• Korean Journal of Materials Research
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• v.33 no.10
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• pp.406-413
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• 2023

This study used optical and scanning electron microscopy to analyze the surface oxidation phenomenon that accompanies a γ'-precipitate free zone in a directional solidified CM247LC high temperature creep specimen. Surface oxidation occurs on nickel-based superalloy gas turbine blades due to high temperature during use. Among the superalloy components, Al and Cr are greatly affected by diffusion and movement, and Al is a major component of the surface oxidation products. This out-diffusion of Al was accompanied by γ' (Ni₃Al) deficiency in the matrix, and formed a γ'-precipitate free zone at the boundary of the surface oxide layer. Among the components of CM247LC, Cr and Al related to surface oxidation consist of 8 % and 5.6 %, respectively. When Al, the main component of the γ' precipitation phase, diffused out to the surface, a high content of Cr was observed in these PFZs. This is because the PFZ is made of a high Cr γ phase. Surface oxidation of DS CM247LC was observed in high temperature creep specimens, and γ'-rafting occurred due to stress applied to the creep specimens. However, the stress states applied to the grip and gauge length of the creep specimen were different, and accordingly, different γ'-rafting patterns were observed. Such surface oxidation and PFZ and γ'-rafting are shown to affect CM247LC creep lifetime. Mapping the microstructure and composition of major components such as Al and Cr and their role in surface oxidation, revealed in this study, will be utilized in the development of alloys to improve creep life.

• Investigative Magnetic Resonance Imaging
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• v.13 no.1
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• pp.31-39
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• 2009

Purpose : This study proposes the keyhole method in order to improve the time resolution of the proton resonance frequency(PRF) MR temperature monitoring technique. The values of Root Mean Square (RMS) error of measured temperature value and Signal-to-Noise Ratio(SNR) obtained from the keyhole and full phase encoded temperature images were compared. Materials and Methods : The PRF method combined with GRE sequence was used to get MR temperature images using a clinical 1.5T MR scanner. It was conducted on the tissue-mimic 2% agarose gel phantom and swine's hock tissue. A MR compatible coaxial slot antenna driven by microwave power generator at 2.45GHz was used to heat the object in the magnetic bore for 5 minutes followed by a sequential acquisition of MR raw data during 10 minutes of cooling period. The acquired raw data were transferred to PC after then the keyhole images were reconstructed by taking the central part of K-space data with 128, 64, 32 and 16 phase encoding lines while the remaining peripheral parts were taken from the 1st reference raw data. The RMS errors were compared with the 256 full encoded self-reference temperature image while the SNR values were compared with the zero filling images. Results : As phase encoding number at the center part on the keyhole temperature images decreased to 128, 64, 32 and 16, the RMS errors of the measured temperature increased to 0.538, 0.712, 0.768 and 0.845$^{\circ}C$, meanwhile SNR values were maintained as the phase encoding number of keyhole part is reduced. Conclusion : This study shows that the keyhole technique is successfully applied to temperature monitoring procedure to increases the temporal resolution by standardizing the matrix size, thus maintained the SNR values. In future, it is expected to implement the MR real time thermal imaging using keyhole method which is able to reduce the scan time with minimal thermal variations.

• The KIPS Transactions:PartA
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• v.15A no.3
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• pp.141-149
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• 2008

In this research we present a novel method which combines and visualizes the design model and the FDM-based simulation result of solidification. Moreover we employ VR displays and visualize stereoscopic images to provide an effective analysis environment. First we reconstruct the solidification simulation result to a rectangular mesh model using a conventional simulation software. Then each point color of the reconstructed model represents a temperature value of its position. Next we map the two models by finding the nearest point of the reconstructed model for each point of the design model and then assign the point color of the design model as that of the reconstructed model. Before this mapping we apply mesh subdivision because the design model is composed of minimum number of points and that makes the point distribution of the design model not uniform compared with the reconstructed model. In this process the original shape is preserved in the manner that points are added to the mesh edge which length is longer than a predefined threshold value. The implemented system visualizes the solidification simulation data on the design model, which allows the user to understand the object geometry precisely. The immersive and realistic working environment constructed with use of VR display can support the user to discover the defect occurrence faster and more effectively.

