• Economic and Environmental Geology
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• v.53 no.6
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• pp.677-685
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• 2020

The host rock of the Usuki Stone Buddha Statues is dark gray welded tuff involved the Aso-4 pyroclastic flow sediments. This Buddha Statues are processing chlorosis from rainfall flowing above and underground water which were urgently needed for conservation measurement. White precipitates, the main source of salt weathering, on the surface of the Buddha Statues are mainly consisted of thenardite, gypsum and dolomite. Extraction experiment result shows that thenardite was dissolved at the beginning of stirring and then redissolved after 4 hours, and gypsum was detected until stirring for 2 hours, and then dissolved after stirring for 4 hours. As a result of monitoring the microclimate environment for 11 months to determine the recrystallization environment of white precipitates, the phase transition between thenadite and mirabilite appears widely in spring, and is maintained in an aqueous solution due to high temperatures in summer and fall. In winter, mirabilite is shown the widest by decreasing temperature. Therefore we requires details monitoring for blocking water transfer port and solved humidity environment in shelter.

• Journal of the speleological society of Korea
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• no.8
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• pp.77-84
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• 1998

A large number of lava tubes in southwestern idaho contain some extremely impressive secondary mineral deposits. Gypsum and mirabilite can be found coating entire lava formation and in some cases entire rooms, thenardite and cristobolite can also be found throughout idaho's lava tubes, although in smaller individual concentrations. To a lesser degree iron and copper-based deposits have been found. On rare occasions and in very small quantities calcium carbonate deposits have been found.(omitted)

• Journal of the speleological society of Korea
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• no.4
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• pp.33-39
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• 1996

Secondary mineral deposits of gypsum, mirabilite, thenardite, crisobolite have long been known and, in fact, are quite common in lava tubes of southwest Idaho. Until recently, calcium carbonate were found in a few tubes in very small amounts and were thought to be qu are. The recent ‘rediscovery’ of Helen's Hidden Hide - Away lava tube h significantly changed this thinking. The deposits in this lava tube are only quite extensive but extremely varied in structure. As this is a v recent discovery, only basic preliminary work will be presented in t paper. It is hoped this will stimulate intrest for further and more inte study of the lava tubes of southwestern Idaho.

• Journal of the speleological society of Korea
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• no.5
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• pp.70-78
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• 1997

Secondary mineral deposits of gypsum, mirabilite, thenardite, and cristpbolite have long been known and, in fact, are quite common in the lava deposits tubes of southwest idaho. Until recently, calcium carbonate were only found in a few tubes in very small amounts and were though to be quite rare. The recent ‘rediscovery’ of Henlen's Hidden Hide -A way lava tube has significantly changed this thinking. The deposits in the lava tube are not only quite extensive but extremely varied in structure. As this is a very recent discovery, only basic preliminary work will be presented in this paper. It is hoped this will stimulate interest for further and more intensive study of the lava tubes of southwestern idaho.

• 한국문화재보존과학회:학술대회논문집
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• 2004.03a
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• pp.78-91
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• 2004

