• Proceedings of the Korean Vacuum Society Conference
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• 2012.08a
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• pp.219-219
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• 2012

The formation and thermal desorption behaviors of octanethiol (OT) SAMs on single crystalline Au (111) and polycrystalline Au, Ag, and Cu substrates were examined by X-ray photoelectron microscopy (XPS), thermal desorption spectroscopy (TDS), and contact angle (CA) measurements. XPS and CA measurements revealed that the adsorption of octanethiol (OT) molecules on these metals led to the formation of chemisorbed self-assembled monolayers (SAMs). Three main desorption fragments for dioctyl disulfide (C8SSC8+, dimer), octanethiolate (C8S+), and octanethiol (C8SH+) were monitored using TDS to understand the effects of surface morphology and the nature of metal substrates on the thermal desorption behavior of alkanethiols. TDS measurements showed that a sharp dimer peak with a very strong intensity on single crystalline Au (111) surface was dominantly observed at 370 K, whereas a broad peak on the polycrystalline Au surface was observed at 405 K. On the other hand, desorption behaviors of octanethiolates and octanethiols were quite similar. We concluded that substrate morphology strongly affects the dimerization process of alkanethiolates on Au surfaces. We also found that desorption intensity of the dimer is in the order of Au＞＞Ag＞Cu, suggesting that the dimerization process occurs efficiently when the sulfur-metal bond has a more covalent character (Au) rather than an ionic character (Ag and Cu).

• The Research Journal of the Costume Culture
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• v.12 no.2
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• pp.279-289
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• 2004

This study was conducted to compare the hunting reaction of finger in the cold water. Finger skin temperature is measured the left middle finger tip immersion in cold water of 5℃ for 30 minutes and measurements were made on finger skin temperature(Ts), thermal comfort, and cold pain sensations during the experiment at the spring (March) and Winter(December). Results were follows. Is before immersion was at the highest in spring and at the lowest in winter and was closely related to the indoor temperature Ts during immersion and recovery. Mean of finger skin temperature(MST), the skin temperature at the first rise(TTR) and amplitude of finger skin temperature reaction during immersion(AT) were significant higher in spring than that in winter(P＜.01). The lowest skin temperature(LST) during the cold water immersion were significantly higher in spring than that in winter (P＜.05). The frequency of the appearance of cold-Induced vase dilation(CIVD) was higher in spring than that in winter. However, time for the first temperature(TTR) and recovery time(RT) had no seasonal variation. In addition, cold pains during immersion were felt more strongly in spring than in winter. Local thermal sensation, finger thermal sensation in dynamic state during hand immersion was different from that in the Winter. Spring was slowly cold in cold water immersion.

• Proceedings of the Materials Research Society of Korea Conference
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• 2011.10a
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• pp.28.2-28.2
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• 2011

The selective catalytic reduction (SCR) of NOx by $NH_3$ is well known as one of the most convenient, efficient, and economical method to prevent NOx emission in flue gas from stationary sources. The degradation of the reactivity is the obstacle for its real application, since high concentrations of sulfur dioxide and thermal factor would deactivate the catalyst. It is necessary to develop high stability of catalysts for low-temperature SCR. Among the transition metal oxides, $WO_3$ is known to exhibit high SCR activity and good thermal stability. The $MnOx-WO_3-TiO_2$ catalysts prepared by sol-gel method with various $WO_3$ contents were investigated for low-temperature SCR. These catalysts were observed in terms of micro-structure and spectroscopy analyses. The $WO_3$ catalyst as a promoter is used to enhance the thermal stability of catalyst since it increases the phase transition temperature of $TiO_2$ support. It was found that the addition of tungsten oxides not only maintained the temperature window of NO conversion but also increased the acid sites of catalyst.

• Journal of Biosystems Engineering
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• v.21 no.1
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• pp.84-93
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• 1996

Several paraffins(CnH2n +2) can be used as the thermal energy storage medium because of their large amount of latent heat and their flexibility of phase change temperature. But they have not been used in the thermal energy storage system because their long term stability have not been verified. Paraffins(CnH2n+2) which the values of n are 23, 24, 26 and 28 were selected for this experimental research. And this research was peformed to apply them to the practical systems. The results were summarized as follows. (1) The increase of phase change cycles had no effect on their phase change temperatures. (2) According as the values of n increased from 23 to 28, the specific heats of paraffins(CnH2n+2) increased, and were in the range of 0.47 0.75 ㎉/$kg^circ C$. (3) Thermal conductivities of them were in the range of 0.14 0.17 W/$m^circ C$. and specific gravities of them were in the range of 765800 kg/m3. (4) The density of paraffins was in the range of 765 800 kg/$m^circ C$ , and the density of solid phase was larger than that of liquid phase. (5) When the number of phase change cycles was 1, 500 cycles, the latent heat of paraffins was 90% of the initial value.

