• 콘크리트학회논문집
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• 제23권2호
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• pp.145-150
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• 2011

전국적으로 토목 및 건축 구조물의 대단위 공사 및 정비 사업이 발족 및 추진되어 부재 크기가 큰 매스 콘크리트 구조물이 많이 건설되고 있다. 대규모 콘크리트 구조물의 콘크리트 매트릭스 내 높은 수화열 발생은 콘크리트의 품질 및 시공 기간을 좌우하는 가장 중요한 요인이 되고 있다. 이로 인해 발생되는 내부 균열이 콘크리트의 내구성, 수밀성 및 강도를 저하 시키게 된다. 벨라이트계 저열 포틀랜드 시멘트와 산업부산물을 이용한 수화열을 저감시키는 방법으로 이 연구에서는 고로 슬래그 또는 플라이애쉬를 7단계로 치환한 2성 분계 결합재와 4단계로 치환한 3성 분계 결합재를 사용하였고, 혼화재의 치환율 변화가 재령에 따른 수화 발열량, 강도 및 SEM, XRD 등의 기초 물성에 미치는 영향을 비교 분석하였다. 플라이애쉬가 치환된 2성 분계 결합재의 28일 누적 수화열은 플라이애쉬 함유량의 증가함에 따른 높은 수화열 저감 효과를 보여주며, 고로 슬래그가 치환된 2성 분계 결합재의 28일 누적 수화열은 고로 슬래그 치환율이 증가함에 따라 감소하지만 수화열 감소 효과는 높은 치환율 대비 낮은 결과를 나타내었다. 3성 분계 결합재의 28일 누적 수화열의 경우 플라이애쉬 치환율이 높아짐에 따라 낮은 수화열 결과를 보여주며 특히 40% 플라이애쉬 및 30% 고로 슬래그 결합재는 벨라이트계 저열 포틀랜드 시멘트 대비 50%의 저열 효과를 보여주었다. 연구 결과를 통해 수화열 발생이 낮고 시공 가능한 압축강도를 가진 벨라이트계 혼합 결합재를 사용하여 콘크리트 내 온도 상승이 감소된 것을 보여주었다.

• Advances in concrete construction
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• 제6권6호
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• pp.561-583
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• 2018

A variety of polycarboxylate ether (PCE)-based superplasticizers are commercially available. Their influence on the rheological retention and slump loss in respect of concrete differ considerably. Fluidity and slump loss are the cardinal features responsible for the quality of concrete. These are related to the dispersion of cement particles and the hydration process which are greatly influenced by type of polycarboxylate ether (PCE)-based superplasticizers. On the backdrop of relatively less studies in the context of rheological retention of high strength self-consolidating concrete (HS-SCC), the experimental investigations were carried out aiming at quantifying the effect of the six different PCE polymers (PCE 1-6) on the rheological retention of HS-SCC mixes containing two types of Ordinary Portland Cements (OPC) and unwashed crushed sand as the fine aggregate. The tests that were carried out included $T_{500}$, V-Funnel, yield stress and viscosity retention tests. The supplementary cementitious materials such as fly ash (FA) and micro-silica (MS) were also used in ternary blend keeping the mix paste volume and flow of concrete constant. Low water to binder ratio was used. The results reveal that not only the PCEs of different polymer groups behave differently, but even the PCEs of same polymer groups also behave differently. The study also indicates that the HS-SCC mixes containing PCE 6 and PCE 5 performed better as compared to the mixes containing PCE 1, PCE 2, PCE 3 and PCE 4 in respect of all the rheological tests. The PCE 6 is a new class of chemical admixtures known as Polyaryl Ether (PAE) developed by BASF to provide better rheological properties in even in HS-SCC mixes at low water to binder mix. In the present study, the PCE 6, is found to help not only in reduction in the plastic viscosity and yield stress, but also provide good rheological retention over the period of 180 minutes. Further, the early compressive strength properties (one day compressive strength) highly depend on the type of PCE polymer. The side chain length of PCE polymer and the fineness of the cement considerably affect the early strength gain.

• 대한건축학회논문집:구조계
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• 제35권9호
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• pp.199-206
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• 2019

Experimental study on the durability characteristics to examine the feasibility of concrete with high water-tightness and self-healing performance to minimize maintenance of concrete for artificial ground is as follows. 1) When blending agent, swelling agents, and curing accelerator were added on the ternary system cement with blast-furnace slag fine particles and fly ash to give a self-healing property, higher blending strengths by 82% at design standard strength of 24MPa and by 74% at design strength of 30MPa, respectively could be obtained. 2) The permeability test for the specimens having high water-tightness and no shrinkage showed that the permeability was reduced at maximum of 98%. However, the permeability was decreased as the design strength was increased, showing the reduction rate of 87% at the design strength of 50MPa. 3) The depth of carbonation of blast-furnace slag and fly ash was increased in all the specimens compared with those of OPC only. However, as the material age was increased, carbonation penetration depth was decreased compared with the reference blend. 4) Compared with the reference blending using only OPC, the freeze-thaw resistance was higher in the case of blending with 40% of blast-furnace slag and 10% of fly ash at the design standard strength of 50MPa. In addition, the freeze-thaw resistance in general was superior in the design standard strength of 50MPa with the lower water-binder ratio (W/B) as compared with the design standard strength of 24MPa and 30MPa with the high water-binder ratios.