• Title/Summary/Keyword: ternary mixtures

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Pool Boiling Heat Transfer Correlation for Mixture Refrigerants (혼합냉매의 풀비등 열전달 상관식)

  • 고영환;김종곤;박진석;정동수;김영일
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.13 no.2
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    • pp.122-133
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    • 2001
  • Pool boiling heat transfer coefficients(HTCs) of HFC32/HFC134a, HFC125/HFC134a, HFC32/HFC125 and HFC32/HFC125/HFC134a were measured on a horizontal smooth tube. The experimental apparatus was specially designed to simulate the real heat transfer tube with the use of the secondary fluid of water. Data were taken in the order of decreasing heat flux starting at 80kW/$m^2\; and\; ending\; at\; 5kW/m^2$ in the pool temperature at $7^{\circ}C$. Test results showed that HTCs of these mixtures were 11~38% lower than those of ideal HTCs calculated by a linear mixing rule with pure fluids、 HTCs. Experimental data were compared with Stephan & Korner, Thome, Schlunder, Thome & Shakir、s correlations only to find that those correlations were not satisfactory for all fluids. Hence, a new correlation based on the present data was proposed which could be applied even to the ternary mixture. The correlation predicts the degradation of HTCs of mixtures well, showing a mean deviation of less than 15% for all the mixture data.

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The Fundamental Properties of High Fluidity Mortar with Activated Ternary Blended Slag Cement (활성화된 삼성분계 고유동 모르타르의 기초특성)

  • Bae, Ju-Ryong;Kim, Tae-Wan;Kim, In-Tae;Kim, Hyoung-Seok
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.6
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    • pp.74-82
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    • 2017
  • This research presents the results of the strength and drying shrinkage properties to study the effect of ground granulated blast furnace slag(GGBFS), fly ash(FA) and calcium sulfoaluminate(CSA) for activated ternary blended slag cement. The activated ternary blended cement(ATBC) mortar were prepared having a constant water-cementitious materials ratios of 0.4. The GGBFS contents ratios of 100%, 80%, 70% and 60%, FA replacement ratios of 10%, 20%, 30% and 40%, CSA ratios of 0%, 10%, 20% and 30% were designed. The superplasticizer of polycarboxylate type were used. The activator was used of 10% sodium hydroxide(NaOH) + 10% sodium silicate($Na_2SiO_3$) by weight of binder. Test were conducted for mini slump, setting time, V-funnel, water absorption, compressive strength and drying shrinkage. According to the experimental results, the contents of superplasticizer, V-funnel and compressive strength increases with an increase in CSA contents for all mixtures. Moreover, the setting time, water absorption ratios and drying shrinkage ratio decrease with and increase in CSA. One of the major reason for the increase of strength and decrease of drying shrinkage is the accelerated reactivity of GGBFS with alkali activator and CSA. The CSA contents is the main parameter to explain the strength development and decreased drying shrinkage in the ATBC.

Synthesis of Cordierite and Preparation of Refractory Setter from Domestic Raw Materials (Cordierite의 합성 및 내화갑제조에 관한 연구)

  • 지응업;최상욱;김광호
    • Journal of the Korean Ceramic Society
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    • v.12 no.4
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    • pp.19-28
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    • 1975
  • In order to obtain the superior refractory setter having better spalling resistance, cordierite was synthesized from domestic raw materials. Raw mixtures were fired between 125$0^{\circ}C$ and 140$0^{\circ}C$, and qualitative determination of crytallization was investigated by x-ray diffraction analysis. The results obtained are as follows; 1) The optimum batch composition of synthesized cordierite is 80.5% of Hadong kaolin (pink), 14% of Kyulsung tromolite talc and 5.5% of magnesia clinker, and the firing temperature is 1375$^{\circ}C$. 2) The composition of the refractory setter which exhibits the best values for the thermal properties is 40% of synthesized cordierite, 30% of kaolin chamotte(contains more than 60% of mullite), and 30% of Japanese clay. 3) The optimum particle size distribution of ternary mixture consists of 50% of coarse articles (3.327-1.168mm), 25% of intermediate particles (1.168-0.208mm) and 25% of fine particles (0.208-0.000mm).

