31권10호
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• pp.2867-2872
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• 2010

Two new energetic organic alkali metal salts, 1,1-diamino-2,2-dinitroethylene rubidium salt [Rb(FOX-7)${\cdot}H_2O$] and 1,1-diamino-2,2-dinitroethylene cesium salt [Cs(FOX-7)${\cdot}H_2O$], were synthesized by reacting of 1,1-diamino-2,2-dinitroethylene (FOX-7) and rubidium chloride or cesium chloride in alkali methanol aqueous solution, respectively. The thermal behaviors of Rb(FOX-7)${\cdot}H_2O$ and Cs(FOX-7)${\cdot}H_2O$ were studied with DSC and TG methods. The critical temperatures of thermal explosion of the two compounds are 216.22 and $223.73^{\circ}C$, respectively. Specific heat capacities of the two compounds were determined with a micro-DSC method, and the molar heat capacities are 217.46 and $199.47\;J\;mol^{-1}\;K^{-1}$ at 298.15 K, respectively. The adiabatic times-to-explosion were also calculated to be a certain value of 5.81 - 6.36 s for Rb(FOX-7)${\cdot}H_2O$, and 9.92 - 10.54 s for Cs(FOX-7)${\cdot}H_2O$. After FOX-7 becoming alkali metal salts, thermal decomposition temperatures of the compounds heighten with the rise of element period, but thermal decomposition processes become intense.

• Tribology and Lubricants
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• 제14권4호
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• pp.29-36
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• 1998

The thermal characteristics of a disk such as temperature distribution, thermal behaviors and thermal stress during a braking operation has been analyzed for a high-speed brake using the finite element method. The maximum stress for a pad loaded against a disk was occurred at the trailing and leading edges of the disk pad at the underlayer-backplate interface. The FEM results indicate that the thermal characteristics of the spot type pad shows good performance compared with those of the flat type pad. Thus, the spot type pad in brake system may be recommended for the high-speed train system.

• 대한기계학회논문집
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• 제18권9호
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• pp.2486-2493
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• 1994

Transient heat transfer characteristics in th radiant heating panel with heat diffusion fin were predicted by numerical analysis. Thermal behaviors of panel, such as temperature distributions in panel and convective and radiative heat fluxes in panel surface with advance of time, were obtained for several important parameters. The performance and thermal comfort of heating panel were studied and compared for various design conditions, such as pipe pitch, area ratio and thermal conductivity of optimal design of the new heating panels with heat diffusion fin. It was concluded that the efficient area ratio of heat diffusion fin is about 0.5, and the greater the thermal conductivity of fin is, the better the performance of panel is.

• 한국주거학회논문집
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• 제19권1호
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• pp.89-96
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• 2008

This study measured the thermal environment and residents' control behaviors of cooing according to 3 groups of household type-families with preschool children, families of middle age and families of senior. The object of this study are to fmd the difference of the actual condition of indoor thermal environment and cooling control behavior by age or household type and to develop user oriented climate control system. The results were summarized as follows. When the age of members at household is younger, the indoor mean temperature and temperature that people turned off the air conditioner became lower. These different indoor thermal environment of each group means that younger generation is familiar with cooler from their early age and these early uses of cooler made them prefer cooler condition than family of senior. Therefore, this results show that different indoor thermal environment is influenced by factors such as household type and metabolism difference and so on.

• International Journal of Air-Conditioning and Refrigeration
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• 제6권
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• pp.1-13
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• 1998

The basic heat transfer process that occurs in a building can best be illustrated by an electrical circuit network. Present paper reports the dynamic simulation of annual energy consumption in an office building by the thermal resistance capacitance network method. Unsteady thermal behaviors and annual energy consumption in an office building were examined in detail by solving the simultaneous circuit equations of thermal network. The results are used to evaluate the accuracy of the modified BIN method for the energy consumption analysis of a large building. Present thermal resistance-capacitance method predicts annual energy consumption of an office building with the same accuracy as that of response factor method. However, the modified BIN method gives 15% lower annual heating load and 25% lower cooling load than those from the present method. Equipment annual energy consumptions for fan, boiler and chiller in the HVAC system are also calculated for various control systems as CAV, VAV, FCU+VAV and FCU+CAV. FCU+CAV system appears to consume minimum annual energy among them.

• 한국공작기계학회:학술대회논문집
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• 한국공작기계학회 2002년도 추계학술대회 논문집
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• pp.36-40
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• 2002

The development of feed drive system with high speed and accuracy has been a major issue in the machine tool industry. Linear motors can be used as the efficient tool to achieve fast feed mechanism and high accuracy. However. a high speed feed drive system with linear motors can generate heat problems such as the variation of temperature distribution and the resultant thermal stress. In this paper, the important heat sources and the resultant thermal errors are presented. The thermal deformation characteristics of the machine tool with linear motors were identified, which are thermal expansion of linear scale, shrinkage, expansion and bending in the machine tool structure.

• 한국초전도ㆍ저온공학회논문지
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• 제12권3호
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• pp.1-6
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• 2010

Since the fiber reinforced polymeric (FRP) composites are considered in next generation of space transportation systems, reliable thermal expansion properties should be well provided for structural design of composite materials. To obtain accurate mechanical behaviors at a cryogenic temperature, precise strain measurement and calibration must be provided. In this work, apparent strains (or thermal output) of temperature self-compensated strain gages were deliberately investigated for epoxy, CTBN modified epoxy and carbon fabric composite system from room temperature to liquid nitrogen temperature. Also, fourth-order thermal output curves were presented for the further calibration. The results showed that the thermal output is heavily dependent on test materials and a large amount of apparent strains were observed for the polymer resins.