염(Salts)은 일반적으로 가장 강력한 풍화요인 물질 중 하나이다. 염의 결정화(crystallization) 및 수화(hydration)작용은 석재의 화학적 풍화 뿐만이 아니라 물리적 풍화를 가속화 시킨다. 감은사지 석탑은 오랜 세월 대기 중에 노출되어 대기환경오염으로 인한 화학적 풍화 뿐만이 아니라 지리적으로 바다에 인접해 있어 바다에서 기원한 염화나트륨(NaCl)의 영향으로 다른 석조물에 비해 심한 물리적 풍화현상을 보이고 있다. 편광 현미경 및 SEM, XRD, XRF를 이용하여 석탑의 구성석재 및 염(salts)에 대한분석을 실시하였으며, 용출실험을 통해 얻은 용액에 대해서는 IC와 ICP-AES를 이용하여 분석하였고, 염류와 석재의 반응산물로 만들어진 염에 대해서는 정방위시료와 부정방위시료를 제작하여 분석하였다. 감은사지 석탑을 이루는 암석은 결정응회암으로 주 구성 광물은 사장석 및 정장석이며 소량의 석영 및 흑운모 등이 함유되어 있고 소량의 유리질 석기로 구성되어 있다. 석재의 표면에는 주 구성 광물들의 화학적 풍화로 인해서 생성된 2차 광물로 팽창성 점토광물인 스멕타이트가 존재하며, 대기오염물질과의 결합에 의해 생성된 대표적인 황산염인 석고$(gypsum,\;CaSO_4{\cdot}2H_2O)$, 소금(halite, NaCl), 해양기원 염류인 소금성분과 대기오염물질이 만들어낸 테나다이트$(thenardite,\;Na_2SO_4)$가 존재한다. 이들 염류는 일차적으로 암석의 표면에 백화현상을 초래하기도 하고, 대기 중의 오염물질과 결합하여 일부는 흑화현상을 보이기도 한다. 또한 암석 내 수분이 증가할 경우 이들 염들이 암석의 공극이나 열극을 따라 내부로 이동하여 subflorescence를 발생시켜 박락 및 박탈의 원인이 되었으며, 온도와 수분의 변화에 따른 이들 염(salts)의 수화 및 결정 작용 그리고 새로운 염(salts)의 침전작용을 반복하면서 석재 내부와 외부의 암석 및 결정에 균열과 미세열극 등이 생성되어 석재 자체의 구조적 안정성에 영향을 주고 있다. 따라서 감은사지 석탑은 지리적 환경 차이로 인해 일반적인 환경의 석조물들과는 다른 형태의 풍화양상을 보이고 있어서 풍화양상 및 풍화형태에 대한 정확한 연구와 이해를 바탕으로 보존대책이 마련되어야 한다.

• Journal of Conservation Science
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• v.38 no.4
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• pp.265-276
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• 2022

A long-term monitoring investigation at Sarushima Battery (Kanagawa, Japan), which is one of the modernization heritages was conducted from 2017.06 to 2020.12. The investigation of the temperature and relative humidity (RH), measurement of the amount of brick decay, and X-ray diffraction analysis of the brick decay was conducted to understand in detail the environment in which the historical brick structure, the state of deterioration, identify the factors of deterioration. Furthermore, it was discussed whether the suitability of these investigation methods for assessing the status, identifying the level of deterioration and the factors that led to deterioration at the historical brick heritages. It was found that the brick deterioration at the site progressed especially in two periods: in April, and from June to August. These periods coincided with the period when the RH inside the structure decreased, and the Toyo-gumi bricks were in the process of absorbing moisture. Several different types of salts were detected in brick decay, especially thenardite, which is considered highly hazardous and destructive during periods when the amount of brick decay increased. Therefore, the RH in the structure and the salts present in the bricks were identified as one of the factors in the deterioration of the bricks at the site. The methods used in this study are appropriate as the initial survey methods for investigating the current conditions and identifying the causes of deterioration because it is possible to understand the environment within the modernization heritages, grasp the details of deterioration progression, and identify the characteristics of deterioration progression and its factors through long-term investigation using the simple methods.

• Journal of the Mineralogical Society of Korea
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• v.2 no.2
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• pp.81-89
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• 1989

Alunite occurs as massive, cavity-filling and veinlets in the Cretaceous Hwangsan Formation in the Sungsan mine, Korea. It is a hydrothermal alteration product of rhyolitic tuffs, and associated with dickite, quartz and barite. The average chemical formula of alunite in the mine is $(K_{0.93}Na_{0.07})_{1.00}Al_{3.00}(SO_4)_{2.00}(OH)_6$. Atomic percentage of Na substituting for K in A site of the alunite structure varies from 5.9 to 9.2. Unit-cell volume and c dimension decrease with increasing Na atomic percentage. On the basis of thermal and high temperature XRD analyses, the decomposition of alunite into $KAl(SO_4)_2$ and $NaAl(SO_4)_2$ concomitant with the liberation of structural water (12.86%) occurs at about $550^{\circ}C$. The reconstruction of $KAl(SO_4)_2$ and $NaAl(SO_4)_2$ to $Al_2(SO_4)_3$, arcanite and thenardite, and the crystallization of ${\gamma}-Al_2O_3$ take place at about $720^{\circ}C$. The destruction of $Al_2(SO_4)_3$ structure takes place at about $760^{\circ}C$ removing 3/4 of total $SO_3$ (27.32%).