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Light Scattering Studies on the Phase Structure of Ethyl Acetate Casting PMMA/PVAc Blends

  • Ha, Chang-Sik;Lee, Won-Ki;Cho, Won-Jei;T. Ougizawa;T. Inoue
    • Macromolecular Research
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    • v.9 no.1
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    • pp.66-70
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    • 2001
  • In this work, we present the development of phase structure of the poly(methyl methacrylate)(PMMA)/ poly(vinylacetate)(PVAc) mixtures in ethyl acetate solution by light scattering. The PMMA/PVAc blends cast from ethyl acetate solutions exhibited fine "modulated structures" over broad blend composition ranges, which originated from the spinodal decomposition of the ternary polymer solutions at low polymer concentrations during the casting. The periodic distance was depended on the blend compositions and evaporation times.

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Uranium(VI) Phosphate Precipitate Formation in a Carbonate Solution

  • Im, Hee-Jung;Park, Kyoung-Kyun;Park, Yeong-Jae;Kim, Won-Ho
    • Proceedings of the Korean Nuclear Society Conference
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    • 2005.05a
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    • pp.311-312
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    • 2005
  • The precipitation of U(VI) in the presence of phosphate and carbonate was investigated in the pH range of 4 to 13 and the following was obtained as a result of this experimental condition. U(VI) precipitates as a $NaUO_{2}PO_{4}$ at pH<9 but as mixtures of phosphate, hydroxides and/or carbonate at pH>9. The portion of the phosphate in the precipitate decreases almost linearly to near zero with an increasing pH in the range of 9 to 13. The U(VI) phosphate is dissolved by the carbonate complex formation at pH<10.5. The ternary complex of a carbonate and phosphate is not found.

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Synthesis and Mechanical Properties of Nano Laminating $Cr_2AlC$ using $CrC_x/Al$ Powder Mixtures

  • Han, Jae-Ho;Park, Sang-Whan;Kim, Young-Do
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.868-869
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    • 2006
  • [ $Cr_2AlC$ ] was synthesized by a reactive hot pressing of $CrC_x(x=0.5)$ and Al powder mixture used as starting materials at the temperature range of $1200^{\circ}C{\sim}1400^{\circ}C$ under 25 MPa in Ar atmosphere. Fully dense $Cr_2AlC$ with high purity was synthesized by hot pressing $CrC_x$ and Al powder mixture at the temperature as low as $1200^{\circ}C$. The average grain size of synthesized bulk $Cr_2AlC$ was varied in the range of $10-100{\mu}m$ depending on hot pressing temperatures. The maximum flexural strength of synthesized bulk $Cr_2AlC$ exceeded 600 MPa.

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Phase behaviors, lamellar structures, and physical properties of synthetic vitamin E ceramide (Tocomide) mixed with cholesterol and linoleic acid

  • Lee, Young-Jin;Kim, Do-Hoon;Park, Ho-Sik;Kang, Hyung-Seok;Kim, Joong-Soo;Kim, Han-Kon
    • Proceedings of the SCSK Conference
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    • 2003.09b
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    • pp.357-368
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    • 2003
  • II-A isotherms and phase behaviors of 'tocomide', a newly synthesized 1,3-bis(N-(2-hydroxyethyl)-tocopherol succinylamino)-2-hydroxypropane, mixed with cholesterol and linoleic acid, was studied for its monolayer miscibility and a stable delivery formulation for antioxidant applications. The monolayer of tocomide and cholesterol was formed in a homogeneously mixed state at air-water interface. The ternary mixtures with linoleic acid showed various bulk structures, including a stable and transparent solution of thermodynamically stable lamellar phase. The lamellar structure was confirmed by the X-ray diffraction (XRD) patterns and polarized microscopy such that pure tocomide formed a liquid crystal at room temperature with a lamellar periodicity of 36.7 $\AA$(2$\theta$=2.41$^{\circ}$).