• KIEAE Journal
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• v.16 no.1
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• pp.11-19
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• 2016

Purpose: PMV, PET, and similar thermal comfort indices and microclimate modeling have recently become actively used to evaluate thermal comfort. This study will look at pedestrian roads with diverse spatial characteristics on university campus using the ENVI-met model as the base for onsite measurement. Method: The PET was used as the thermal comfort index. The first microclimate measures were collected on September 20, 2014, and the second microclimate measures were collected on June 1, 2015. The ENVI-met model was used at the same time. Result: As a results, Onsite measurement results differed depending on the PET spatial characteristics. The location associated with the most discomfort had a PET of $47.8^{\circ}C$. The spatial characteristics of this place included a with no shade. The most comfortable location had shade, and the PET was $24.6^{\circ}C$. When the ENVI-met model and onsite measurements were compared, similar patterns were found, but with a few differences at specific points; this was due to the limitation of using input materials such as trees, buildings, and covering materials with the ENVI-met model. This factor must be thoroughly considered when analyzing modeling results.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.21 no.3
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• pp.157-166
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• 2009

The pulverized coal combustion behavior in the coal fired utility boiler has been investigated with the CFD and process analysis techniques. The used commercial software were CFX and PROATES, and these were coupled each other to get more reliable boundary condition set-up, resulting in more reliable solution. For two cases which were the actual operation condition of A power plant, the calculated values from the coupled CFD and process analysis for thermal energy system were compared with the plant data, and the good agreements were obtained for Case 1 and 2. The calculated temperature distributions on the surface of heat exchangers were compared with the plant data for the steam temperatures across heat exchangers, and these explained the actual operating situation very well. The temperature deviation across the final superheater tube, which was believed to be the main cause of the frequent tube failure, were also explained very well with the calculated distributions of gas temperature and radiation on the plane of the final superheater.

• Journal of Photoscience
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• v.8 no.3_4
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• pp.113-117
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• 2001

Several styrylquinolium salts were synthesized to investigate their absorption and thermal properties, which had five different p-aminobenzene units and three different counter ions (iodide, perchlorate, and hexafluorophosphorate anion), respectively. Hydroxy, methoxy, and methyl group in the meta position to the amino group led to bathochromic shift, while Ν-ethyl-Ν-chloroethylamino unit instead of Ν,Ν-diethylamino unit resulted in hypsochromic shift. A dye having a methoxy group in the meta position to the amino group had the highest molar extinction coefficient ($\xi$), while a dye carrying chloro group in Ν-alkyl chains had the lowest $\xi$. The type of counter ions had no effect on spectral properties like the maximum absorption wavelength and $\xi$. All styryl dyes had exothermic peaks at decomposition in DSC curves. Among these styryl dyes, S2 series with perchlorate anions showed the strongest exothermic decomposition. From TGA spectra, S3 series with hexafluorophosphorate anions had the best thermal stability and the sharpest threshold at thermal decomposition.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2007.11a
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• pp.76-79
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• 2007

From the previous researches about flow characteristic of micro-nozzle， we found that viscosity and back pressure induced heavy losses in micro nozzle. To overcome thess losses, we began to study new conceptual micro propulsion system that is thermal transpiration based micro propulsion system. It has no moving parts and can pump the gaseous propellant by temperature gradient only (cold to hot). Most of previous research on thermal transpiration is in its early stage and mainly studied for application to small vacuum facility or gas chromatography in ambient condition using nanoporous material like aerogel. In this study, we focus on basic research of propulsion system based on thermal transpiration using polyimide material in vacuum conditions.

• Journal of Radiation Protection and Research
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• v.28 no.4
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• pp.281-290
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• 2003

The KN-12 spent nuclear fuel transport cask, which is a Type B(U) package designed to comply with the requirements of Korea Atomic Energy Act[1], IAEA Safety Standards Series No.TS-R-1[2] and US 10 CFR Part 71[3], is designed for carrying up to 12 PWR spent fuel assemblies in a basket structure. The cask has been licensed in accordance with Korea Atomic Energy Act and was fabricated in Korea in accordance with the requirements of ASME B&PV Sec.III, Div.3[4]. The cask must maintain thermal integrity in accordance with the related regulations and be evaluated to verify that the thermal performance of the cask complies with the regulatory requirements. The temperatures of the cask and components were determined by using finite elements methods with a numerical tool, safety tests using an 1/8 height slice model of the real cask were conducted to demonstrate verification of the numerical tool and methods, and heat transfer tests for normal transport conditions were performed as a fabrication acceptance test to demonstrate the heat transfer capability of the cask.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.11 no.4
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• pp.97-103
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• 2012

This study investigates thermal insulation properties of multi layer materials depending on thickness of air layers. Numerical analysis on the heat flow of different insulating materials was conducted to identify whether their temperature distributions demonstrate the reduced rate of heat transfer conclusively or not. Analytical model is divided into two categories. One is to distinguish temperature distribution of the air-layer materials from the non-air layer ones. The other is to compare the efficacy between eight-layered insulating materials with no air-layer contained and three-layered insulating materials which include an air-layer definitely. In the latter case, the identical thickness is assigned to each material. The effect of thermal insulation by including an air-layer is verified in the first analytical model. The result of the second model shows that the insulation of the eight-layered materials is coterminous at the three-layered ones with an air-layer and the thermal insulation of the two materials is imperceptible. The benefits of cost and energy saving are anticipated if air-layers are efficiently incorporated in multi layer insulating materials in a greenhouse.