• Analytical Science and Technology
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• v.5 no.1
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• pp.143-152
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• 1992

Corrosion resistances in various acids and high temperature oxidation properties have been investigated for the Ni-base superalloy KM 1557. Corrosion tests were performed in $H_2SO_4$, HCl, $HNO_3$, $H_3PO_4$ and $CH_3COOH$. Oxidation tests were carried out in air for 20 and 110hrs at $900^{\circ}C$, $950^{\circ}C$ and $1050^{\circ}C$. Hot corrosion tests were done in salt bath of 75% $Na_2SO_4-25%$ NaCl at $900^{\circ}C$ for 20hrs. After the tests, the samples were observed by optical microscopy and analysed by EPMA and X-ray mapping in order to investigate the distribution of composition. It was shown that corrosion resistances in various acids and hot salt bath were proven to be excellent. It was suggested that the amounts of oxides were determined mainly by the depth of internal and intergranular $Al_2O_3$ oxide layers.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.19 no.6
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• pp.311-317
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• 2009

3Y-TZP block doped with $HfO_2$ and $CeO_2$ for dental ceramic block to the proliferation of CAD/CAM systems was prepared by heating at $800{\sim}1100^{\circ}C$ and then sintering at $1450^{\circ}C$. The influences of heating temperature and addition of $HfO_2$ and $CeO_2$ on the mechanical and chemical properties of 3Y-TZP block were investigated. Using the EDS mapping images, $HfO_2$ and $CeO_2$ was well dispersed in the 3Y-TZP matrix. 3 wt% $HfO_2$ doped block showed the optimum biaxial strength (1 GPa), while 3 wt% $CeO_2$ doped block enhanced the stability of $t-ZrO_2$ under hydrothermal atmosphere.

• Korean Journal of Microbiology
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• v.38 no.2
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• pp.74-80
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• 2002

The purpose of this work was to investigate the characterization and sequence of catechol 1,2-dioxygenase (Cl,2O) purified from Acinetobacter sp. KS-1 which was grown on benzoate as a sole carbon source. Cl,2O demonstrated its enzyme activity to catechol and 4-methylcatechol. The optimum temperature of Cl,2O was $35^{\circ}C$, and the optimal pH was in the range from pH 7.5 to 9.0. $Ag^{+}$, $Hg^{+}$, and $Cu^{2+}$ showed inhibitory effect on the activity of Cl,2O. Molecular weight of the enzyme was determined to approximately 36 kDa by SDS-PAGE and 7-terminal amino acid sequence of Cl,2O was analyzed as $^{1}MNYQQIDALVKQMNVDTAKG^{20}$and exhibited 95% sequence homology with that of Cl,2O from Acinetobacter radioresistens In addition, trypsin digestion and peptide mapping were performed for internal sequencing analysis. Molecular weights of three digested peptide fragments were analyzed as 966.3 Da, 1933.8 Da and 2081.7 Da by MALDI-TOF, which were matched with each internal sequences $^{1}SQSDFNLRR^{9}\, ^{1}HGNRPSHVHYFNSAPGYR^{18}\, ^{1}TIEGPLYVAGAPESVGFAR^{19}$) of. A. radioresistens. PCR product was amplified with the degenerated primers derived from N-terminal and each internal amino acid sequences.

• Journal of Climate Change Research
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• v.9 no.1
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• pp.13-29
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• 2018

This study presented evaluation procedure for selecting appropriate GCMs and downscaling method by focusing on the climate extreme indices suitable for climate change adaptation. The procedure includes six stages of processes as follows: 1) exclusion of unsuitable GCM through raw GCM analysis before bias correction; 2) calculation of the climate extreme indices and selection of downscaling method by evaluating reproducibility for the past and distortion rate for the future period; 3) selection of downscaling method based on evaluation of reproducibility of spatial correlation among weather stations; and 4) MME calculation using weight factors and evaluation of uncertainty range depending on number of GCMs. The presented procedure was applied to 60 weather stations where there are observed data for the past 30 year period on Korea Peninsula. First, 22 GCMs were selected through the evaluation of the spatio-temporal reproducibility of 29 GCMs. Between Simple Quantile Mapping (SQM) and Spatial Disaggregation Quantile Delta Mapping (SDQDM) methods, SQM was selected based on the reproducibility of 27 climate extreme indices for the past and reproducibility evaluation of spatial correlation in precipitation and temperature. Total precipitation (prcptot) and annual 1-day maximum precipitation (rx1day), which is respectively related to water supply and floods, were selected and MME-based future projections were estimated for near-future (2010-2039), the mid-future (2040-2069), and the far-future (2070-2099) based on the weight factors by GCM. The prcptot and rx1day increased as time goes farther from the near-future to the far-future and RCP 8.5 showed a higher rate of increase in both indices compared to RCP 4.5 scenario. It was also found that use of 20 GCM out of 22 explains 80% of the overall variation in all combinations of RCP scenarios and future periods. The result of this study is an example of an application in Korea Peninsula and APCC Integrated Modeling Solution (AIMS) can be utilized in various areas and fields if users want to apply the proposed procedure directly to a target area.

