• Title/Summary/Keyword: thermal anisotropy

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Low Thermal Expansion of $Al_2TiO_5$ Ceramics Prepared from Electrofused Powders

  • Kim, Ik-Jin;Kwak, Hyo-Sup
    • The Korean Journal of Ceramics
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    • v.5 no.4
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    • pp.414-418
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    • 1999
  • The synthesis of polycrystalline $Al_2TiO_5$ ceramics with low thermal expansion by fusion in an electric arc furnance was investigated. The thermal expansion curves of $Al_2TiO_5$ ceramics were lowered because of microcracks caused by the strong thermal expansion anisotropy of the crystal axes and were accompanied by hysteresis curves. These phenomena are explained by the opening and closing of microcracks. The difference in microcracking temperatures of dilatometric cooling curves in the range of 400~$620^{\circ}C$ is caused by the difference in sintering temperature, grain size and stabilization status.

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Anisotropy Angle Dependence of Interlayer Exchange Coupling of Perpendicular Magnetic [CoFe/Pt/CoFe]/IrMn Multilayers ([CoFe/Pt/CoFe]/IrMn 다층박막의 수직자기 이방성 각도에 따른 상호교환결합력 특성)

  • Lee, Sang-Suk;Choi, Jong-Gu;Hwang, Do-Guwn;Rhee, Jang-Roh
    • Journal of the Korean Magnetics Society
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    • v.18 no.6
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    • pp.232-236
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    • 2008
  • Dependence of interlayer exchange coupling on antiferromagnetic IrMn thickness, thermal stability, and parallel anisotropy angle in perpendicular anisotropy [CoFe/Pt/CoFe]/IrMn multilayers was investigated. The magnetic property of [CoFe($10{\AA}$)/Pt($8{\AA}$)/CoFe($10{\AA}$)] induced by antiferromagnetic ordering of IrMn layer was maintained a stable perpendicular anisotropy up to $250^{\circ}C$ and from $7{\AA}$ to $160{\AA}$ of IrMn thickness. The value of interlayer exchange coupling of [CoFe/Pt/CoFe]/IrMn multilayers with perpendicular anisotropy increased to 1.5 times at anisotropy angle of $60^{\circ}$ more than of $0^{\circ}$. On the other side, the interlayer exchange coupling at anisotropy angle of $90^{\circ}$ was $\infty$ Oe, it was likely diverted to a parallel shape magnetization.

Thin Film Growth and Evaluation Method for Conventional Co-Cr Based Perpendicular Magnetic Recording Media: Problems and New Solutions

  • Saito, Shin;Hoshi, Fumikazu;Hasegawa, Daiji;Takahashi, Migaku
    • Journal of Magnetics
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    • v.7 no.3
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    • pp.115-125
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    • 2002
  • We proposed a novel method to evaluate the magnetic properties of the initial layer and the columnar structure separately for CoCr-based perpendicular recording media. We show that the thickness of the initial layer and the intrinsic magnetocrystalline anisotropy of columnar structure can be quantitatively evaluated using the plotted product of perpendicular anisotropy to magnetic film thickness versus magnetic film thickness ($K_{u{\bot}}^{ex{p.}}$ $\times$ d$_{mag.}$ vs. d$_{mag.}$ plot). Based on the analyses, it is found that: (1) compared with CoCrPtTa media, CoCrPtB media have relatively thin initial layer, and have fine grains with homogeneous columnar structure with c-plane crystallographic orientation; (2) CoCrPtB media can be grown epitaxially on Ru or CoCr/C intermediate layer, and as the result, the magnetic properties of the media within thin thickness region of d$_{mag.}$ $\leq$ 20 nm is significantly improved; (3) the key issue of material investigation for CoCr-based perpendicular recording media will be focused on how to fabricate c-plane-oriented columnar grains well isolated with nonmagnetic substance in epitaxial-growth media, while maintaining the thermal stability of the media.