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Rich Phase Separation Behavior of Biomolecules

  • Shin, Yongdae
    • Molecules and Cells
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    • v.45 no.1
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    • pp.6-15
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    • 2022
  • Phase separation is a thermodynamic process leading to the formation of compositionally distinct phases. For the past few years, numerous works have shown that biomolecular phase separation serves as biogenesis mechanisms of diverse intracellular condensates, and aberrant phase transitions are associated with disease states such as neurodegenerative diseases and cancers. Condensates exhibit rich phase behaviors including multiphase internal structuring, noise buffering, and compositional tunability. Recent studies have begun to uncover how a network of intermolecular interactions can give rise to various biophysical features of condensates. Here, we review phase behaviors of biomolecules, particularly with regard to regular solution models of binary and ternary mixtures. We discuss how these theoretical frameworks explain many aspects of the assembly, composition, and miscibility of diverse biomolecular phases, and highlight how a model-based approach can help elucidate the detailed thermodynamic principle for multicomponent intracellular phase separation.

Studies on the Fusibility of Fly Ash-Flux Mixtures (융제 첨가 비산회의 융융성 연구)

  • Yang, Hyun S.;Lee, Kyu C.;Park, Chu S.
    • Applied Chemistry for Engineering
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    • v.8 no.6
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    • pp.985-993
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    • 1997
  • The effects of CaO and MgO fluxes on the fusibility of fly-ashes were investigated for two different fly-ashes. A fusion temperature of mixtures of selected fly-ashes and fluxes were measured by the ASTM test method(D1857) and the differential thermal analysis. IDT of these samples added CaO and MgO as a fluxing agent dropped in the range of 114 to $294^{\circ}C$ and 80 to $224^{\circ}C$, respectively. Compared with ash fusion temperature to Base/Acid ratio, the lowest ash fusion temperature were measured in the range of 0.7 to 0.8 for CaO-fly ash mixtures and 0.3 to 0.4 for MgO-fly ash mixtures. As a result, MgO in small addition acted as a more effective flux than CaO. A conventional Base/Acid ratio and liquidus point of ternary diagram did not show a good correlation with ash fusion temperature for these samples. In pure fusion temperature of fly ash-mixtures, DTA was better method than ASTM test method.

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A simplified phase diagram in the ternary system $Y_2O_3-Ta(Nb)_2O_5-ZrO_2$ ($Y_2O_3-Ta(Nb)_2O_5-ZrO_2$ 삼성분계 상태도)

  • 이득용;김대준;장주웅;이명현
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.7 no.3
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    • pp.377-383
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    • 1997
  • Yttria-stabilized TZP alloyed with pentavalent oxides $(Ta_2O_5,\;Nb_2O_5)$ were fabricated by the conventional sintering method at $1500^{\circ}C$ in air to construct the simplified ternary phase diagram. The phase stability of tetragonal -$ZrO_2$ from the quasi-binary system $ZrO_2-YTa(Nb)O_4$, which do not transform to monoclinic-$ZrO_2$ even for a wide range of grain size and annealing temperature, was investigated to determine composition region of the non-transformable $t-ZrO_2$ solid solution$(NT_{ss})$. Phase stability of $NT_{ss}$ was probably due to the enhanced stability of $_YTa(Nb)O4$ having the tetragonal fergusonite structure. It was experimentally found that mixtures having $NT_{ss}$ alloyed with $T_{ss}$ by weight%% showed both excellent phase stability of $t-ZrO_2$ and fracture toughness even though the calculated composition of the mixture /was located outside $NT_{ss}$ composition region.

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