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Predicting Potential Habitat for Hanabusaya Asiatica in the North and South Korean Border Region Using MaxEnt (MaxEnt 모형 분석을 통한 남북한 접경지역의 금강초롱꽃 자생가능지 예측)

  • Sung, Chan Yong;Shin, Hyun-Tak;Choi, Song-Hyun;Song, Hong-Seon
    • Korean Journal of Environment and Ecology
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    • v.32 no.5
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    • pp.469-477
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    • 2018
  • Hanabusaya asiatica is an endemic species whose distribution is limited in the mid-eastern part of the Korean peninsula. Due to its narrow range and small population, it is necessary to protect its habitats by identifying it as Key Biodiversity Areas (KBAs) adopted by the International Union for Conservation of Nature (IUCN). In this paper, we estimated potential natural habitats for H. asiatica using maximum entropy model (MaxEnt) and identified candidate sites for KBA based on the model results. MaxEnt is a machine learning algorithm that can predict habitats for species of interest unbiasedly with presence-only data. This property is particularly useful for the study area where data collection via a field survey is unavailable. We trained MaxEnt using 38 locations of H. asiatica and 11 environmental variables that measured climate, topography, and vegetation status of the study area which encompassed all locations of the border region between South and North Korea. Results showed that the potential habitats where the occurrence probabilities of H. asiatica exceeded 0.5 were $778km^2$, and the KBA candidate area identified by taking into account existing protected areas was $1,321km^2$. Of 11 environmental variables, elevation, annual average precipitation, average precipitation in growing seasons, and the average temperature in the coldest month had impacts on habitat selection, indicating that H. asiatica prefers cool regions at a relatively high elevation. These results can be used not only for identifying KBAs but also for the reference to a protection plan for H. asiatica in preparation of Korean reunification and climate change.

Three Cyanide-Bridged One-Dimensional Single Chain CoIII-MnII Complexes: Rational Design, Synthesis, Crystal Structures and Magnetic Properties

  • Zhang, Daopeng;Zhao, Zengdian;Wang, Ping;Chen, Xia
    • Bulletin of the Korean Chemical Society
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    • v.33 no.5
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    • pp.1581-1585
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    • 2012
  • Two pyridinecarboxamide dicyanidecobalt(III) building blocks and two mononuclear seven-coordinated macrocycle manganese(II) compounds have been rationally selected to assemble cyanide-bridged heterobimetallic complexes, resulting in three cyanide-bridged $Co^{III}-Mn^{II}$ complexes. Single X-ray diffraction analysis show that these complexes $\{[Mn(L^1)][Co(bpb)]\}ClO_4{\cdot}CH_3OH{\cdot}0.5H_2O$ ($\mathbf{1}$), $\{[Mn(L^2)][Co(bpb)]\}ClO_4{\cdot}0.5CH_3OH$ ($\mathbf{2}$) and ${[Mn(L^1)][Co(bpb)]\}ClO_4{\cdot}H_2O$ ($\mathbf{3}$) ($L^1$ = 3,6-diazaoctane-1,8-diamine, $L^2$ = 3,6-dioxaoctano-1,8-diamine; $bpb2^{2-}$ = 1,2-bis(pyridine-2-carboxamido)benzenate, $bpmb2^{2-}$ = 1,2-bis(pyridine-2-carboxamido)-4-methyl-benzenate) all present predictable one-dimensional single chain structures. The molecular structures of these one-dimensional complexes consists of alternating units of $[Mn(L)]^{2+}$ ($L=L^1$ or $L^2$) and $[Co(L^{\prime})(CN)2]^-$ ($L^{\prime}=bpb2^{2-}$, or $bpmb2^{2-}$), forming a cyanide-bridged cationic polymeric chain with free $ClO_4{^-}$ as the balance anion. The coordination geometry of manganese(II) ion in the three one-dimensional complexes is a slightly distorted pentagonal-bipyrimidal with two cyanide nitrogen atoms at the trans positions and $N_5$ or $N_3O_2$ coordinating mode at the equatorial plane from ligand $L^1$ or $L^2$. Investigation over magnetic properties of these complexes reveals that the very weak magnetic coupling between neighboring Mn(II) ions connected by the diamagnetic dicyanidecobalt(III) building block. A best-fit to the magnetic susceptibility of complex ${\mathbf}{1}$ leads to the magnetic coupling constants $J=-0.084(3)cm^{-1}$.