A Study on the Microstructural Control of LAS Ceramics (I): $Li_O$.$4B_2O_3$ Frit Addition on the Microstructure and Thermal Expansion of $\beta$-Eucryptite Ceramics (LAS계 내열충격성 재료의 미세구조 제어 (I): $Li_O$.$4B_2O_3$ 프릿트 첨가가 $\beta$-Eucryptite 세라믹스의 미세구조 및 열팽창특성에 미치는 영향)

  • 박정현;김현민;이화선
    • Journal of the Korean Ceramic Society
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    • v.28 no.5
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    • pp.415-421
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    • 1991
  • Influence of Li2O.4B2O3 frit addition on the microstructure and thermal expansion properties of $\beta$-eucryptite ceramics was studied. With 1.0~10.0wt% frit addition, sintering temperature range was enlarged and densified body was obtained. Thermal expansion was increased from -6.67$\times$10-6 $^{\circ}C$-1 of pure sintered body to 1.03$\times$10-6$^{\circ}C$-1 of 6 wt% added body, but this increasement was accompanied by inhibition of thermal expansion anisotropy, so that improved microcracking property.

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Evaluation of mechanical and thermal properties of insulation materials for HTS power devices at liquid nitrogen temperature

  • Shin, Hyung-Seop;Diaz, Mark Angelo
    • Progress in Superconductivity and Cryogenics
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    • v.19 no.2
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    • pp.53-57
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    • 2017
  • In superconducting power devices including power cables in which high temperature superconducting (HTS) tapes are utilized, a reliable electrical insulation should be achieved for its maximum performance. For an efficient design of HTS superconducting devices, a comparative evaluation of the mechanical and thermal propperties for various insulation materials at cryogenic temperatures is required. Especially, in the process of the property evaluation of the sheet-shaped insulation materials, anisotropy according to the machining direction should be considered because the mechanical and thermal properties are significantly influenced by the sample orientation. In this study, the cryogenic thermal and mechanical properties of various insulation material sheets such as PPLP, Cryoflex, Teflon, and Kapton were determined considering sample orientation. All samples tested at cryogenic temperature showed significantly higher tensile strength as compared with that of room temperature. The ultimate tensile strength at both temperature conditions significantly depended upon the sample orientation. The thermal properties of the insulation materials exhibited a slight difference among samples depending on the orientation: for the PPLP and Cryoflex, the CD orientation showed larger thermal contraction up to 77 K as compared to the MD one. MD samples in PPLP and Cryoflex showed a lower CTE and thermal contraction which made it more promising as an insulation material due to its comparable CTE with HTS CC tapes.

The Effect of Manganese Substituted M-type Hexagonal Ba-ferrite

  • Lee, In-Kyu;Sur, Jung-Chul;Shim, In-Bo;Kim, Chul-Sung
    • Journal of Magnetics
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    • v.14 no.2
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    • pp.93-96
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    • 2009
  • The Mn-substituted M-type Ba-ferrite ($BaFe_{12-x}Mn_xO_{19}$; x = 0, 2, 4, 6) powders were prepared by the HTTD (High Temperature Thermal Decomposition) method. The effect of $Mn^{3+}$ Jahn-Teller ions on the magnetic properties has been studied by x-ray diffraction, vibrating sample magnetometry, and $M{\ddot{o}}ssbauer$ spectroscopy. With increasing Mn substitution, the lattice parameter $a_0$ increases while $c_0$ decreases. The magnetocrystalline anisotropy constants ($K_1$) were determined as 2.9, 2.2, 1.8, and, $1.3{\times}10^6\;erg/cm^3$ for x = 0, 2, 4, and 6, respectively, by the LAS method. We have studied the change of cation distribution by $M{\ddot{o}}ssbauer$ spectroscopy which is closely related to $K_1$.