• Korean Journal of Remote Sensing
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• v.38 no.6_1
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• pp.1141-1180
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• 2022

The application of satellite imageries has increased in the field of hydrology and water resources in recent years. However, challenges have been encountered on obtaining accurate evapotranspiration and soil moisture. Therefore, present researches have emphasized the necessity to obtain estimations of satellite-based evapotranspiration and soil moisture with related development researches. In this study, we presented the research status in Korea by investigating the current trends and methodologies for evapotranspiration and soil moisture. As a result of examining the detailed methodologies, we have ascertained that, in general, evapotranspiration is estimated using Energy balance models, such as Surface Energy Balance Algorithm for Land (SEBAL) and Mapping Evapotranspiration with Internalized Calibration (METRIC). In addition, Penman-Monteith and Priestley-Taylor equations are also used to estimate evapotranspiration. In the case of soil moisture, in general, active (AMSR-E, AMSR2, MIRAS, and SMAP) and passive (ASCAT and SAR)sensors are used for estimation. In terms of statistics, deep learning, as well as linear regression equations and artificial neural networks, are used for estimating these parameters. There were a number of research cases in which various indices were calculated using satellite-based data and applied to the characterization of drought. In some cases, hydrological cycle factors of evapotranspiration and soil moisture were calculated based on the Land Surface Model (LSM). Through this process, by comparing, reviewing, and presenting major detailed methodologies, we intend to use these references in related research, and lay the foundation for the advancement of researches on the calculation of satellite-based hydrological cycle data in the future.

• Korean Journal of Agricultural and Forest Meteorology
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• v.5 no.3
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• pp.200-207
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• 2003

'||'||'||'&'||'||'||'quot;Overheating index'||'||'||'&'||'||'||'quot;, the normalized difference in incident solar energy between a target surface and a level surface, is helpful in estimating the spatial variation in daily maximum temperature at the landscape scale. It can be computed as the ratio of the 4-hour cumulative solar irradiance surplus or deficit from that over a level surface to the maximum possible deviation (15 MJ $m^{-2}$ ) during the midafternoon. Ecosystem models may, for simplicity, use an empirical proxy (exposure index) variable combining slope and aspect in place of the overheating index to account for the variation of midafternoon solar irradiance. A comparative study with real-world landscape data was carried out to evaluate the performance of exposure index in replacing the overheating index. Overheating indices for summer solstice, fall equinox and winter solstice were calculated at 573,650 grid cells constituting the land surface of Donggye-Myun, Sunchang County in Korea, based on a 10-m DEM. Exposure index was also calculated for the same area and fitted for the variation of overheating index to derive a 2$^{nd}$ -order linear regression equation. The coefficient of determination ($R^2$) was 0.50 on summer solstice, 0.56 on fall equinox, and 0.44 on winter solstice, respectively. These are much lower than the theoretically calculated $R^2$ values ranging from 0.7 in summer to 0.9 in autumn. According to our study, exposure index failed to accurately predict the cumulative solar irradiance over a complex terrain, hindering its application to daily maximum temperature estimation. We suggest direct calculation of the overheating index in preference to using the exposure index.

• Korean Journal of Agricultural and Forest Meteorology
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• v.10 no.1
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• pp.1-8
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• 2008

The concept of growing degree-days (GDD) is widely accepted as a tool to relate plant growth, development, and maturity to temperature. Information on GDD can be used to predict the yield and quality of several crops, flowering date of fruit trees, and insect activity related to agriculture and forestry. When GDD is expressed on a spatial basis, it helps identify the limits of geographical areas suitable for production of various crops and to evaluate areas agriculturally suitable for new or nonnative plants. The national digital climate maps (NDCM, the fine resolution, gridded climate data for climatological normal years) are not provided on a daily basis but on a monthly basis, prohibiting GDD calculation. We applied a widely used GDD estimation method based on monthly data to a part of the NDCM (for Hapcheon County) to produce the spatial GDD data for each month with three different base temperatures (0, 5, and $10^{\circ}C$). Synthetically generated daily temperatures from the NCDM were used to calculate GDD over the same area and the deviations were calculated for each month. The monthly-data based GDD was close to the reference GDD using daily data only for the case of base temperature $0^{\circ}C$. There was a consistent overestimation in GDD with other base temperatures. Hence, we estimated spatial GDD with base temperature $0^{\circ}C$ over the entire nation for the current (1971-2000, observed) and three future (2011-2040, 2041-2070, and 2071-2100, predicted) climatological normal years. Our estimation indicates that the annual GDD in Korea may increase by 38% in 2071-2100 compared with that in 1971-2000.