Low Temperature Sintering and Microwave Dielectric Properties of Ba5Nb4O15 Ceramics (Ba5Nb4O15 세라믹스의 저온소결 및 마이크로파 유전특성)

  • Kim, Jong-Dae;Kim, Eung-Soo
    • Journal of the Korean Ceramic Society
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    • v.41 no.10 s.269
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    • pp.783-787
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    • 2004
  • Microwave dielectric properties and the microstructure of $Ba_5Nb_4O_{15}$ ceramics with $PbO-B_2O_3-SiO_2$ glass frit were investigated to reduce the sintering temperature of $Ba_5Nb_4O_{15}$ ceramics as a function of the amount of glass frit from $0.5wt\%$ to $10wt\%$ and the sintering condition. The sintered density and the microwave dielectric properties of $Ba_5Nb_4O_{15}$ ceramics were remarkably changed with the amount of glass fit which existed as a liquid phase and assisted the densification. $Ba_5Nb_4O_{15}$ with $3wt\%$ $PbO-B_2O_3-SiO_2$ glass frit sintered at $900^{\circ}C$ for 2 h showed dielectric constant (K) of 41.4, a quality factor (Q $\times$f) of 13,485 GHz, and a Temperature Coefficient of resonant Frequency (TCF) of 9 ppm/$^{\circ}C$. Due to no trace of physical and chemical reaction between this composition and Ag electrode cofired at $900^{\circ}C$ for 2 h, this ceramics can be a good candidate for the multilayer dielectric filter.

Changes in Physicaochemical Properties of Soil, Yield, and Milling Quality of Rice Grown under the Long-term No-till Rice System (장기 무경운 벼 생산체계에서 토양의 이화학성, 쌀 수량 및 도정형질의 변화)

  • 홍광표;김영광;정완규;손길만;송근우;최용조;최진용
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.48 no.3
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    • pp.196-199
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    • 2003
  • This experiment was conducted to evaluate the differences in physicochemical properties of soil, grain yield and milling recovery ratio and grain appearance of rice grown in long-term no-till and ordinary till systems. The paddy in no-till rice system was unploughed but straw-mulched for 15 years from 1988 to 2002 at the Experimental Paddy of Gyeongnam Agricultural Research and Extension Services, while the paddy in ordinary till system was ploughed and puddled every crop year, A 5cm organic layer was formed in 11-year no-till rice system, in which exchangeable cation and phosphate were accumulated. In no-till paddy organic matter, bulk density and solid phase of surface soil significantly increased, while pH, exchangeable cation, phosphate, liquid and gaseous phase decreased. Tillage made the very top soil soft, but made deep soil below 5cm significantly hard. In the 1st year of no-till, topsoil showed hard, but in the process of the time in no-till system, the top- and sub-soil showed softer, Yield and yield components of rice showed no differences between till- and no-till rice systems. Milling recovery ratio and grain appearance were not significantly different between no-till and till-rice systems.

Characterization of the Extracellular ${\beta}-Galactosidase$ Produced from Streptomyces sp. YB-9 (Streptomyces sp. YB-9가 생산하는 균체외 ${\beta}-galactosidase$의 특성)

