• Title/Summary/Keyword: tert-buthylhydroperoxide

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Phase equilibria and structure identification of tert-butylhydroperoxide + gaseous clathrate hydrates (이성분계(3차 부틸-히드로과산화물 + 기체) 클러스레이트 하이드레이트의 구조적 특성과 열역학적 안정성에 관한 연구)

  • Youn, Yeobeom;Cha, Minjun;Kwon, Minchul;Lee, Huen
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.150.1-150.1
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    • 2011
  • Structure-II hydrate has been highlighted due to its higher gas storage capacity and favorable thermodynamic conditions. In this study, we introduce a new structure-II hydrate former, tert-butyl hydroperoxide (TBHP) and confirm the structural characteristics through High-Resolution Powder Diffraction (HRPD), $^{13}C$ solide-state NMR and Ramanspectroscopy. Here,we also investigated the thermodynamic stability of binary(TBHP+gaseous) clathrate hydrates. The experimental data were generated using an isochoric pressure-search method. The dissociation data for (TBHP +gaseous) clathrate hydrates are compared with the other hydrocarbon hydrate and pure gaseous hydrate.

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