Wave propagation in fibre-reinforced anisotropic thermoelastic medium subjected to gravity field

  • Abd-Alla, A.M.;Abo-Dahab, S.M.;Bayones, F.S.
    • Structural Engineering and Mechanics
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    • v.53 no.2
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    • pp.277-296
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    • 2015
  • The objective of this paper is to investigate the surface waves in fibre-reinforced anisotropic thermoelastic medium subjected to gravity field. The theory of generalized surface waves has firstly developed and then it has been employed to investigate particular cases of waves, viz., Stoneley waves, Rayleigh waves and Love waves. The analytical expressions for displacement components, force stress and temperature distribution are obtained in the physical domain by using the harmonic vibrations. The wave velocity equations have been obtained in different cases. The numerical results are given and presented graphically in Green-Lindsay and Lord-Shulman theory of thermoelasticity. Comparison was made with the results obtained in the presence and absence of gravity, anisotropy, relaxation times and parameters for fibrereinforced of the material medium. The results indicate that the effect of gravity, anisotropy, relaxation times and parameters for fibre-reinforced of the material medium are very pronounced.

Thermal, Mechanical Properties of LAS with the Addition of Mullite ($Li_2O-Al_2O_3-SiO_2$계 소지의 Mullite 첨가에 의한 열적, 기계적 특성에 관한 연구)

  • 최도문;유재근;이응상
    • Journal of the Korean Ceramic Society
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    • v.30 no.5
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    • pp.381-388
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    • 1993
  • Due to the anisotropy of thermal expansion, LAS system which has low thermal expansion property is hard to obtain a dense sintered body. Therefore, the thermal expansion coefficient and the mechanical strength were decreased. In this study, mullite, which has good mechanical properties in high temperature and comparatively low thmeral expansion coefficient, was taken as a additive in LAS system. And then, sintering, thermal, and mechanical properties were investigated. The results are follows; When mullite is added in eucryptite composition (Li2O.Al2O3.2SiO2) of LAS system, the creation of liquid phase results in the densification of sintered body and the specimen sintered at 136$0^{\circ}C$ for 2 hours shows optimum sintering condition. With the addition of mullite in eucryptite composition, mechanical strength is increased by the control of grain growth. Especially, flexual strength of EM0 specimen was about double value than the basic composition. Thermal expansion coefficients of EM0 and EM15 specimens sintered at 136$0^{\circ}C$ were -8.23$\times$10-6/$^{\circ}C$ and -4.90$\times$10-6/$^{\circ}C$ in the temperature range of RT.~80$0^{\circ}C$. As the mullite content are increased, negative thermal expansion ratios are decreased.

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Thermal Shock Resistance of $Al_2$TiO$_5$ Ceramics Prepared from Electrofused Powders (전기용융 분말로부터 합성된 $Al_2$TiO$_5$ Ceramics의 열충격 저항성)

  • ;Constantin Zografou
    • Journal of the Korean Ceramic Society
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    • v.35 no.10
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    • pp.1061-1069
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    • 1998
  • The thermal instability of Al2TiO5 Ceramics was contrlled by solid solution with MgO SiO2 and ZrO2 through electrofusion in an arc furnace. The thermal expansion properties of Al2TiO5 composites show the hysteresis due to the strong anisotropy of The crystal axes of these material. These phenomena are ex-plained by the opening and closing of microcracks. The difference in microcracking temperatures e.g 587.6(ATG2), 405.9(ATG3) and 519.7$^{\circ}C$(ATG4) is caused by the difference in grain size and stabilizer type. The thermal shock behaviour under cyclic conditions between 750-1400-75$0^{\circ}C$ show no change in mi-crostructure and phase assemblage for all three stabilized specimens. After the thermal loading test at 110$0^{\circ}C$ for 100hrs. ATG1 and ATG2 materials decomposes completely to its components corundum and ru-tile in both cases. However with approximatelly 20% retention of the Al2TiO5 Thus in order to prevent decomposition of the stabilized material in the critical temperature range 800-130$0^{\circ}C$ it must be traversed within a short period of time.

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