  • Lee, Kyung-Seop;Kim, Chang-Jin;Yoon, Ki-Hong
    • Applied Biological Chemistry
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    • v.46 no.4
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    • pp.299-304
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    • 2003
  • A strain YB-9 was isolated from soil as a producer of the extracellular ${\beta}-D-galactosidase$, which catalyzes the hydrolysis of lactose. The strain YB-9 was identified as Streptomyces sp. on the basis of its cultural, morphological and physiological properties. After treating culture supematant of the isolate with ammonium sulfate $(15{\sim}70%)$, the precipitated protein was used as a crude ${\beta}-galactosidase$ for analyzing its reaction properties with $para-nitrophenyl-{\beta}-D-galactoside$ $(pNP-{\beta}Gal)$ and lactose as substrates. The {\beta}-galactosidase showed its maximal activity at pH $6.0{\sim}6.5$ and $60^{\circ}C$. The hydrolyzing activity of ${\beta}-galactosidase$ for both $pNP-{\beta}Gal$ and lactose was decreased by galactose. Its hydrolyzing activity for lactose was slightly decreased by glucose, but the activity for $pNP-{\beta}Gal$ was increased to 1.3-folds by glucose. Especially, its hydrolyzing activity was not affected for lactose and was increased to 1.6-folds for $pNP-{\beta}Gal$ by xylose.

The Electrochemical Property Studies on Polyacenic Semiconductor Anode Material (음극 폴리아센 반도체 재료의 전기화학적 특성연구)

  • Kim Han-Joo;Park Jong-Eun;Son Won-Keun;Lee Hong-Ki;Park Soo-Gil;Lee Ju-Seong
    • Journal of the Korean Electrochemical Society
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    • v.2 no.3
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    • pp.134-137
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    • 1999
  • The polyacenic semiconductor material (PAS) electrode prepared by the pyrolytic treatment of phenol-formaldehyde resin is one of useful electrodes. As an anode material of lithium rechargeable batteries, amorphous carbon materials have been studied extensively because of their high electrochemcal performance and cyclicability. Carbon materials do not lead to the formation of lithium dendrite which is one of the most serious problems in applying Li-based materials to an electrode of batteries. The polyacene materials prepared from phenol resin at relatively low temperatures $(550\~750^{\circ}C)$ show a highly Li\doped state up to $C_2Li$ state without liberation of Li cluster. We prepared each polyacene materials at various temperature and investigated electro- chemical properties. We tried to change the mole ratio of [H]/[C] which is $0.24\~0.4$ range. Considering of electrochemical properties of PAS material, the PAS material is one of the most suitable materials for electrodes of a polymer battery.

Effect of Annealing on Structural and Electrical Properties of VOx Thin Films (VOx 박막의 구조적 특성과 전기적 특성에 대한 열처리 영향)

  • Lee, Jang Woo;Chung, Chee Won
    • Applied Chemistry for Engineering
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    • v.17 no.5
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    • pp.471-475
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    • 2006
  • $VO_x$ thin films with the thickness of 450 nm were prepared on a $Pt/Ti/SiO_{2}/Si$ substrate at room temperature by a reactive radio frequency (rf) magnetron sputtering method. The deposition rates of $VO_x$ thin films were investigated as a function of $O_{2}$ concentration and rf power. As the $O_{2}$ concentration in a $O_{2}/Ar$ mixture increased, the deposition rate decreased. However, the deposition rate increased with increasing rf power. The deposited $VO_x$ thin films were annealed at $450^{\circ}C$ for 2, 4, and 6 h in $O_{2}$ and $N_{2}$ ambient. After annealing, the phase changes of $VO_x$ thin films were investigated using X-ray diffraction analysis. The plane and cross-sectional views of $VO_x$ thin films before and after annealing were observed by field emission scanning electron microscopy. The metal-insulator transition (MIT) properties of $VO_x$ thin films were measured using current-voltage measurement. The excellent MIT properties were observed in $VO_x$ thin films annealed in $O_{2}$ ambient.

Preparation and Heating Characteristics of N-doped Graphite Fiber as a Heating Element (질소가 도핑 된 흑연섬유 발열체의 제조 및 발열특성)

  • Kim, Min-Ji;Lee, Kyeong Min;Lee, Sangmin;Yeo, Sang Young;Choi, Suk Soon;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.28 no.1
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    • pp.80-86
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    • 2017
  • In this study, nitrogen functional groups were introduced on graphite fiber (GF) to modify their electrical properties, and heating properties were investigated according to the treatment conditions. GF was prepared by a thermal solid-state reaction at $200^{\circ}C$ for 2 h. Surface properties of the nitrogen doped GF were examined by XPS, and its resistance and heating temperature were measured using a programmable electrometer and thermo-graphic camera, respectively. The XPS result showed that the nitrogen functional groups on the GF surface were increased with increasing of urea contents, and the heating property of the GF was also improved as nitrogen functional groups were introduced. The maximum heating temperature of GF treated by urea was $53.8^{\circ}C$ at 60 V, which showed 55% improved heating characteristics compared to that of non-treated GF. We ascribe this effect to introduced nitrogen functional groups on the GF surface by thermal solid-state reaction, which significantly affects the heating characteristics of GF.

Property Changes of the Salt-Seasoned and Fermented the Broken Roes of Alaska Pollock Stuffed into Cellulose Casing (Cellulose casing에 충진한 명태 절란젓의 숙성중 품질변화)

  • Park, Jong-Hyuk;Kim, Sang-Moo
    • Korean Journal of Food Science and Technology
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    • v.34 no.2
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    • pp.220-224
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    • 2002
  • Alaska pollock roe is mainly used for the production of salt-seasoned and fermented seafood (Myungran-jeot). Alaska pollock roes with broken egg membrane are usually discarded as a waste product. In this study, the broken roes of Alaska pollock were salt-seasoned and stuffed into cellulose casing for commercial production. The chemical and microbial changes of the broken roes of Alaska pollock stuffed into cellulose casing fermented at 5 and $25^{\circ}C$, respectively, were analyzed at different ripening periods. On 5 week fermentation, pH decreased down to 5.60 and 5.10 at 5 and $25^{\circ}C$, respectively, but the amounts of lactic acid, amino-nitrogen, and volatile basic nitrogen increased continously as ripening period increased, higher at 25 than $5^{\circ}C$. The amounts of amino-nitrogen, 620 and 780 mg/100 g, were the highest on 3 week fermentation at $5^{\circ}C$ and on 1 week at $25^{\circ}C$, respectively. The numbers of total viable cell and lactic acid bacteria, $3.1{\times}10^6$ and $3.1{\times}10^5\;CFU/g$ at $5^{\circ}C$, and $1.9{\times}10^7$ and $2.8{\times}10^6\;CFU/g$ at $25^{\circ}C$, respectively, were the highest on 2 week fermentation.

Growth Response of Zoysiagrass (Zoysia japonica Steud.) as Affected by Nitrogen Fertilizer Application Rate (질소비료 시비량에 따른 들잔디의 생육반응)

  • Bae, Eun-Ji;Han, Jeong-Ji;Lee, Kwang-Soo;Park, Yong-Bae;Choi, Su-Min
    • Weed & Turfgrass Science
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    • v.4 no.4
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    • pp.397-404
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    • 2015
  • This study was conducted to find out the optimum nitrogen fertilization for production of good quality and high yield zoysiagrass (Zoysia japonica Steud.), the changes in chemical properties of soil in pot and field experiments treated with different levels of nitrogen fertilizer. In pot experiment, the fresh and dry weights of shoots and stolons and the number of shoots increased as nitrogen levels increased, and showed no significant between 24 and $48kg\;N\;10\;a^{-1}$. In field experiment, the shoot length, fresh and dry weights of shoots, roots and stolons, the number of shoots and total stolons length linearly increased as affected by increased nitrogen application, and were not significantly different between 24 and $32kg\;N\;10\;a^{-1}$. In both experiments, pH and exchangeable cations ($Ca^{2+}$ and $Mg^{2+}$) in soil decreased as the rate of nitrogen application increased. As a results, chemical properties of soil were more deteriorated in the plots of higher nitrogen fertilizer rate. Thus, these results demonstrated that the nitrogen fertilizer rate for maximum growth of zoysiagrass was $24kg\;N\;10\;a^{-1}$ in consideration of growth and soil condition.